The development of membrane systems that are adaptive-whose physical and/or chemical properties can be manipulated after synthesis—expands the applicability of membrane technology. In this work, we have employed both polyaniline and polypyrrole based membranes to demonstrate how transport of ionic species can be regulated using external electrical stimuli. In the case of polyaniline membranes, the transport of various acids has been studied and with polypyrrole, transport of simple cations such as potassium and sodium with chloride as counterions has been in vestigated.
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References
1.
Angelopoulous, M., A. Ray, A.G. McDiarmid and A. Epstein.1987"Polyaniline: Processability from Aqueous Solutions and Effect of Water Vapour on Conductivity", Synthetic Metals, 21:21-30.
2.
Burgmayer, P. and R.W. Murray.1984. "Ion Gate Electrodes. Polypyrrole as a Switchable Ion Conductor Membrane", Journal of Physical Chemistry, 88:2515-2521.
3.
Hofer, H., ed. 1981. Transport across Biological Membranes.London: Pit-man.
4.
Imisides, M.D., R. John, P.J. Riley and G.G. Wallace.1991. "The Use of Electropolymerization to Produce New Sensing Surfaces: Emphasizing Electrodeposition of Heteroaromatic Compounds", Electroanalysis, 3:879-889.
5.
Kaufman, J.H., K.K. Kanazawa and G.B. Street.1984. "Gravimetric Electrochemical Voltage Spectroscopy: In-situ Measurements during Electrochemical Doping of the Conducting Polymer Polypyrrole", Physical Review Letters , 53:2461-2464.
6.
Lakshiminarayaniah, N., ed. 1984. Equations for Membrane Biophysis.NY: AP.
7.
Loh, I.H., R.A. Moody and J.C. Huang.1990. "Electrically Conductive Membranes Synthesis and Applications", Journal of Membrane Science , 50:31-49.
8.
Marque, P., J. Roncali and F. Garnier.1987. "Electrolyte Effect on the Electrochemical Properties of Poly(3-Methylthiophene) Thin Films", Journal of Electroanalytical Chemistry, 218:107-118.
9.
Masahiro, I.1986. "Photoresponsive Polymers Reversible Bending of Rod-Shaped Acrylamide Gels in an Electric Field", Chemical and Pharmaceutical Bulletin, 19:2890-2892.
10.
Minoura, N., S.I. Aiba and Y. Fujiwara.1986. "Control of Solute Permeability Based on pH-Induced Reversible Conformational Change in Block Copolypeptide Membranes" , Journal of Applied Polymer Science , 31:1935-1942.
11.
Naarmann, H., G. Kohler and J. Schlag.U.S. patent no. 4,468,291, 1984.
12.
Ruckenstem, E. and J.S. Park.1991. "New Method for the Preparation of Thick Conducting Polymer Composites", Journal of Applied Polymer Science, 42:925-934.
13.
Shimidzu, T., A. Ohtam, T. Iyoda and K. Honda.1987. "Charge-Controllable Polypyrrole/Polyelectrolyte Composite Membranes", Journal of Electroanalytical Chemistry , 223:123-135.
14.
Skotheim, T. A., ed. 1986. Handbook of Conducting Polymer.New York: Marcel Dekker.
15.
Spach, G., ed. 1983. Physical Chemistry of Transmembrane Ion Motions.Amsterdam: Elsevier .
16.
Tamamura, R.T. and N. Osamu.U.S. patent no. 4,559,112, 1985.
17.
Wang, E., Y. Liu, S. Dong and J. Ding.1990. "Electrochemical Study of Ion Transport across the Polypyrrole Membrane between Two Electrolyte Solutions", J. Chem. Soc. Faraday. Trans. , 86:2243-2247.
18.
Yoshida, M., M. Asano, M. Kumakula, R. Kataki, T. Mashimo, H. Yuasa and H. Yamanaka.1990. "Thermoresponsive Hydrogels Based on Acrylolyl-L-Proline and Their Use as Long Acting Testosterone Delivery Systems" , Design and Drug Delivery, 237:1-16.
19.
Zhao, Q., C.J. Kolaskie and L.L. Miller1987. "The Incorporation of Electrolyte Cations into Polypyrrole and Poly-3-Methylthiophene during Electrochemical Reduction" , Journal of Electroanalytical Chemistry , 223:283-286.
20.
Zhao, H., W.E. Price and G.G. Wallace.1992. "Electrochemically Controlled Transport of Potassium Chloride across a Conducting Polymer Membrane", Journal of Electroanalytical Chemistry, 334:111-120.
21.
Zhao, H., W.E. Price and G.G. Wallace. In press. "Transport of Copper (II) across Stand Alone Conducting Polymer Membranes", Polymer .
22.
Zhong, C. , W. Storck and K. Doblhofer.1990. "The Membrane Properties of the Electro-Polymerized Conducting Pyrrole/N-Sulfopropyl-Pyrrole Copolymer", Ber Bunsenges Physical Chemistry, 994:1149-1155