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Abstract

The use of natural fibres as composite reinforcements is inevitable in view of developing a sustainable environment. When a natural fibre is extracted from a plant or ground or animal, they are prone to contain impurities and other unwanted substances. By removing these unwanted substances and by enhancing the strengths of the fibres, the reinforcements become predominant to carry the loads in a composite material and thus help the composite to acquire major mechanical properties. Hence, pretreatment methods are adopted for green fibres and it includes a series of chemical treatment, drying, heating in a furnace, and so on. These treatments help to enhance the surface roughness of the fibre, and thus, it increases the bonding strength with the surrounding matrix. The present study gives a clear picture of various pretreatment methods made in different research and their effect on the properties of the composite materials.

Keywords

Pretreatment natural fibre properties natural composites synthesis

Introduction

A green fibre-based composite material is developed by reinforcing natural fibres in a synthetic or natural resin in required shapes. The characteristics of such new materials depend on several factors. The reinforcement properties and resin properties are a major concern, which decide the characteristics of the composite material.^1-3 Apart from this, the operating conditions during fabrication and pretreatment methods adopted also play a vital role in fixing the composite properties. The various factors that affect the characteristics of a green fibre-based composite are shown in Figure 1. Natural fibres are extracted from various sources like plants, animals and minerals. Among the three types, plant- and mineral-based fibres are mainly focussed upon by the researchers in the last decade due to their availability and processing capability.

Figure 1.

Factors influencing the properties of green composites.

Plant-based fibres are derived from various parts of a plant like leaves, stems, fruits, grains and roots, whereas mineral fibres are derived from the underground and certain rocks.^4,5 Several natural fibres have been extracted and they are subjected to severe pretreatments before usage as a proper reinforcement in a composite material. Some important natural fibres and their characteristics are presented in Table 1.^6-11 On the other hand, the chemical composition of natural fibres has a dominant influence on the fibre characteristics. Cellulose is a semicrystalline substance with many hydroxyl groups giving hydrophilic properties to the surrounding matrix when a green fibre is reinforced in polymeric composites.¹² On the other hand, hemicellulose has an open structure with several hydroxyl and acetyl groups making it soluble in water and hygroscopic by nature. This causes the matrix to absorb moisture from atmospheric air.¹³ Lignin is amorphous and contains phenylpropane elements in its chemical structure. This provides it to gain a small resistance against water absorption among other constituents.¹⁴ The major chemical compositions of some important natural fibres are presented in Table 2.^15-17

Table 1.

Important green fibres and their properties.^6–11

Fibre	Density (kg/m³)	Diameter (µm)	Tensile strength (MPa)	Young’s modulus (GPa)	Failure strain (%)
Abaca	1500	10–30	400	12	3–10
Alfa	890	—	350	22	5.8
Bagasse	1250	490	70	17	3–5
Bamboo	880–1100	100–200	391–713	18–55	1.3
Banana	1350	50–250	500–550	12–20	5–6
Coconut	800	100–450	131–175	4–13	15–40
Coir	1200	10–16	175	4–6	30
Cotton	1500–1600	20	287–597	5–13	7–8
Curaua	1380	66	913	50–70	3.9
Date palm	1000–1200	14–18	97–196	2.5–5.4	2–4.5
Flax	1500	50–100	345–1035	50–70	2.7–3.2
Hemp	1100	120	389–900	35	1.6
Henequen	1490	180	430–580	10.1–16.3	1.6
Isora	1200–1300	10	500–600	—	5–6
Jute	1300	260	393–773	23–27	1.4
Kenaf	1310	106	427–519	23–27	1.8
Licuri	—	132–165	287–597	5–13	7–8
Nettle	1500	20–80	650	38	1.7
Oil palm	700–1550	150–250	248	25	3.2
Palmyra palm	1200	300–320	276	8.99	3.08
Piassava	1400	—	134–143	1.07–4.59	7.8–21.9
Pineapple	800–1600	25–34	400–627	14.5	1.44
Ramie	1500	34	560	24.5	2.5
Sisal	1500	50–80	511–635	9.4–22	2.0–2.5
Softwood kraft	1500	—	1000	40	4.4
Spider silk	14	2–8	875–972	11–13	17–18
Talipot	—	80–800	43–263	10–13	5.1
Vetiver	1500	100–220	247–723	12–49.8	1.6–2.4
Wool	—	20–30	120–174	2.3–3.4	25–35
Linen	1400	12–60	800	50–70	2.7–3.5

Table 2.

Chemical composition of natural fibres.¹⁵^–1⁷

Fibre	Cellulose (%)	Lignin (%)	Hemicellulose (%)	Pectin (%)	Fat/wax (%)
Banana	63–64	65.2	18.6	—	—
Sisal	84.93	7–11	10–24	0.8	0.3
Nettle	53–82.6	0.5	—	0.9–4.8	—
Abaca	56–63	7–9	15–17	0.5	0.2
Henequen	77.6	13.1	4–8	—	—
Ramie	91	0.7	5–16.7	1.9–2.1	0.3
Cotton	92–95	—	5.7	1.2	0.6
Pineapple	71.6	10.5	80.5	2–4	4–7
Hemp	77.07	3.7–13	14–22.4	0.8	0.7
Flax	62–71	2–2.5	16–18	1.8–2	1.5
Kenaf	65.7	15–19	21.5–23	—	—
Jute	63.24	12–26	13.6–21	0.2–4.4	0.5
Kapok	13	—	—	—	—
Coir	43	45	1.7	3–4	—
Oil palm	65	19	—	—	—
Isora	74	23	—	—	1.09
Linen	82	4	2	—	—

Among the chemical contents, celluloses add almost all characteristics to the fibre except water resistance, whereas hemicelluloses, lignin, wax and ash alleviate the properties of green fibre. Hence, chemical pretreatment is vital for all green fibres to remove unwanted substances. Alkali treatment is on such treatment, which removes the unwanted substances and adds the properties to green fibres.¹⁸ Apart from enhancing the properties of the fibre, the pretreatment also improves the machinability of green fabric composites to a notable extent.^19,20 The pretreatments, on the other hand, elevate the surface roughness of the fibre and make it more suitable to bond with the surrounding resin causing a strong bond between the fibre and the matrix.²¹ On the other hand, physical treatments are also used with the help of gases like argon and plasma as mediums. Plasma treatment raises the mechanical properties like tensile strength, flexural strength and interlaminar shear strength of flax-reinforced composites to a considerable extent.²² Several chemicals have been utilized for treating green fibres, and mostly, these treatments made a positive sign on the characteristics of green fibres. The present study gives a detailed picture of various chemical treatment methods and their effect on the characteristics of the fibre.

Alkali treatment

Compounds with hydroxide groups, such as sodium hydroxide (NaOH), potassium hydroxide, and so on, are commonly called alkali, and the treatment is said to be alkalination.^23,24 Several research works have focussed on the influence of NaOH treatment on the mechanical strengths and other properties of the natural fibre composites. All these have proved that alkalination is one of the common methods of pretreatment and may be applicable for all-natural fibres. Alkali treatment has been given to jute fibre, and then, it is reinforced in the natural rubber matrix in the form of composite plates. Mechanical characteristics have been evaluated, and it is revealed that the interfacial bonding between the natural rubber matrix and the jute fibre is enhanced to a maximum extent with the help of alkali treatment. This improves the stress transfer mechanism effectively and thus increases the composite characteristics, such as tensile strength, tensile modulus and hardness.²⁵ During the alkali treatment, the OH present in the green fibre OH of the alkali forms H₂O, O and Na ions, as shown in Figure 2. Alkali treatment has been given to vetiver fibres and the pretreated fibre is utilized as reinforcements in a polyester matrix to fabricate composite samples and reported that, alkali enhances the adhesive bonding between the matrix and the fibre.²⁶ In addition to the qualities discussed earlier, alkali treatment also reduces the spiral angle and raises the molecular orientation of the green fabrics.²⁷

Figure 2.

Reaction of alkali with green fibre.

Alkali treatment has been done on three different green fibres, namely, flax, linen and bamboo, before reinforcing in the epoxy matrix. A characteristic analysis revealed that alkali alleviated the tensile strength and tensile modulus of all the three green fibre yarns. At the same time, it is observed that the tensile strength and bending strength of composites are improved by 22% and 16%, respectively, in comparison to the untreated samples. Also, it is reported that alkali treatment notably enhanced the adhesive strength between the fibre and the matrix.²⁸ Alkali treatment of flax and linen, on the other hand, improved the compressive strength, compressive modulus, shear strength and shear modulus of the composites but reduced the impact strength and damping ratio of the composites. The decrease in the impact strength and damping ratio is due to the alleviated interfacial adhesion between the fibre and the matrix during alkali treatment.²⁹ Several works have been done to study the influence of alkali treatment on different green fibre composites. Some of them and their effects are given in Table 3.

Table 3.

Influence of alkali treatment of green fibres on composite properties.

