Chemomechamcal energy conversion exhibited by a gel lever has been studied both theoretically and experimentally. Based on the thermodynamical theory of anisotropic swelling, the effective mechanical work produced, the chemical energy consumed, and the efficiency of conver sion are discussed. The results of model calculations are compared with real experiments performed on water-swollen poly(vinyl alcohol) gels. The mechanical work as well as the free energy change during the process have been determined from experimental data.
Get full access to this article
View all access options for this article.
References
1.
Candau, S. , J. Bastide and M. Delsanti1982 "Structural Elastic and Dynamic Properties of Swollen Polymer Networks", Adv Polym. Sci. , 2744.
2.
de Gennes, P G 1979. Scaling Concepts in Polymer Physics Ithaca, NY: Cornell University Press.
3.
De Rossi, D. and K. Umezawa.1991. "Electrically Driven Pseudomuscular Gel Actuators", Preprints of Second Symposium on Polymer Gels, December 10, 11, Tsukuba, Japan
4.
Dusek, K. and W. Prins.1969. "Structure and Elasticity of Non-Crystalline Polymer Networks", Adv. Polym. Sci , 6:1.
5.
Flory, P.J.1953Principles of Polymer Chemistry. Ithaca, NYCornell University Press
6.
Hecht, A.M., F. Horkay, E. Geissler and M. Zrinyi.1990. "Experiments on Swollen Networks under Amsotropic Deformation", Polym. Comm. , 3153
7.
Horkay, F. , M. Nagy and M. Zrinyi.1980. "Apparatus for the Measurement of the Mechanical-Rheological Properties of Gels", Acta Chim., Sci , Hung. , 103387
8.
Horkay, F. and M. Zrinyi1986 "Studies on Mechanical and Swelling Behavior of Polymer Networks on the Basis of the Scaling Concept 6. Gels Immersed in Polymer Solutions ", J. Macromol. Sci., Phys., B25.307
9.
Horkay, F. and M. Zrinyi1988 "Studies on Mechanical and Swelling Behavior of Polymer Networks on the Basis of the Scaling Concept 7, Effect of Deformation on the Swelling Equilibrium Concentration of Gels", Macromolecules , 21.3260.
10.
Horkay, F. and M. Zrinyi.1989 "Mechanochemical Energy Conversion of Neutral Polymer Gels", Makromol. Chem. , Svmp , 30:133
11.
Katchalsky, A.1951 "Solutions of Polyelectrolytes and Mechanochemical Systems ", J. Polym. Sci , 7393
12.
Kilian, H.G.1985. 'An Interpretation of the Strain-Invariants in Largely Strained Networks", Colloid and Polymer Science, 263:30.
13.
Kuhn, W.1948. "Reversible Dehnung und Kontraktion bei Anderung der Ionization eines Netzwerks polyvalenter Fadenmolekulionen", Experientia , 5:318.
14.
Kuhn, W. , B. Hargitay, A. Katchalsky and H. Eisenberg.1950. "Reversible Dilatation and Contraction by Changing the State of High-Polymer Acid Networks". Nature , 165514
15.
Kuhn, W. and B. Hargitay1951 "Muskelahnliche Kontraktion und Dehnung von Netzwerken polyvalenter Fademolekulionen". Experientia, 7393.
16.
Nagy, M. and F. Horkay1980 "A Simple and Accurate Method for the Determination of Solvent Activity in Swollen Gels", Acta Chim , Sci. , Hung , 10449
17.
Osada, Y.1987 "Conversion of Chemical into Mechanical Energy by Synthetic Polymers", Advances in Polymer Science, 82.1
18.
Pines, E. , L.K. Wun and W. Prins1973. "Mechanochemical Energy Conversion", Journal of Chem Educ , 50-753
Treloar, L R G1975The Physics of Rubber Elasticity. OxfordClarendon Press
23.
Zrinyi, M. and F. Horkay1987. "On the Elastic Modulus of Swollen Gels", Polymer, 28:1139
24.
Zrinyi, M. , H.G. Kilian and F. Horkay.1989a. "On the Decisive Role of Finite Chain Extensibility and Global Interactions in Networks", Colloid & Polymer Sci., 267:311
25.
Zrinyi, M. , H.G. Kilian and F. Horkay, 1989b. "On the Uniaxial Stress-Strain Dependence of Highly Swollen Chemically Cross-Linked Networks", Makromol. Chem. , Symp. , 30:199.