Commercial diesel vehicles that comply the China/EURO VI emission regulations are generally equipped with selective catalytic reduction (SCR) systems for reducing
emission and
sensors at its downstream for accurate closed-loop control. However,
sensors have significant ammonia cross-sensitivity pushing up their readings. Moreover, for the closed-loop control of SCR systems effectively estimating the critical states from the
sensor readings remains a further challenge. In this paper, an ammonia cross-sensitivity model with segmented sin and quadratic composite functions describing high frequency characteristics is established by analyzing the experimental data of an SCR system. A control-oriented three-states model of an SCR system is established, and based on it an extended Kalman filter (EKF) observer coupled to the ammonia cross-sensitivity model is proposed. The simulation results show that from the
sensor readings the EKF observer can effectively estimate the deterioration trend of the
and
emissions, and describe the dynamic change process of the ammonia coverage rate. The experimental results under the four non-excitation cycles show that the EKF observer can effectively estimate the deterioration trend, that the average estimated accuracy of
and
during their deterioration stage can respectively reach 86.16% and 54.87%, and that the observer has better robustness to disturbances from the operating conditions.