S. no.	Green fibres used	Matrices used	Important findings	References
1.	Palmyra palm-leaf stalk	Polyester	60% Increase in TS, 37% increase in TM, 55% increase in the IS	³⁰
2.	Banana	Polypropylene	43% Increase in TS, 104% increase in TM, 67% increase in the FS, 15% increase in H	³¹
3.	Sisal	Polylactic acid	30% Increase in TS, 17% increase in FS, 107% increase in IS	³²
4.	Wheat straw	Epoxy	3% Alkali enhanced the thermal stability of the composites and adhesion of fibre/matrix interface	³³
5.	Betel nut, luffa, oil palm, rice straw, sisal	Epoxy, polyester, polylactic acid, polypropylene, zein	Elevation of sound absorption coefficients of all types of composites and enhancement of fibre/matrix adhesion	³⁴
6.	Bagasse	Polyvinyl chloride	48% Increase in TM, 10% increase in thermal stability, 14% increase in IS	³⁵
7.	Vetiver	Vinyl ester	27% Increase in TS, 30% increase in FS, 29% increase in CS, 59% increase in IS.²⁷ Alkali treatment also improved the water resistance and thermal degradation behaviour of the composites²⁸	^36,37
8.	Luffa	Polyester	Elevation of fibre/matrix adhesion and improvement in TS, CS, FS and IS considerably	³⁸
9.	Piassava	Polyester	10% Alkali is mostly suited to elevate the interfacial adhesion and storage modulus of the composites. The critical volume fraction of fibres is established between 30% and 40%	³⁹
10.	Flax	Poly furfuryl alcohol	Increase in thermal stability, storage modulus, damping factor, FS and water resistivity of the composites	⁴⁰
11.	Jute and palmyra palm	Unsaturated polyester	Elevation of fibre/matrix adhesion. It is concluded that along with alkali treatment, the use of fibres in hybrid form elevates the mechanical strength considerably	⁴¹
12.	Dharbai	Polyester	Alkali concentration and soaking time has significant influence on the mechanical properties. A concentration of 4–6% and soaking time of 24–37 h seem to be the optimum conditions to get maximum properties	⁴²
13.	Flax seed	Polybutylene succinate	Elevation in FS by 84%, enhancement in interfacial adhesion, interlocking and wetting of fibres with the matrix	⁴³
14.	Ramie	Polylactic acid	Enhancement in the crystallinity, crystal orientation factor of the fibre, 57% improvement in TS, 48% improvement in TM, 18% increase in FS and 91% increase in FM	⁴⁴
15.	Jute	Polyester	1% Alkali at 50°C for 60 min and a material t₀ liquor ratio of 1:10 is the optimum condition to achieve maximum mechanical properties	⁴⁵

TS: tensile strength; TM: tensile modulus; SB: strain at break; IS: impact strength; FS: flexural strength; FM: flexural modulus; CS: compressive strength; H: hardness.

Acryl treatments

Acrylation is followed after the alkali treatment as a sequential procedure and is done with the help of acrylic acid (C₃H₄O₂). Acrylation helps to reduce the hydrophilic nature of the fibre, thereby improving the strengths of the fibre. Studies on the influence of acrylation of sisal-reinforced phenolic plastics proved that acrylation enhanced two important properties, namely tensile and flexural strengths by 34% and 37%, respectively. In addition, acrylation also helped to improve the electrical strength and volume resistance of the composites by 37% and 43%, respectively. The water uptake ability of the composite is also found to diminish because of the replacement of the hydrophilic vinyl ester molecules present in the structure.⁴⁶ Acrylic acid has been used for pretreating banana fibres and is reinforced in the unsaturated polyester matrix to form composites. Mechanical and physical properties of the developed composites have been studied and showed that acrylic acid treatment enhanced the flexural strength, flexural modulus, impact strength and water resistivity of the composites to a notable extent in comparison to alkali-treated composites. Hence, acrylic acid treatment is superior to alkali treatment for enhancing the mechanical and physical properties of the composites.⁴⁷

Acrylonitrile (C₃H₃N) has been used as an agent for pretreating bamboo fabric mat and is reinforced in epoxy and polyester resins during composite preparation. A characteristic analysis of the prepared materials showed an elevation in the tensile strength and tensile modulus for both the resins. Also, acrylonitrile treatment of bamboo fabric drastically reduced the water-absorbing capacity of the composite from 75% to 14%.⁴⁸ A research study on the effect of acrylic acid treatment given to abaca fibre is made to study the mechanical properties. It is revealed that acrylic acid treatment enhanced the tensile strength and flexural strength of the composites to a maximum extent as compared to alkali and permanganate treatment. It is also reported that further elevation in the strength could be achieved by treating the abaca fabrics with benzendiazonium.⁴⁹ The effect on acrylonitrile grafting of Saccharum ciliare fibre is studied in another research and reported that the degree of chemical modification plays a vital role in deciding the properties, namely water resistance, chemical resistance and swelling behaviour.⁵⁰ In another research, bleached jute fabrics is surface modified by graft copolymerization using acrylonitrile and observed that the modification improved the thermal stability, breaking strength and dyeability of fabric to a maximum extent.⁵¹ The length of fibre also plays a dominant role in deciding the strengths of the composite. A comparison between 3, 5, 7 and 9 mm length hemp fibres when treated with acrylonitrile showed the highest tensile strength with 5 mm fibre-reinforced samples. It is also suggested that 3 mm length is not sufficient to achieve maximum strengths of the composites.⁵²

Peroxidation

Peroxide contains the group O–O in the form ROOR. Hydrogen peroxide (H₂O₂) is used for treating vetiver roots before reinforcing it in the polyester matrix. Peroxidation is given to green fibres after alkali treatment. During the treatment, HOOH decomposes into HO′ radicals; HO′ then reacts with the H group of the green fibre, as shown in Figure 3.²⁶ Property analysis on the fabricated composites concluded that peroxide treatment enhanced all the mechanical properties, as compared to the alkali-treated sample and, in particular, it is reported that peroxide can improve the bending strength and elongation capacity of the composite to a notable extent.

Figure 3.

Reaction of peroxide with green fibre.

Sisal fibres have been pretreated with alkali and then followed by H₂O₂. The treated fibres have been reinforced in polylactic acid matrix to form composite samples and an analysis of the mechanical characters is done. The results concluded that peroxidation enhanced the tensile strength, flexural strength and impact strength of the composites. It is also inferred that the water absorption of the treated fibre composite is much lower than that of the untreated fibre composites, and a witness on the enhanced thermal resistivity is observed with the treated fibre composites.³² Peroxidation is given to oil palm mesocarp fibre and reinforced in polybutylene succinate matrix in the form of plates. The plates are then tested and seen that there is a 54% increase in the tensile strength, 830% hike in the tensile modulus and 43% hike in the strain at break as a result of peroxidation.⁵³ The rate at which a green fibre absorbs water increases with the number of days exposed. Peroxidized coconut husk-reinforced composites are generally stable against water absorption as a result of the removal of hemicellulose and lignin from the green fibre.⁵⁴ Peroxide treatment is one of the vital treatment methods in eliminating the lignin content from the green fibre. As a result, when the peroxidized green fibres are used as reinforcements in composites, it elevates its tensile and thermal properties.⁵⁵ A more or less similar result has been recorded during testing of peroxidized oil palm fibre-reinforced materials.⁵⁶

Benzoylation

Benzoylation is aimed to enhance all the important characteristics of the green fibre and is done using benzoyl chloride solution (C₆H₅C=OCl). Before benzoylation, the green fibre is treated with NaOH and then immersed in benzoyl chloride solution for several hours. Then, the fibres are washed in distilled water and dried in an oven. The chemical reaction between benzoyl chloride and the fibre is shown in Figure 4. A comparative analysis among three different chemical treatments, namely alkylation, peroxidation and benzoylation of vetiver-reinforced laminates revealed that benzoylation is superior in enhancing almost all the mechanical strengths of the composite.²⁶

Figure 4.

Benzoylation of green fibres.

