A short review on the curing of fluoroelastomers is presented and in addition, an insight is given into its compounding practice. Curing systems of commercial interest and experimental curing systems are discussed with their respective mechanisms of crosslinking. An attempt is also made at discussing the physical and chemical changes that take place during postcuring while attention is drawn to areas of further work.
PierceO.R., McBeeE.J. and ClineR.E., J. Am. Chem. Soc., 75, 1953, 5618
4.
HazeldineR.N. and MarklowR.J., J. Am. Chem. Soc., 78, 1956, 962
5.
McBeeE.J., RobertsC.W. and PuerckhauerG.W.R., J. Am. Chem. Soc., 79, 1957, 2329
6.
FarrantP., DyckesG.W., DunmireR. and ButlerG.B., J. Am. Chem. Soc., 79, 1957, 6536
7.
ArnoldR.G., BarneyA.L. and ThompsonD.C., Rubber Chem. Technol., 46, 1973, 619
8.
KojimaG., YamabeM., WachiH. and KodamaS., Rubber Wld., 190, 1984, 38
9.
LyonsB.J., ‘The crosslinking of fluoropolymers with ionising radiation: a review1, Paper presented to International Conference on Radiation Processing for Plastics and Rubber II, Canterbury, England, March 1984
10.
DixonS., RexfordD.R. and RuggJ.S., Ind. Eng. Chem, 49, 1957, 1687
RuggJ.S. and StevensonA.C, Rubber Age, 82, 1957, 102
14.
KojimaG. and WachiH., Rubber Chem. Technol, 51, 1978, 940
15.
PaciorekK.J.L, ‘Chemical crosslinking of fluoroelastomers’, Chapter in ‘Fluoropolymers’, (High Polymers, Volume XXV) (Ed. L.A. Wall), Wiley Interscience, 1972
16.
SmithJ.F, Rubber Wld, 140, 1959, 263
17.
MoranA.L. and PattisonD.R, Rubber Age, 103, 1971, 37
18.
SpainR.G, ‘Behaviour of some elastomers in petroleum-based fluids at elevated temperature’, Paper presented to Division of Rubber ChemistryACS meeting, CincinnatiU.S., May 1958
19.
WeissJ, J. Polym. Sci, 29, 1958, 425
20.
WexlerS. and MarshallR, J. Am. Chem. Soc., 86, 1964, 781
21.
BohmG.G.A. and TveekremJ.O, Rubber Chem. Technol, 55, 1982, 575
22.
GriffinW.R, Rubber Wld, 136, 1957, 687
23.
RobbL.E., HonnF.J. and WolfD.R., Rubber Age, 82, 1957, 286
24.
ApothekerD. and KrusicP.J., PatentU.S. 4,035,565, 1977
25.
SmithJ.F., Rubber Wld., 142, 1960, 102
26.
ReillyW.L. and BrownH.C., J. Am. Chem. Soc., 78, 1956, 6032
27.
BryanC.J., Rubber Chem. Technol., 50, 1977, 83
28.
SchmiegelW.W., ‘Viton Fluoroelastomer Crosslinking by Bisphenols’, Paper presented at the South German Meeting of the Deutsche Kautschuk und Gummi Gesellschaft, April 1977
29.
PaciorekK.L., MitchellL.C. and LenkC.T., J. Polym. Sci., 45, 1960, 405
30.
SmithJ.F. and PerkinsG.T., J. Appl. Polym. Sci., 5, 1961, 460
31.
DavisH.R. and HonnF.J., PatentU.S. 3,071,565, 1963
32.
SmithJ.F., PatentU.S. 2,955,104, 1970
33.
GallagherG.A., PatentU.S. 3,016,368, 1962
34.
CongerR.P. and Van BuskirkP.R., PatentU.S. 3,208,979, 1965
35.
PaciorekK.L., LajinessW.G. and LenkC.T., J. Polym. Sci., 60, 1962, 141
OgunniyiD.S. and HepburnC., Plast. Rubber Proc. Appl., 6, 1986, 3
39.
HepburnC. and OgunniyiD.S., ‘Hexamethylene-N, N'bis(tert-butyl peroxycarbamate) as a new crosslinking agent for elastomers’, Proceeding of the International Rubber Conference, Kyoto, Japan, 1985
40.
ThomasD.K., J. Appl. Polym. Sci., 8, 1964, 1415
41.
KalfayanS.H., SilverR.H. and LiuS.S., Rubber Chem. Technol., 49, 1976, 1001
42.
OgunniyiD.S., Eur. Polym. J., 23, 1987, 557
43.
KalfayanS.H., SilverR.H. and MazzeoA.A., Rubber Chem. Technol., 48, 1975, 944
