Poly(ether-ketone)/fly ash (FA) composites reinforced with 0-30 wt% FA were fabricated using ball milling followed by hot compaction. The composites were investigated for mechanical and viscoelastic properties. Scanning electron microscopy revealed excellent dispersion and good adhesion of FA particles with the matrix. The addition of FA increased the microhardness by 70% and the storage modulus (below glass transition) by 75%. The reinforcing efficiency was better above the glass transition, which increased to around 177% at 250°C. This research indicates that the FA can be used as an alternative reinforcement of costly ceramic powder for the electronic packaging substrate or printed circuit board applications.
FinkJK. High performance polymers. In: FinkJK (ed). William Andrew. New York, USA: William Andrew, 2014, pp. 153–175.
2.
RaoVL. Polyether ketones. J Macromol Sci Part C1995; 35: 661–712.
3.
PadhanMMaratheUBijweJ. Tribology of Poly(etherketone) composites based on nano-particles of solid lubricants. Compos B Eng2020; 201: 1–20.
4.
PatkiAMGoyalRK. Investigation of non-isothermal crystallization, dynamic mechanical and dielectric properties of poly(ether-ketone) matrix composites. Polym Technol Mater2020; 00: 1–14.
5.
KumarMKumarAGoyalRK, et al.A novel approach of fabricating low-cost high temperature printed circuit board substrate based on poly ( ether-ketone )/fly ash composites. J Mater Sci Mater Electron2023; 1238: 1–15.
6.
BijweJSharmaSSharmaM, et al.Exploration of potential of solid lubricants and short fibers in Polyetherketone (PEK) composites. Wear2013; 301: 810–819.
7.
GoyalRKTiwariANUpM, et al.Effect of aluminum nitride on thermomechanical properties of high performance PEEK. Compos Part A Appl Sci Manuf2007; 38: 516–524.
8.
GoyalRKAgrawalRBhargavaAK. Poly(ether-ketone) (PEK)/ceramic nanocomposites as alternate materials for printed circuit board application. Polym Technol Mater2022; 61: 471–481.
9.
DravidSVBhosaleSDDatarS, et al.Nickel nanoparticle-filled high-performance polymeric nanocomposites for EMI shielding applications. J Electron Mater2020; 49: 1630–1637.
10.
PatkiAMGoyalRK. High performance polyetherketone-hexagonal boron nitride nanocomposites for electronic applications. J Mater Sci Mater Electron2019; 30: 3899–3908.
11.
BhattAPriyadarshiniSAcharath MohanakrishnanA, et al.Physical, chemical, and geotechnical properties of coal fly ash: a global review. Case Stud Constr Mater2019; 11: e00263.
12.
YangYFGaiGSCaiZF, et al.Surface modification of purified fly ash and application in polymer. J Hazard Mater2006; 133: 276–282.
13.
RayDBhattacharyaDMohantyAK, et al.Static and dynamic mechanical properties of vinylester resin matrix composites filled with fly ash. Macromol Mater Eng2006; 291: 784–792.
14.
ReddyBRSrinivasC. Fabrication and characterization of silicon carbide and fly ash reinforced aluminium metal matrix hybrid composites. Mater Today Proc2018; 5: 8374–8381.
15.
AnandhanS. Recent trends in fly ash utilization in polymer composites. Int J Waste Resour2014; 04: 3–4.
16.
SinglaMChawlaV. Mechanical properties of epoxy resin – fly ash composite. J Miner Mater Charact Eng2010; 09: 199–210.
17.
KimYHwangSChoiJ, et al.Valorization of fly ash as a harmless flame retardant via carbonation treatment for enhanced fire-proofing performance and mechanical properties of silicone composites. J Hazard Mater2021; 404: 124202.
18.
AhmaruzzamanM. A review on the utilization of fly ash. Prog Energy Combust Sci2010; 36: 327–363.
19.
ŠešlijaMRosićARadovićN, et al.Laboratorijska ispitivanja elektrofilterskog pepela. Teh Vjesn2016; 23: 1839–1848.
20.
KosmatkaSHWilsonML. Design and control of concrete mixtures – The guide to applications, methods and materials. Illinois, USA, 2011.
21.
KasarAKGuptaNRohatgiPK, et al.A brief review of fly ash as reinforcement for composites with improved mechanical and tribological properties. Jom2020; 72: 2340–2351.
22.