Influence of benzoylation of palmyra palm leaf-reinforced polyester laminates on the characteristics has been studied in a research and reported that benzoylation has a similar effect like the mercerization in enhancing the tensile strength and tensile modulus of the composites. Also, benzoylation alleviates the hydrophilic nature of the green fibre to a maximum extent and thus reduces the water-absorbing nature of the composites to a greater extent, as compared to mercerized green fibre composites.³⁰ When a green fibre is immersed in chemicals, in addition to the removal of unwanted substances, it is prone to change the dimensions. Many chemicals reduce the diameter of the green fibre as a result of the removal of unwanted substances and some may also reduce the length of the green fibre. Most of the chemicals are good in improving the surface roughness of the green fibre and especially benzoyl chloride is superior in doing that as compared to other chemicals. It has been proved that during benzoyl chloride treatment of sisal fibres, the crystallinity and surface roughness is elevated to a notable extent and thus makes the green fibre to effectively bond with the surrounding resin. This makes the composite to increase its thermal stability and mechanical strengths of the composites.⁵⁷

The properties of a green fibre could be elevated in several ways. Apart from the chemical pretreatment, there are also several other methods like hydrothermal treatment, microwave treatment, and so on. The effectiveness of these treatments is different for different green fibres. A comparison between hydrothermal treatment, microwave treatment, alkali treatment and benzoylation treatment of rice husk fibres revealed that, benzoylation is superior among the treatments in raising the physical and mechanical properties of the composites. Alkali treatment, hydrothermal treatment and microwave treatment, respectively, follow the benzoylation.⁵⁸ In another experimental study with jute fabrics, the effect of benzoylation has been compared with different chemicals, namely NaOH, NaClO₂, acrylonitrile, acetic anhydride, potassium permanganate (KMnO₄) and diphenylmethane diisocyanate. The results showed that benzoylation is most effective in elevating the mechanical properties and offers the highest resistance to water absorption. It is finally concluded that the enhancements in the characteristics are happened due to the proper interfacial adhesion at the fibre and matrix junction.⁵⁹ Characteristic investigations on benzoylated jute-reinforced epoxy laminates proved that benzoylation is on par with the silane treatment to elevate the storage modulus mechanical strengths and thermal stability of the composites.⁶⁰

Acetyl treatments

Acetylation is done using acetic anhydride ((CH₃CO)₂O) and acetic acid (CH₃COOH). Before this chemical treatment, the green fibres are treated with alkali and is then followed by acetylation. During the acetylation process, acetic anhydride reacts with the OH group of the green fibre and forms acetic acid, as shown in Figure 5. Piassava fibres are pretreated with acetic anhydride and subjected to mechanical characterization. The results showed that the chemical treatment has a predominant influence on the storage modulus of the composites. Thee fibre/matrix adhesion is superior below the glass transition temperature of the composites. Above the glass transition temperature, the storage modulus is not influenced by the chemical treatment but primarily on the fibre volume fraction.³⁹ Investigations on the influence of acetic acid treatment to jute fibres reported that chemical pretreatment using acetic acid elevated the thermal stability and tensile strength of the composites. Also, it is observed that adding 2–4% nanoclay along with acetic acid treatment elevated the decomposition temperature of the composite by alleviating the coefficient of thermal expansion by 19%. The interlaminar shear stress is observed to increase by 20% compared to the untreated composite, and the storage modulus of the composite is also found to increase to a considerable extent.^60,61

Figure 5.

Acetylation of green fibres.

Acetylation of flax fibres has been done with acetic anhydride and then reinforced in the polypropylene matrix during composite synthesis. A water absorption study has been performed on the fabricated materials and showed that there is a 50% increase in the resistance to water absorption and the thermal stability is hiked to a notable extent due to the acetylation process. It is noted that the degree of acetylation plays a dominant role in deciding the mechanical strengths and an 18% acetylation is suggested to acquire a maximum of 25% elevation in the tensile and flexural strength of the composites.⁶² A similar trend has been reported in another research on the banana empty fruit bunch fibre-reinforced polypropylene materials. It is witnessed that acetylation is better than alkali treatment in elevating the interfacial shear strength and mechanical properties, such as tensile strength, tensile modulus and impact strength. It is also noted that the acetylation process helped in uniform dispersion of fibres in the matrix that avoids defects like voids, microholes, and so on.⁶³ The behaviour of materials will change due to its age and due to the type of atmosphere it is used. Hence, hydrothermal ageing is an important phenomenon as several materials are subjected to thermal and moisture-filled atmospheres. The influence of hydrothermal ageing on the mechanical properties has been studied on the alfa fibre-reinforced polypropylene materials and found that at the beginning, the acetylated materials showed an elevation of 36% in the young’s modulus. After ageing, it is found that acetylated materials are far better in maintaining the properties, as compared to that of the untreated materials.⁶⁴ Several research have been done to study the influence of acetylation on different green fibre composites. Some of them and their effects are given in Table 4.

Table 4.

Influence of acetylation of green fibres on composite properties.

S. no.	Green fibres used	Matrices used	Important findings	References
1.	Wood	High-density polyethylene	Improvement in the interfacial adhesion and Youngs modulus but a drop in the strain at break	⁶⁵
2.	Kenaf	Polylactic acid	As the acetylation time is elevated, mechanical strengths and water resistance of the composites raises. Optimum acetylation time is found to be 2 h	⁶⁶
3.	Piassava	Polystyrene	Elevation of tensile, flexural impact strength and water resistance of the composites	⁶⁷
4.	Maize	Rubber	Addition of acetyl groups in to the cellulose results in enhancement of mechanical properties, reduced moisture absorption and an alleviated hydrothermal ageing	⁶⁸
5.	Luffa	Polyester	A drop in the hydrophilic behaviour, diffusion coefficient, water absorption and a raise in all mechanical properties.	⁶⁹
6.	Sea grass	Epoxy	Reduction in wear, elevation in impact strength, tensile strength and flexural strength	⁷⁰
7.	Luffa	Polyester	A hike in the flexural strength, flexural modulus and strain at break. Optimum fibre loading is found to be 10%	⁷¹
8.	Hemp	Polylactic acid	10–13% Higher activation energy as a result of high bond energy leading to enhanced thermal stability of the composites	⁷²
9.	Cochlosperum Planchonii	Polyester	Elevation of interfacial adhesion between fibre and matrix resulting in improved mechanical properties	⁷³
10.	Coconut shell	Polyethylene	Increase in the tensile strength, strain at break, Young’s modulus, thermal stability, crystallinity and interfacial adhesion	⁷⁴

Permanganate treatment

During permanganate treatment, the green fibres are initially treated with an alkali and are followed by immersion of fibres in KMnO₄/acetone solution. The fibres are then washed in distilled water and dried in an oven. During the permanganate treatment, the double bond between the oxygen and manganese of the permanganate breaks and the OH group of green fibre combines with the oxygen of permanganate, as shown in Figure 6. Permanganate treatment has been given to palmyra palm leaves fibre and then reinforced into polyester matrix during composite fabrication. Mechanical properties have been analyzed on the prepared materials and concluded that the permanganate treatment enhanced the flexural strength, flexural modulus and impact strength of the composites by 70%, 110% and 42%, respectively, in comparison to the untreated laminates.³⁰ Abaca fibres are pretreated with a 6% alkali solution for about 30 min and then washed in distilled water. The alkali-treated fibres are then immersed in 0.5% KMnO₄ in acetone solution for 2 min. Then, the fibres are washed and heated in a furnace to remove moisture. The treated fibres are reinforced in the epoxy matrix to fabricate the composites and a property analysis is done. The results revealed that permanganate treatment is superior to alkali treatment in elevating the tensile strength and flexural strength of the composites. It is suggested that the strengths may be further elevated by treating the fibre with other chemicals like acrylic acid and benzene diazonium.⁴⁹

Figure 6.

Permanganate treatment of green fibres.

Characteristic studies on the influence of KMnO₄-treated Sansevieria ehrenbergii fibre composites reported that KMnO₄ is the best treatment procedure for enhancing the tensile strength of the composites. It is also witnessed that the tensile strength drops with elevation in the water absorption period and the water absorption increases with the elevation in the water absorption period. It is suggested that the chemically treated composites are more suitable for body panels, bumpers, and interior parts of automobiles.⁷⁵ KMnO₄ is used along with acetone for solid-to-liquid conversion and the liquid KMnO₄ is used for pretreating the jute fibres. The pretreated jute fabric is reinforced in the epoxy matrix during composite preparation and a study on the characteristics is done. It is observed that the chemical treatment removed some portions of hemicellulose, lignin, pectin, wax and other covering materials, as a result, a strong bonding has been achieved between the fibre and the matrix resulting in the elevation of stress transfer capacity of the fibre. Moreover, it is noted that the hydrophilic nature of the composites is alleviated to a considerable extent.⁷⁶

Enzymatic treatments

Enzymes are one of the proteins available in living beings. Enzymes are secreted by the source and act as a catalyst during biochemical reactions to enhance the rate of reaction without any changes to themselves. Lipase, maltase, lactase, helicase, laccase, xylanase, trypsin, amylase, and so on are some examples of enzymes present in living beings. Enzymatic treatments help to improve the characteristics of green fibres to a notable extent. Banana fibres are treated with two types of enzymes, namely laccase and xylanase, at different concentrations and reinforced in polypropylene matrix during composite preparation. Mechanical strengths analysis of the developed materials revealed that a 20% concentration of xylanase provided a maximum increase of 21% for hardness, 69% for tensile strength, 189% for tensile modulus, 103% for flexural strength and 121% for impact strength of the composites.³² Enzymes are very effective in destroying the pectin, hemicelluloses and lignin present in the green fibres, therefore, it alleviates the fibre diameter and elevates the fibre aspect ratio. Hence, enzymatic treatments create a high fibre/matrix interface area resulting in better adhesion between the fibre and the matrix. An elevated adhesion produces improved mechanical properties in a composite material.⁷⁷

