Adsorption of tetramethyltetrazene on NaAuy surface leads to formation of aromatic compounds constituting thermal ionization mass spectrum, in accordance with the ionization rules of nitrogen-containing molecules established earlier. The suggested mechanism of tetramethyltetrazene adsorption on NaAuy surface is characteristic of azide adsorption on metal surfaces.
RasulevUKZandbergEYa.Surface ionization of organic compounds and its applications. Prog Surf Sci1988;
28: 181–412.
2.
ZandbergEYRasulevUKSharapudinovMP.Surface ionization of ethyl- diethyl-, and triethylamine molecules on tungsten oxides. Theor Exp Chem1973;
7: 299–304.
3.
BafraliRBellAT.Adsorption and decomposition of CH3NH2 on Mo(100)-c(2 × 2)N.Surf Sci1994;
316: 267–3276.
4.
NaitabdiARochetFCarniatoS, et al.
Room temperature differential conductance measurements of triethylamine molecules adsorbed on Si(001).Phys Chem Chem Phys2016;
18: 23231–23237.
5.
NaitabdiABournelFGalletJJ, et al.
Triethylamine on Si(001)-(2 × 1) at 300 K: Molecular adsorption and site configurations leading to dissociation.J Phys Chem C2012;
116: 16473–16486.
6.
Sarmiento-LopezAGBerumen-EspañaGLopez-SerranoC, et al.
Influence of supported gold particles on the surface reactions of diethylamine on TiO2.Surf Sci2016;
653: 197–204.
7.
LiuJLvCJinC, et al.
Adsorption and decomposition of methylamine on a Pt(100) surface: a density functional theory study.RSC Adv2015;
5: 20208–20217.
8.
WuJBYangYWLinYF, et al.
Adsorption and decomposition studies of t-butylamine, diethylamine, and methylethylamine on Si(100)-(2 × 1).J Phys Chem B2004;
108: 1677–1685.
9.
ChenJJWinogradN.The adsorption and decomposition of methylamine on Pd(111.)Surf Sci1995;
326: 285–300.
10.
ZandbergEYRasulevUK.Regularities of the formation of ions by amines during surface ionization and reactions in adsorbed layers. Izvestia An SSSR ser fizicheskaya1976;
40: 1561–1565.
11.
ZandbergEYRasulevUK.Formation of protonized ions in the thermal ionization of organic molecules.Dokl Akad Nauk SSSR1969;
187: 777–780.
12.
ZandbergEYRasulevUK.Surface ionization of organic compounds.Russ Chem Rev1982;
51: 819–832.
13.
FujiiTKitaiTI.Surface ionization mass spectrometry of organic compounds. I. Nitrogen-containing aliphatic organic compounds.Int J Mass Spectr Ion Proces1986;
71: 129–140.
14.
AlberasDJKissJLiuZM, et al.
Surface chemistry of hydrazine on Pt (111). Surf Sci1992;
278: 51–61.
15.
TafreshiSSRoldanADzadeNY, et al.
Adsorption of hydrazine on the perfect and defective copper (111) surface: A dispersion-corrected DFT study.Surf Sci2014;
622: 1–8.
16.
ArmstrongJLSunYMWhiteJM.Thermal decomposition of 1,1-dimethylhydrazine on Si(100)-2 × 1.Appl Surf Sci1997;
120: 299–305.
17.
SunYMSloanDWMcEllistremM, et al.
Surface chemistry of 1,1dimethylhydrazine on GaAs(100).J Vac Sci Tech A1995;
13: 1455–1460.
18.
RasulevUKKhalikovSM.Surface ionization of some derivatives of alkyl hydrazines.Zh Org Khim1976;
22: 479–484.
19.
Knat’koMVLapushkinMNPaleevVI.Thermally stimulated desorption of ionized particles from the oxygen-activated Na/Au surface.Tech Phys2004;
49: 905–908.
20.
Knat’koMVLapushkinMN. and
Paleev VI thermally stimulated desorption of Na+ and Cs+ ions from a NaAu alloy film grown on Au.Tech Phys2005;
50: 498–502.
21.
XiaCWangLLMaligal-GaneshR, et al.
Intermetallic NaAu2 as a heterogeneous catalyst for low-temperature CO oxidation.J Am Chem Soc2013;
135: 9592–9595.
BeynonJH.Metastable ions in mass spectra.Anal Chem1970;
42: 97A–102A.
24.
Knat'koMV.Lapushkin ML and paleev VI formation and thermal decomposition of NaAu alloy: surface ionization studies.Phys Low-Dimen Struct1998;
5/: 85–92.
