This paper presents a novel nonlinear local bond-slip model for fiber-reinforced polymer (FRP) laminates externally bonded to thermally damaged concrete substrates. The proposed model is an extension of an existing two-parameter bond-slip model and incorporates two key parameters including interfacial fracture energy (
) and interfacial brittleness index (
). To study the variations of
and
with different thermal damage levels of the concrete substrate, an extensive experimental database of shear tests on FRP-to-thermally damaged concrete bonded joints was collected from the existing literature. The
values were calculated from the peak pull loads with proper consideration of the bond length and width effects, while the
values were obtained by least-squares regression analysis using experimental load-displacement curves or measured strain distributions in the FRP laminates. The results have indicated that the
values initially exhibit a slight increase accompanied by mild thermal damage of the concrete substrate after exposure to moderately high temperatures; however, these values significantly decrease when the exposure temperature exceeds 300°C. The
values initially decrease with high-temperature exposure and stabilize at around 50% of the initial values when the temperatures reach around 400°C. Despite the inherent variability in the test database, the proposed temperature-dependent bond-slip model has demonstrated its accuracy, as demonstrated by the comparisons between the theoretical predictions generated by the model and the corresponding shear test results. This interfacial bond-slip model is expected to serve as a constitutive law to characterize the bond behavior between externally bonded FRP laminates and thermally damaged concrete substrate, thus facilitating the practical application of high-performance FRP composites in the repair and strengthening of thermally or fire-damaged RC members.