Enzymes also make the green fibre to easily spun and weave during fabric preparation. The conditions under which enzymes are involved also decide the property of a composite material. Optimum conditions have been arrived for enzymatic treatment of banana fibres and are found to be at a temperature of 45°C, pH of 4.5 and for a time of 6 h.⁷⁸ Laccase is an effective enzyme to modify jute fabrics before reinforcement. Laccase acts as a mediator while grafting octadecylamine on to the jute surface and elevates the hydrophobicity of jute fibres. When the laccase-treated jute is reinforced into the polypropylene matrix, it enhances the tensile strength, tensile modulus strain at break and bonding of jute with the polypropylene effectively.⁷⁹ Enzymatic treatments alleviate the diameter of the green fibre. This is identified while testing flaxseed fibres after it is subjected to pectinase enzyme treatment. Pectinase enzyme removes pectin from the fibre that develops smooth fibres. Wax present in the green fibre is also removed during enzyme treatment and its rate depends on the time of exposure. Prolonged enzymatic treatment is necessary to achieve a better tensile and impact properties, hence, pectinase is more suitable for the treatment of flaxseed fibres.⁸⁰ Enzyme treatment increases the surface area of flax fibres, which is exposed to the surrounding matrix and enhances the thermal stability, crystallinity index and water resistivity.⁸¹

Effect of coupling agents

Like the various chemical pretreatments, coupling agents also help to achieve a superior bonding between the fibre and the matrix, which in turn enhances the characteristics of the composites. Among the several coupling agents, maleic anhydride-modified polypropylene (MAP) and polybutadiene isocyanate (PBI) are used to modify aspen wood fibre composites. A comparison among pure polypropylene, untreated fibre composite and treated fibre composites has been done and shown that untreated fibre composites were poor in all aspects when compared to virgin polypropylene, thus, the effect of reinforcements is not achieved. However, the addition of 3% MAP and 5% PBI enhances the interfacial adhesion between the fibre and the matrix to a greater extent and thus elevates the tensile and impact properties of the composites. Thus, it is concluded that PBI is an effective coupling agent for aspen wood-reinforced polypropylene composites.⁸² Investigation on the influence of succinic anhydride grafted oil palm fibre-reinforced composites proved that a 40% fibre loading is most suited to achieve a maximum tensile strength. It is also observed that the thermal stability of composites is increased due to the chemical treatment.⁸³

Silanes (SiH₄) are also used as coupling agents for green fibres. Silane treatment decreases the number of cellulose hydroxyl groups present in the interface of fibre and matrix. The hydrolysable alkoxy group of silanes reacts with the moisture and forms silanols. Silanols then react with OH group of the green fibre and forms invariable covalent bonds with the cell walls, which are then chemically adsorbed to the surface of the fibre.^84,85 The chemical reactions are shown in Figure 7.

Figure 7.

Reaction of silanes with green fibres.

Bamboo fibres have been treated with six types of silanes, namely, γ-aminopropyltriethoxysilane (S1), 2-methoxyethoxy silane (S2), 3-aminopropyltrimethoxysilane (S3), N-octyltrimethoxysilane (S4), bistetrasulfide (S5), 3-trimethoxysilyl-propyl-methacrylate (S6), alkali and a combination of alkali and silanes before reinforcement in the matrix. A comparative property analysis among the developed composites revealed that the tensile modulus of silane-treated samples is inferior to that of the untreated samples. At the same time, the tensile strength of the alkali treated sample is 55% higher than that of the untreated sample. Also, it is observed that the fibres treated with both alkali and silane are superior in properties as compared to that of only silane-treated samples. Hence, it is concluded that alkali treatment is an important procedure before providing the green fibres with silane coupling.⁸⁶ Oligomeric siloxane is another coupling agent, which has a high capacity to enhance the characteristics of green fabrics. Jute fibres are initially treated with alkali and then followed by oligomeric siloxane before reinforcement in high-density polyethylene. Mechanical properties on the treated bamboo fibre composites have been analyzed and reported that there seems to be a 34% hike in the tensile strength, a 49% increase in the flexural strength and a 169% hike in the interlaminar shear strength as a result of chemical modification.⁸⁷ Hence, coupling agents are well proven to be the best way of modifying the green fabrics. Several works have been done to study the influence of coupling agents on different green fibres. Some of them and their effects are given in Table 5.

Table 5.

Influence of coupling agents of green fibres on composite properties.

S. no.	Green fibres + matrix used	Coupling agents used	Important findings	References
1.	Alfa + polypropylene	Maleic anhydride	7% Increase in Youngs modulus than the untreated one. Thermal degradation after ageing has been effectively resisted due to the silane treatment	⁶⁴
2.	Flax and hemp + epoxy acrylate	Polysilazane and organosilane	Increase in TS by 19.7% compared to untreated composite. However, polyvinyl alcohol coating alleviates the strength	⁸⁸
3.	Oil palm + polypropylene	Maleic anhydride	Enhancement of TS, FS is achieved at an optimum fibre loading of 30% and at 3% of silane treatment	⁸⁹
4.	Kenaf + polypropylene	Maleic anhydride	Elevation of TS, TM and IS and a decrease in melt flow index. Pretreatment elevates the interfacial adhesion and forms a three-dimensional structure in fibre/matrix junction	⁹⁰
5.	Flax + epoxy	3-Aminopropyltrimethoxysilane	20% Reduction in water absorption of the composites	⁹¹
6.	Basalt + polylactic acid	Maleic anhydride	26% Enhancement in strength and stiffness as compared to untreated fibre composite. Increased bonding at the fibre/matrix interface is evident	⁹²
7.	Sisal + polyester	Ammoniapropyl-triethoxy-silane (KH 550), methacryloxypropyl-trimethoxy-sliane (KH570)	KH 570 is an effective method to enhance fibre/matrix adhesion and consequent increase in mechanical strength than KH550	⁹³
8.	Coconut sheath + polyester	Trichoroviny silane	Increase in the time-to-flame out and interfacial adhesion. Thermal stability of the composites may be further raised by adding 5% of nanoclay	⁹⁴
9.	Roystonea regis + epoxy	3-Aminopropyl triethoxy silane	Enhancement of TS when a combination of silane and alkali are used as treatment, whereas highest impact strength is noted only with silane treatment	⁹⁵
10.	Hemp + polyamide	Aminosilane, epoxysilane and ureidosilane	Wear rate and friction coefficient decline as a result of silane treatments. This takes place due to the change in the wear mechanism because of the silane treatment. Ureidosilane is found to be the best among the three silanes	⁹⁶
11.	Palm petiole + epoxy	Aminopropyl triethoxysilane	Enhancement in TS, TM, FS, FM and IS of the composites as a result of silane treatment and happens due to the improved bonding between the fibre and matrix	⁹ ⁷
12.	Curaua + polyester	Triethoxymethyl silane	2.5 Times increase in the interfacial shear strength as compared to that of the untreated fibre composites, which takes place due to the increase in the bonding sites with the matrix	⁹⁸
13.	Oil palm + polyester	Phenyl silane	11% Improvement in the flexural strength and bonding ability at a fibre loading of 40%. This takes place due to the enhanced surface property of the fibre as a result of silane treatment	⁹⁹
14.	Cotton + epoxy	Maleic anhydride	An increase of 60–70% in TS, FS and IS due to enhancement of interfacial adhesion between fibre and matrix	¹⁰⁰
15.	Sugarcane + polyester	3-Aminopropyl-triethoxysilane	Silane treatment alleviates the water uptake ability and thickness swelling of the fibre and composites	¹⁰¹

TS: tensile strength; TM: tensile modulus; SB: strain at break; IS: impact strength; FS: flexural strength; CS: compressive strength; H: hardness; ILSS: interlaminar shear strength.

Other chemical treatments

Dimethylacetamide treatment

Apart from the discussed treatment methods, there are several other chemicals that are occasionally used in research. One among those is the N, N-dimethylacetamide (DMA), which has been used to treat jute fabrics before reinforcement in styrene-co-acrylonitrile resin. Composites have been formed in the form of panels and subjected to strength assessment. It is observed that DMA treatment to jute fabrics produced an impact strength of 20 KJ/m², a flexural strength of 42 MPa and a compressive strength of 61 MPa, which are the highest among the fabricated samples. It is also noted that there is an enhanced interfacial bonding of jute with the matrix and offered a maximum resistance to moisture absorption.¹⁰²

Polyhydroxybutyrate treatment

Polyhydroxybutyrate (PHB) is a synthetic polymer used mainly as a matrix during composite preparation. It is also used as an agent for treating green fabrics to enhance the properties. Jute fabric is treated with NaOH and PHB before incorporating it into the vinyl ester matrix and an investigation on the characteristics is done. It is observed that the chemical treatments do not have any influence on the flexural strength and flexural modulus when the composites are in a state of dry condition but the impact strength is found to be higher as compared to the untreated fibre composites. The water resistance behaviour is found to be more with the PHB-treated composite as compared to alkali-treated and untreated composites. The impact energy of the composite seems to increase drastically due to the PHB treatment as this occurs due to the formation of ductile PHB layer around the fibre, which elevates the energy during fracture.¹⁰³

