Achieving synergistic viscosity and mechanical performance in Poly(aryl ether ketone) copolymers through bisphenol A-phenolphthalein side group ratio modulation

Abstract

Poly (aryl ether ketone) (PAEK) plays a critical role in the production and application of special engineering plastics. However, the traditional PAEK has some limitations in processing, such as high melt viscosity and high energy consumption. This study successfully synthesized a series of PAEK copolymers with bisphenol A and phenolphthalein side groups through nucleophilic polycondensation, aiming to reduce the high energy consumption associated with material processing. By adjusting the ratio of bisphenol A to phenolphthalein side groups, this research explores their influence on the properties of the copolymers. Comprehensive characterization using various testing methods revealed that increasing the bisphenol A content led to a decrease in heat deflection temperature and glass transition temperature. Although mechanical performance showed a slight decline, it remained comparable to other advanced engineering materials. Notably, tuning the ratio of bisphenol A to phenolphthalein significantly improved the melt rheological properties of the copolymers, reducing melt viscosity, enhancing polymer chain flexibility, decreasing crosslinking tendencies, broadening the processing window, and lowering energy consumption. This study provides a novel strategy for tailoring the performance of PAEK copolymers, offering substantial potential for further research and application. These copolymers are good candidates for next-generation high-performance engineering plastics.