Chromium sulfate and sodium bicarbonate treatments

Fibres extracted from ladies finger plant are subjected to alkali treatment, chromium sulfate treatment and a combination of chromium sulfate and sodium bicarbonate treatment. A comparison among the three revealed that alkali treatment has elevated the surface roughness by eliminating the hydrophilic hemicellulose present in the fibre, whereas the remaining treatments alleviate the surface roughness by forming a thin layer on the fibre and an improved chemical bonding with cellulose of the fibre. It is also noted that the tensile strength and tensile modulus of the fibre have been increased due to the surface treatments. As the span length goes up, there is a drop in the tensile strength and Young’s modulus, whereas there is no significant improvement in the thermal stability. The overall performance of double stage chemical treatment is found most satisfactory as compared to the alkali and single-stage treatments.¹⁰⁴

Stearic acid treatment

A 1% of stearic acid is liquified in ethyl alcohol and used as an agent to treat Phoenix pusilla fibres. The fibre is then dried and reinforced in the polymer matrix in the required shapes for mechanical testing. It is revealed that the stearic acid treatment increased the roughness of the fibre, which happened due to the removal of hemicellulose, oil and wax present in the fibre. Moreover, the surface treatment reduced the amorphous nature of the fibre by elevating the crystallinity index. This made the fibre to be more stable against an elevated atmosphere and it is confirmed that the tensile properties are substantially improved due to the stearic acid treatment.¹⁰⁵ In another research, stearic acid is used as an agent for the treatment of banana fabric-reinforced polyethylene composites, and it is recognized that stearic acid helped the banana fibres to improve its elastic modulus and the bonding capacity with surrounding resin.¹⁰⁶

Fire-retardant treatments

Some chemicals are specifically used to elevate some properties of the green fibre with a sacrifice in common properties. Ammonium phosphate and aluminum hydroxide are well-known fire retardants and are primarily intended to hike the fire resistance of the green fibres. The fire resistance of the green fibre goes up with an elevation in the fire-retardant composition. For flax fibres, a fire-retardant content of 20–30% would be an optimum amount for enhancing the fire resistance. On the other hand, the fire-retardant treatment reduces some other properties like tensile strength and tensile modulus of the composites to a notable extent.¹⁰⁷ Thus, depending on the application where a composite material is used, fire retardants could be used as surface modifiers at the loss of some common mechanical properties.

Hydrochloric acid treatment

Hydrochloric acid (HCl) is another chemical used for the pretreatment of green fibres and is done by immersing the green fibres in the aqueous solution of HCl for about 2 h. After the treatment, the green fibres are washed several times and heated in a furnace to remove the moisture. HCl-treated oil palm fibres show a low degree of swelling in moisture and happen due to the improvement in the cross-linking density between the fibre and polymer. Due to this fibre–polymer interaction, the other properties, such as load-bearing capacity, dynamic mechanical properties and ageing resistance of the composites, also increase and this could be evidenced by an elevated storage modulus and an alleviated mechanical loss factor. Hence, HCl is an effective agent to hike the characteristics of oil palm fibre-reinforced materials.¹⁰⁸ On the other hand, HCl in comparison with NaOH does not enhance the interlaminar shear strength of kenaf fibres when tested for single fibre pull-out test. The fibre experiences brittle and ductile failure during the test as a result of HCL treatment.¹⁰⁹

Sodium chlorite treatment

Sodium chlorite (NaClO₂) is mainly intended to bleach the green fibres in an acid solution. During the treatment, NaClO₂ forms chlorine dioxide. Chlorine dioxide then reacts with the lignin and hydrophilic hemicellulose present in the green fibre and removes off the lignin from the fibre. Finally, the hydrophilic property of the fibre is changed and the fibre becomes hydrophobic. Also, the delignification of the green fibre makes it more flexible and reduces the stiffness.⁸⁴ Apart from the enhancement in the hydrophobic nature, NaClO₂ along with alkali improves the tensile strength and makes the material more suitable to work under moisture.^110,111

Comparison between treated and untreated green fibre composites

A comparative analysis has been done between treated green fibre composites and untreated green fibre composites to justify the significance of chemical pretreatments. A summary of the analysis is presented in Table 6.

Table 6.

Comparison between treated and untreated green fibre composites.

S. no.	Fibre/treatment method used	Properties before treatment	Properties after treatment	References
1.	Mulberry/sodium hydroxide	TS = 464 MPa TM = 10.45 GPa SB = 4.73%	TS = 606 MPa TM = 11.78 GPa SB = 5.33%	¹⁸
2.	Sisal /methacryloxypropyl-trimethoxy-sliane	TS = 54 MPa FS = 78 MPa IS = 16.5 kJ/m²	TS = 67 MPa FS = 92 MPa IS = 19 kJ/m²	⁹³
3.	Roystonea regis/alkali + 3-aminopropyltriethoxysilane	TS = 38.89 MPa TM = 2207 MPa SB = 3.97%	TS = 44.12 MPa TM = 1957 MPa SB = 3.82%	⁹⁵
4.	Palm petiole/aminopropyltriethoxysilane	TS = 0.55 MPa TM = 0.58 GPa FS = 7 MPa FM = 6 GPa IS = 0.8 J	TS = 0.7 MPa TM = 0.7 GPa FS = 9 MPa FM = 11 GPa IS = 1 J	⁹⁷
5.	Banana/3-aminopropyltriethoxysilane	TS = 102 MPa TM = 3400 MPa SB = 2.5%	TS = 142 MPa TM = 3750 MPa SB = 5.8%	¹¹²
6.	Catharenthus roseus/sodium hydroxide	TS = 27.02 MPa TM = 1.23 GPa SB = 2.15%	TS = 30.43 MPa TM = 1.84 GPa SB = 1.7%	¹¹³
7.	Grewia serrulate/acetic acid	IS = 18 kJ/m² H = 21.7 Hv	IS = 50 kJ/m² H = 43 Hv	¹¹⁴
8.	Banana/sodium hydroxide	TS = 33 MPa FS = 58 MPa IS = 125 J/m	TS = 35 MPa FS = 62 MPa IS = 138 J/m	¹¹⁵
9.	Rattan/sodium hydroxide	TS = 215.36 MPa	TS = 225.45 MPa	¹¹⁶
9.	Rattan/acrylic acid	TS = 215.36 MPa	TS = 360.71 MPa	¹¹⁶
10.	Pine apple leaves/sodium hydroxide	TS = 475 MPa WR = 60%	TS = 670 MPa WR = 93%	¹¹⁷
11.	Basalt/hydrochloric acid	TS = 270 MPa H = 63 D	TS = 360 MPa H = 87 D	¹¹⁸
11.	Basalt/sodium hydroxide	TS = 270 MPa H = 63 D	TS = 330 MPa H = 78 D	¹¹⁸
12.	Olive husk/sodium hydroxide	TS = 55 MPa TM = 1595 MPa SB = 4.2%	TS = 56 MPa TM = 1675 MPa SB = 4.4%	¹¹⁹
13.	Saw dust/maleic anhydride	TS = 23 MPa	TS = 33 MPa	¹²⁰
13.	Saw dust/(3-aminopropyl)-triethoxysilane	SB = 4.4%	SB = 4.5%	¹²⁰
14.	Wood/maleic anhydride	TS = 9.2 MPa TM = 245 MPa FM = 860 MPa IS = 9.1 kJ/m²	TS = 17 MPa TM = 275 MPa FM = 975 MPa IS = 9.5 kJ/m²	¹²¹
15.	Jute/sodium hydroxide	TS = 22 MPa TM = 1350 MPa FS = 37.5 MPa IS = 2 J	TS = 28 MPa TM =1750 MPa FS = 43.5 MPa IS = 3.5 J	¹²²
16.	Sisal/diphenylmethane diisocyanate	TS = 45 MPa	TS = 73 MPa	¹²³
17.	Cane/sodium hydroxide	TS = 16.5 MPa TM = 2.4 GPa FS = 54 MPa	TS = 25.5 MPa TM = 3.65 GPa FS = 78 MPa	¹²⁴
18.	Flax/sodium bicarbonate	TS = 135 MPa TM = 11 GPa FS = 146.4 MPa FM = 11.5 GPa	TS = 160 MPa TM = 14.9 GPa FS = 177 MPa FM = 13 GPa	¹²⁵

TS: tensile strength; TM: tensile modulus; SB: strain at break; IS: impact strength; FS: flexural strength; FM: flexual modulus; H: hardness; WR: water retention.

Conclusions

To make the green fibres more suitable for reinforcing in polymer-based materials, the basic nature of the fibre is to be modified. The surface modification of fibre could be done by several chemicals and these have a specific effect on the fibre. The important properties may include mechanical strengths, moduli, interlaminar shear strength, bonding ability, water and chemical retention, flammability, thermal strengths, and so on. Among the different chemicals, NaOH is proven to be the best in elevating the majority of the characteristics of the fibre. This is revealed by research works done on many fibres, such as banana, sisal, bagasse, vetiver, luffa, flax, jute, and so on. It has been proved that NaOH is effective in enhancing the interfacial adhesion between the fibre and matrix and thus elevates the composite tensile properties up to 60%, impact properties up to 107% and flexural properties up to 91%. In addition, NaOH elevates the interlocking and wetting of fibres with the matrix, thermal stability and storage modulus of the composites. On the other hand, silanes and other chemicals, such as acrylic acid, acetic acid and other coupling agents, are also effective in enhancing some of the surface properties of green fibres. Each chemical has a significant effect on improving a property of the fibre. Hence, the selection of chemicals depends on the typical application of the green fibre materials. Sometimes, depending on the type of atmosphere where the fibre is utilized, two or more chemical treatments are necessary to make it suitable for usage. The working conditions, such as the concentration of chemicals, temperature involved, duration, and so on, are to be seriously taken during the treatments as they have a direct impact on the characteristics of the fibre. Hence, a chemical treatment with a proper operating condition becomes more important for green fibres before composite fabrication.

Footnotes

Declaration of conflicting interests

The author(s) declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Funding

The author(s) received no financial support for the research, authorship, and/or publication of this article.

ORCID iD

R Vinayagamoorthy

References

Praveen Kumar

Nalla Mohamed

. A comparative analysis on tensile strength of dry and moisture absorbed hybrid kenaf/glass polymer composites. J Ind Text 2018; 47: 2050–2073.

Vinayagamoorthy

Venkatakoteswararao

. Synthesis and property analysis of green resin-based composites. J Thermoplast Compos Mater. Epub ahead of print 20 February 2019. DOI: 10.1177/0892705719828783.

Vinayagamoorthy

. Trends and challenges on the development of hybridized natural fiber composites. J Nat Fibers. Epub ahead of print 9 April 2019. DOI: 10.1080/15440478.2019.1598916.

Piah

MRM

Baharum

Abdullah

. Mechanical properties of bio-composite natural rubber/high density polyethylene/mengkuang fiber (NRHDE/MK). Polym Polym Compos 2016, 24: 767–774.

Vinayagamoorthy

. A review on the polymeric laminates reinforced with natural fibers. J Reinf Plast Compos 2017; 36: 1577–1589.

Osorio

Trujillo

Van Vuure

, et al. Morphological aspects and mechanical properties of single bamboo fibers and flexural characterization of bamboo/epoxy composites. J Reinf Plast Compos 2011; 30: 396–408.

Thiruchitrambalam

Shamnugam

. Influence of pre-treatments on the mechanical properties of palmyra palm leaf stalk fiber-polyester composites. J Reinf Plast Compos 2012; 30: 1400–1414.

Vinayagamoorthy

. Effect of particle sizes on the mechanical behaviour of limestone-reinforced hybrid plastics. Polym Polym Compos 2020; 28: 410–420.

Ruksakulpiwat

Suppakarn

Sutapun

, et al. Vetiver–polypropylene composites: physical and mechanical properties. Compos Part A: Appl Sci Manuf 2007; 38: 590–601.

10.

Kulkarni

Sathyanarayana

Rohatgi

, et al. Mechanical properties of banana fibres. J Mater Sci 1983; 18: 2290–2296.

11.

Avinash Pai

Ramanand Jagtap

. Surface morphology and mechanical properties of some unique natural fiber reinforced polymer composites-a review. J Mater Environ Sci 2015; 6: 902–917.

12.

Alvarez

Ruscekaite

Vazquez

. Mechanical properties and water absorption behavior of composites made from a biodegradable matrix and alkaline-treated sisal fibers. J Compos Mater 2003; 37: 1575–1588.

13.

Frederick

Norman

. Natural fibers plastics and composites. New York: Kluwer Academic Publishers, 2004.

14.

Rowell

Young

Rowell

. Paper and composites from agro-based resources. Boca Raton: CRC Lewis Publishers, 1997.

15.

Zainudin

Sapuan

Abdan

, et al. Dynamic mechanical behaviour of banana-pseudostem-filled unplasticized polyvinyl chloride composites. Polym Polym Compos 2009; 17: 55–61.

16.

Yuvaraj

Kumar

Saravanan

. An Experimentation of chemical and mechanical behaviour of epoxy-sisal reinforced composites. Polym Polym Compos 2017; 25: 221–224.

17.

Venkatachalam

Navaneethakrishnan

Rajasekar

, et al. Effect of pretreatment methods on properties of natural fiber composites: a review. Polym Polym Compos 2016; 24: 555–566.

18.

Vinayagamoorthy

. Mechanical performance of glass- and biofibre-reinforced hybrid composites. In: Babu

Paulo Davim

(eds) Glass fibre-reinforced polymer composites. 1st ed. Berlin: Walter de Gruyter, 2020, pp. 1–16.

19.

Vinayagamoorthy

. A review on the machining of fiber-reinforced polymeric laminates. J Reinf Plast Compos 2018; 37: 49–59.

20.

Vinayagamoorthy

Manoj

Narendra Kumar

, et al. A central composite design based fuzzy logic for optimization of drilling parameters on natural fiber reinforced composite. J Mech Sci Technol 2018; 32: 2011–2020.

21.

Salem

Tirkes

Akar

, et al. Enhancement of mechanical, thermal and water uptake performance of TPU/jute fiber green composites via chemical treatments on fiber surface. e-Polymers 2020; 20: 133–143.

22.

Sarikanat

Seki

Sever

, et al. The effect of argon and air plasma treatment of flax fiber on mechanical properties of reinforced polyester composite. J Ind Text 2016; 45: 1252–1267.

23.

Vinayagamoorthy

. Friction and wear characteristics of fibre reinforced plastic composites. J Thermoplast Compos Mater 2020; 33: 828–850.

24.

Vinayagamoorthy

Rajmohan

. Machining and its challenges on bio-fibre reinforced plastics: a critical review. J Reinf Plast Compos 2018; 37: 1037–1050.

25.

Roy

Debnath

Tzounis

, et al. Effect of various surface treatments on the performance of jute fibers filled natural rubber (NR) composites. Polymers 2020; 12: 1–14.

26.

Vinayagamoorthy

. Influence of fiber surface modifications on the mechanical behavior of Vetiveria zizanioides reinforced polymer composites. J Nat Fibers 2019; 16: 163–174.

27.

Jiang

. Effect of surface treatment on the morphology of sisal fibers in sisal/polylactic acid composites. J Reinf Plast Compos 2012; 31: 621–630.

28.

Yan

Chouw

Yuan

. Improving the mechanical properties of natural fibre fabric reinforced epoxy composites by alkali treatment. J Reinf Plast Compos 2012; 31: 425–437.

29.

Yan

. Effect of alkali treatment on vibration characteristics and mechanical properties of natural fabric reinforced composites. J Reinf Plast Compos 2012; 31: 887–896.

30.

Thiruchitrambalam

Shanmugam

. Influence of pre-treatments on the mechanical properties of palmyra palm leaf stalk fiber–polyester composites. J Reinf Plast Compos 2012; 31: 1400–1414.

31.

Vishnu Vardhini

Murugan

Surjit

. Effect of alkali and enzymatic treatments of banana fibre on properties of banana/polypropylene composites. J Ind Text 2017; 47: 1849–1864.

32.

Rajesh

Ratna Prasad

Gupta

AVSSKS

. Mechanical and degradation properties of successive alkali treated completely biodegradable sisal fiber reinforced poly lactic acid composites. J Reinf Plast Compos 2015; 34: 951–961.

33.

Mittal

Sinha

. Effect of alkali treatment on the thermal properties of wheat straw fiber reinforced epoxy composites. J Compos Mater 2016; 5: 323–331.

34.

Jayamani

Hamdan

Bakri

MKB

, et al. Analysis of natural fiber polymer composites: effects of alkaline treatment on sound absorption. J Reinf Plast Compos 2016; 35: 703–711.

35.

Saini

Narula

Choudary

, et al. Effect of particle size and alkali treatment of sugarcane bagasse on thermal, mechanical, and morphological properties of PVC-bagasse composites. J Reinf Plast Compos 2010; 29: 731–740.

36.

Vinayagamoorthy

Rajeswari

. Mechanical performance studies on Vetiveria zizanioides/jute/glass fiber-reinforced hybrid polymeric composites. J Reinf Plast Compos 2014; 33: 81–92.

37.

Vinayagamoorthy

Sivanarasimha

Padmanabhan

, et al. Experimental studies on water absorption and thermal degradation of natural composites. Int J Appl Eng Res 2015; 10: 663–668.

38.

Vinayagamoorthy

Saswath Kaundinya

Mani Teja

GLSN

, et al. A study on the properties of natural sandwich laminates. Indian J Sci Technol 2016; 9: 1–6.

39.

d’Almeida

ALFS

Calado

Barreto

, et al. Effect of surface treatments on the dynamic mechanical behaviour of piassava fiber–polyester matrix composites. J Therm Anal Calorim 2011; 103: 179–184.

40.

Tshwafo Motaung

Mfiso Mngomezulu

Mpitloane Hato

. Effects of alkali treatment on the poly(furfuryl) alcohol–flax fibre composites. J Thermoplast Compos Mater 2018; 31: 48–60.

41.

Shanmugam

Thiruchitrambalam

. Influence of alkali treatment and layering pattern on the tensile and flexural properties of palmyra palm leaf stalk fiber (PPLSF)/jute fiber polyester hybrid composites. Compos Interfaces 2014; 21: 3–12.

42.

Kalyana Sundaram

Jayabal

. Regression modeling and particle swarm optimization of mechanical properties of potassium hydroxide pretreated Dharbai fiber-reinforced polyester composites. Proc IMechE Part L: J Mater Des Appl 2016; 230: 105–115.

43.

Azhar

Zhang

, et al. Fabrication and mechanical properties of flaxseed fiber bundle-reinforced polybutylene succinate composites. J Ind Text 2020; 50: 98–113.

44.

Yang

Zhu

Yang

, et al. Improving mechanical properties of ramie/poly (lactic acid) composites by synergistic effect of fabric cyclic loading and alkali treatment. J Ind Text 2017; 47: 390–407.

45.

Patel

Parsania

. Preparation and physico-chemical study of glass–sisal (treated–untreated) hybrid composites of bisphenol-c based mixed epoxy–phenolic resins. J Reinf Plast Compos 2010; 29: 52–59.

46.

Jannah

Mariatti

Abu Bakar

, et al. Effect of chemical surface modifications on the properties of woven banana-reinforced unsaturated polyester composites. J Reinf Plast Compos 2009; 28: 1519–1531.

47.

Pradeep Kushwaha

Kumar

. Studies on performance of acrylonitrile-pretreated bamboo-reinforced thermosetting resin composites. J Reinf Plast Compos 2010; 29: 1347–1352.

48.

Mohammad Hossain

Dewan

Hosur

, et al. Effect of surface treatment and nanoclay on thermal and mechanical performances of jute fabric/biopol ‘green’ composites. J Reinf Plast Compos 2011; 30: 1841–1856.

49.

Punyamurthy

Sampathkumar

Bennehalli

, et al. Influence of fiber content and effect of chemical pre-treatments on mechanical characterization of natural abaca epoxy composites. Indian J Sci Technol 2015; 8: 1–11.

50.

Singha

Shama

Thakur

. Pressure induced graft-co-polymerization of acrylonitrile onto Saccharum cilliare fibre and evaluation of some properties of grafted fibre. Bull Mater Sci 2008; 31: 7–13.

51.

Mondal

MIH

Islam

. Dyeing and thermal behavior of jute fibre grafted with nitrile monomer. Fashion Text 2015; 2: 1–12.

52.

Murali

Chandramohan

. Chemical treatment on hemp/polymer composites. J Chem Pharm Res 2014; 6: 419–423.

53.

Then

Ibrahim

Zainuddin

, et al. Influence of alkaline-peroxide treatment of fiber on the mechanical properties of oil palm mesocarp fiber/poly(butylene succinate) biocomposite. Bioresources 2015; 10: 1730–1746.

54.

Faola

Oladele

Adewuyi

, et al. Effect of chemical treatment on water absorption capability of polyester composite reinforced with particulate agro-fibres. Chem Mater Res 2013; 3: 106–112.

55.

Zaaba

Jaafar

Ismail

. The effect of alkaline peroxide pre-treatment on properties of peanut shell powder filled recycled polypropylene composites. J Eng Sci 2017; 13: 75–87.

56.

Suradi

Yunus

Beg

MDH

, et al. Oil palm bio-fiber reinforced thermoplastic composites-effects of matrix modification on mechanical and thermal properties. J Appl Sci 2010; 10: 3271–3276.

57.

Kalia

Vijay Kaushik

Rajesh Sharma

. Effect of benzoylation and graft copolymerization on morphology, thermal stability, and crystallinity of sisal fibers. J Nat Fibers 2011; 8: 27–38.

58.

Wang

Yang

. Effect of pretreatment on the soil aging behaviour of rice husk fibers/polyvinyl chloride composites. Bioresources 2019; 14: 59–69.

59.

Arifuzzaman Khan

Shaik

Shamsul Alam

, et al. Effect of chemical treatments on the physical properties of non-woven jute/PLA biocomposites. Bioresources 2015; 10: 7386–7404.

60.

Singhal

Tiwari

. Effect of various chemical treatments on the damping property of jute fibre reinforced composite. Int J Adv Mech Eng 2014; 4: 413–424.

61.

Sathishumar

. Influence of cellulose water absorption on the tensile properties of polyester composites reinforced with Sansevieria ehrenbergii fibers. J Ind Text 2016; 45: 1674–1688.

62.

Bledzki

Mamun

Lucka-Gabor

, et al. The effects of acetylation on properties of flax fibre and its polypropylene composites. eXPRESS Polym Lett 2008; 2: 413–422.

63.

Haydar Zaman

Ruhul Khan

. Acetylation used for natural fiber/polymer composites. J Thermopast Compos Mater. Epub ahead of print 10 April 2019. DOI: 10.1177/0892705719838000.

64.

Hamour

Boukerrou

Djidjelli

, et al. Effects of MAPP compatibilization and acetylation treatment followed by hydrothermal aging on polypropylene alfa fiber composites. Int J Polym Sci 2015; 2015: 1–9.

65.

Benmbarek

Robert

Sammouda

, et al. Effect of acetylation and additive on the tensile properties of wood fiber - HDPE composite. J Reinf Plast Compos 2013; 32: 1646–1655.

66.

Rodríguez

Francucci

. PHB coating on jute fibers and its effect on natural fiber composites performance. J Compos Mater 2015; 50: 2047–2058.

67.

Obasi

Nwanonenyi

Chiemenem

, et al. Effects of fibre acetylation and fibre content on the properties of piassava fibre reinforced polystyrene. Futo J Ser 2018; 4: 475–491.

68.

Chigondo

Shoko

Nyamunda

, et al. Maize stalk as reinforcement in natural rubber composites. Int J Sci Technol Res 2013; 2: 263–271.

69.

Ghali

Aloui

Zidi

, et al. Effect of chemical modification of luffa cylindrica fibers on the mechanical and hygrothermal behaviours of polyester/luffa composites. Bioresources 2011; 6: 3836–3849.

70.

Milan

Christopher

Winowlin Jappes

, et al. Investigation on mechanical properties and chemical treatment of sea grass fiber reinforced polymer composites. J Chem Pharm Sci 2015; 7: 72–77.

71.

Ghali

Msahli

Zidi

, et al. Effects of fiber weight ratio, structure and fiber modification onto flexural properties of luffa-polyester composites. Adv Mater Phys Chem 2011; 1: 78–85.

72.

Oza

Ning

Ferguson

, et al. Effect of surface treatment on thermal stability of the hemp-PLA composites: correlation of activation energy with thermal degradation. Compos: Part B 2014; 67: 227–232.

73.

Echiye

Ashwe

Nyior

, et al. Dynamic mechanical analysis of ukam (Cochlosperum planchonii) fibre reinforced polyester composites. Int J Sci Eng Res 2018; 9: 447–453.

74.

Tengku Faisal

Amri

Salmah

, et al. The effect of acetic acid on properties of coconut shell filled low density polyethylene composites. Indo J Chem 2010; 10: 334–340.

75.

Chung

T-J

Park

J-W

Lee

H-J

, et al. The improvement of mechanical properties, thermal stability, and water absorption resistance of an ecofriendly PLA/kenaf biocomposite using acetylation. Appl Sci 2018; 8: 1–13.

76.

Christian

Fidelis

Solomon

, et al. Study on chemical treatments of jute fiber for application in natural fiber reinforced composites (NFRPC). Int J Adv Eng Res Sci 2017; 4: 21–26.

77.

Karaduman

Gokcan

Onal

. Effect of enzymatic pretreatment on the mechanical properties of jute fiber-reinforced polyester composites. J Compos Mater 2012; 47: 1293–1302.

78.

Ortega

Morón

Monzón

, et al. Production of banana fiber yarns for technical textile reinforced composites. Materials 2016; 9: 1–16.

79.

Dong

Fan

, et al. Enzymatic hydrophobization of jute fabrics and its effect on the mechanical and interfacial properties of jute/PP composites. eXPRESS Polym Lett 2016; 10: 420–429.

80.

Jonn Foulk

Rho

Mercedes Alcock

, et al. Modifications caused by enzyme-retting and their effect on composite performance. Adv Mater Sci Eng 2011; 2011: 1–9.

81.

Cao

Chan

Chui

, et al. Characterization of flax fibres modified by alkaline, enzyme, and steam-heat treatments. Bioresources 2012; 7: 4109–4121.

82.

Siyamak

Ibrahim

Abdolmohammadi

, et al. Effect of fiber esterification on fundamental properties of oil palm empty fruit bunch fiber/poly (butylene adipate-co-terephthalate) biocomposites. Int J Mol Sci 2012; 13: 1327–1346.

83.

Agrawal

Saxena

Sharma

, et al. Activation and crystallization kinetics of untreated and treated oil palm fiber reinforced phenol formaldehyde composites. Mater Sci Eng A 2000; 277: 77–82.

84.

Tabil

Panigrahi

. Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. J Polym Environ 2007; 15: 25–33.

85.

Lakshmanan

Ghosh

Dasgupta

, et al. Optimization of alkali treatment condition on jute fabric for the development of rigid biocomposite. J Ind Text 2018; 47: 640–655.

86.

Pradeep Kushwaha

Kumar

. Effect of silanes on mechanical properties of bamboo fiber-epoxy composites. J Reinf Plast Compos 2010; 29: 718–724.

87.

Seki

Sarıkanat

Ezan

. Effect of siloxane treatment of jute fabric on the mechanical and thermal properties of jute/HDPE. J Reinf Plast Compos 2012; 31: 1009–1016.

88.

Ishikawaa

Takagib

Nakagaitob

, et al. Effect of surface treatments on the mechanical properties of natural fiber textile composites made by VaRTM method. Compos Interfaces 2014; 21: 329–336.

89.

Ramli

Yunus

Beg

MDH

, et al. Effects of coupling agent on oil palm clinker and flour-filled polypropylene composites. J Reinf Plast Compos 2011; 30: 431–439.

90.

Kim

K-J

. Modification of nano-kenaf surface with maleic anhydride grafted polypropylene upon improved mechanical properties of polypropylene composite. Compos Interfaces 2015; 22: 433–445.

91.

Fathi

Foruzanmehr

Elkoun

, et al. Novel approach for silane treatment of flax fiber to improve the interfacial adhesion in flax/bio epoxy composites. J Compos Mater 2019; 53: 2229–2238.

92.

Kurniawan

Kim

Lee

, et al. Towards improving mechanical properties of basalt fiber/polylactic acid composites by fiber surface treatments. Compos Interfaces 2015; 22: 553–562.

93.

Huang

Yin

, et al. Effects of fiber loading and chemical treatments on properties of sisal fiber-reinforced sheet molding compounds. J Compos Mater 2017; 51: 3175–3185.

94.

Rajini

Winowlin Jappes

Siva

, et al. Fire and thermal resistance properties of chemically treated ligno-cellulosic coconut fabric–reinforced polymer eco-nanocomposites. J Ind Text 2016; 47: 104–124.

95.

Goud

Rao

. Combined effect of alkali and silane treatments on tensile and impact properties of roystonea regia natural fiber reinforced epoxy composites. Appl Polym Compos 2013; 1: 187–196.

96.

Nishitani

Kajiyama

Yamanaka

. Effect of silane coupling agent on tribological properties of hemp fiber-reinforced plant-derived polyamide 1010 biomass composites. Materials 2017; 10: 1–21.

97.

Vinod Kumar

Chandrasekaran

Santhanam

, et al. Effect of coupling agent on mechanical properties of palm petiole nanofiber reinforced composite. Mater Sci Eng 2017; 183: 012006.

98.

Brum da Silva

Luz

Siva

, et al. Effect of silane treatment on the curaua fibre/polyester interface. Plast Rubber Compos 2019; 48: 160–167.

99.

Anyakora

. Combined effect of fibre loading and silane treatment on the flexural properties of oil palm empty fruit bunch reinforced composites. Int J Eng Res Gen Sci 2017; 5: 119–123.

100.

Bodur

Bakkai

Sonmez

. The effects of different chemical treatment methods on the mechanical and thermal properties of textile fiber reinforced polymer composites. J Compos Mater 2016; 50: 3817–3830.

101.

Atiqah

Jawaid

Sapuan

, et al. Physical properties of silane-treated sugar palm fiber reinforced thermoplastic polyurethane composites. Mater Sci Eng 2018; 368: 012047.

102.

Peng

Zeng

, et al. Regenerated thermosetting styrene-co-acrylonitrile sandwich composite panels reinforced by jute fibre: structures and properties. Bull Mater Sci 2016; 1: 109–117.

103.

Nourbakhsh

Kokta

Ashori

, et al. Effect of a novel coupling agent, polybutadiene isocyanate, on mechanical properties of wood-fiber polypropylene composites. J Reinf Plast Compos 2008; 27: 1679–1687.

104.

Hossain

Hasan

Md Hasan

, et al. Effect of chemical treatment on physical, mechanical and thermal properties of ladies finger natural fiber. Adv Mater Sci Eng 2013; 2013: 1–6.

105.

Madhua

Sanjay

Pradeepa

, et al. Characterization of cellulosic fibre from Phoenix pusilla leaves as potential reinforcement for polymeric composites. J Mater Test Technol 2019; 8: 2597–2604.

106.

Albinante

Elen Beatriz Pachecoa

Leila Viscontea

, et al. Modification of Brazilian natural fibers from banana’s tree to apply as fillers into polymers composites. Chem Eng Trans 2014; 37: 715–720.

107.

Bachtiar

Kurkowiak

Yan

, et al. Thermal stability, fire performance, and mechanical properties of natural fibre fabric-reinforced polymer composites with different fire retardants. Polymers 2019; 11: 1–16.

108.

Ooi

Ismail

Bakar

. The effect of hydrochloric acid treatment on properties of oil palm ash-filled natural rubber composites. Bioresources 2013; 8: 5133–5144.

109.

Nirmal

Saijod Lau

Hashim

. Interfacial adhesion characteristics of kenaf fibres subjected to different polymer matrices and fibre treatments. J Compos 2014; 2014: 1–12.

110.

Panigrahi

Tabil

. A study of flax fibre-reinforced polyethylene biocomposites. Appl Eng Agric 2009; 25: 525–531.

111.

Mishra

Misra

Tripathy

, et al. The influence of chemical surface modification on performance of sisal–polyester biocomposites. Polym Compos 2002; 23: 164–170.

112.

Ezema Ike-Eze

Aigbodion

Ude

, et al. Experimental study on the effects of surface treatment reagents on tensile properties of banana fiber reinforced polyester composites. J Mater Environ Sci 2019; 10: 402–410.

113.

Vinod

Vijay

Lenin Singaravelu

, et al. Characterization of untreated and alkali treated natural fibers extracted from the stem of Catharanthus roseus. Mater Res Express 2019; 6: 1–11.

114.

Satish Shenoy

Mahesha

Vijaya Kini

, et al. Effect of chemical treatments on hardness and toughness properties of Grewia serrulata reinforced polymer composites. J Mech Eng Res Develop 2019; 42: 228–230.

115.

Komal

Verma

Ashwani

, et al. Effect of chemical treatment on thermal, mechanical and degradation behavior of banana fiber reinforced polymer composites. J Nat Fibers 2018; 17: 1026–1038.

116.

Sahooa

Mohantya

Nayakb

, et al. Chemical treatment on rattan fibers: durability, mechanical, thermal, and morphological properties. J Nat Fibers. Epub ahead of print 28 November 2019. DOI: 10.1080/15440478.2019.1697995.

117.

Jaina

Sinhaa

Jain

. Compendious characterization of chemically treated natural fiber from pineapple leaves for reinforcement in polymer composites. J Nat Fibers. Epub ahead of print 8 September 2019. DOI: 10.1080/15440478.2019.1658256.

118.

Raajeshkrishna

Chandramohan

Saravanan

. Effect of surface treatment and stacking sequence on mechanical properties of basalt/glass epoxy composites. Polym Polym Compos 2018; 27: 201–214.

119.

Isadounene

Hammiche

Boukerrou

, et al. Accelerated ageing of alkali treated olive husk flour reinforced polylactic acid (PLA) biocomposites: physico-mechanical properties. Polym Polym Compos 2018; 26: 223–232.

120.

Shao

. Study on effect of surface treating method on mechanical behavior of three plant fiber reinforced polypropylene composites. Polym Polym Compos 2017; 25: 93–102.

121.

Hanana

Chimeni

Rodrigue

. Morphology and mechanical properties of maple reinforced LLDPE produced by rotational moulding: effect of fibre content and surface treatment. Polym Polym Compos 2018; 26: 299–308.

122.

Singh

JIP

Singh

Dhawan

. Effect of alkali treatment on mechanical properties of jute fiber-reinforced partially biodegradable green composites using epoxy resin matrix. Polym Polym Compos 2020; 28: 388–397.

123.

Bassyouni

. Dynamic mechanical properties and characterization of chemically treated sisal fiber-reinforced polypropylene biocomposites. J Reinf Plast Compos 2018; 37: 1402–1417.

124.

Dj Ladghem Chikouche

Merrouche

Azizi

, et al. Influence of alkali treatment on the mechanical properties of new cane fibre/polyester composites. J Reinf Plast Compos 2015; 16: 1329–1339.

125.

Fiore

Scalici

Valenza

. Effect of sodium bicarbonate treatment on mechanical properties of flax-reinforced epoxy composite materials. J Compos Mater 2017; 52: 1061–1072.

Influence of fibre pretreatments on characteristics of green fabric materials

Abstract

Keywords

Introduction

Alkali treatment

Acryl treatments

Peroxidation

Benzoylation

Acetyl treatments

Permanganate treatment

Enzymatic treatments

Effect of coupling agents

Other chemical treatments

Dimethylacetamide treatment

Polyhydroxybutyrate treatment

Chromium sulfate and sodium bicarbonate treatments

Stearic acid treatment

Fire-retardant treatments

Hydrochloric acid treatment

Sodium chlorite treatment

Comparison between treated and untreated green fibre composites

Conclusions

Footnotes

Declaration of conflicting interests

Funding

ORCID iD

References