MeyersRA.Encyclopedia of sustainability science and technology. New York, USA, 2012. Epub ahead of print2012. DOI: 10.1007/978-1-4419-0851-3
23.
BhagatSRMahajanL. Thermal power plant waste by-product and its utility in concrete. IOP Conf Ser Mater Sci Eng2020; 970, Epub ahead of print 2020. DOI: 10.1088/1757-899X/970/1/012010
24.
YousufAManzoorSOYoussoufM. Fly ash : production and utilization in India - an overview. J Mater Environ Sci2020; 11: 911–921.
25.
RaghavendraGOjhaSKumar AcharyaS, et al.Fabrication and characterization of nano Fly ash by planetary ball Milling. Artic Int J Mater Sci Innov2014; 2: 59–68.
26.
Central Electricity Authority. Report on fly ash generation at coal/lignite based thermal power stations and its utilization in the country for the year 2021-22. Minist Power, Gov India, 2022, pp. 1–97.
27.
FerreiraCRibeiroAOttosenL. Possible applications for municipal solid waste fly ash. J Hazard Mater2003; 96: 201–216.
28.
DindiAQuangDVVegaLF, et al.Applications of fly ash for CO2 capture, utilization, and storage. J CO2 Util2019; 29: 82–102.
29.
GeJCYoonSKChoiNJ. Application of fly ash as an adsorbent for removal of air and water pollutants. Appl Sci2018; 8, Epub ahead of print 2018. DOI: 10.3390/app8071116
30.
RohatgiPKWeissDGuptaN. Applications of fly ash in synthesizing low-cost MMCs for automotive and other applications. JOM2006; 58: 71–76.
31.
JoshiMDGoyalAPatilSM, et al.Tribological and thermal properties of hexagonal boron nitride filled high-performance polymer nanocomposites. J Appl Polym Sci2016; 133: 1–9.
QiaoJAmirkhiziAVSchaafK, et al.Dynamic mechanical analysis of fly ash filled polyurea elastomer. J Eng Mater Technol Trans ASME2011; 133, Epub ahead of print 2011. DOI: 10.1115/1.4002650
34.
SandlerJWernerPShafferMSP, et al.Carbon-nanofibre-reinforced poly(ether ether ketone) composites. Compos Part A Appl Sci Manuf2002; 33: 1033–1039.
35.
GaikwadSDDravidSVSonawaneBU, et al.Dynamic mechanical and creep properties of poly(ether ketone)-graphite nanoplatelet (GNP) nanocomposites. Polym Plast Technol Mater2019; 58: 1691–1701.
36.
IshidaHRimdusitS. Very high thermal conductivity obtained by boron nitride-filled polybenzoxazine. Thermochim Acta1998; 320: 177–186.
37.
ArzakAEguiazábalJINazábalJ. Effect of annealing on the properties of poly(ether ether ketone). Polym Eng Sci1991; 31: 586–591.
38.
CebeP. Annealing study of poly(etheretherketone). J Mater Sci1988; 23: 3721–3731.
39.
MohammedAAAl-HassaniESOleiwiJK, et al.The effect of annealing on the behavior of polyetheretherketone composites compared to pure titanium. Mater Res Express2019; 6: 0–22.
40.
HegdeSPuchaRVSitaramanSK. Enhanced reliability of High-Density Wiring (HDW) substrates through new base substrate and dielectric materials. J Mater Sci Mater Electron2004; 15: 287–296.
41.
GoyalRKTiwariANUpM, et al.Thermal, mechanical, and dielectric properties of high performance PEEK/AlN nanocomposites. J Nanosci Nanotechnol2009; 9: 6902–6909.
42.
GoyalRKJagadalePAMulikUP. Thermal, mechanical, and dielectric properties of polystyrene/expanded graphite nanocomposites. J Appl Polym Sci2008; 111: 2071–2077.
43.
GoyalRKTiwariANNegiYS. Role of interface on dynamic modulus of high- performance poly(etheretherketone)/ceramic composites. J Appl Polym Sci2010; 121: 436–444.
44.
WypychG. PEK polyetherketone. In: Handbook of Polymers, 2016, pp. 377–379.
45.
LiRWangLYangT, et al.Investigation of MSWI fly ash melting characteristic by DSC-DTA. Waste Manag2007; 27: 1383–1392.
46.
WangWLuCLiY, et al.An investigation on thermal conductivity of fly ash concrete after elevated temperature exposure. Constr Build Mater2017; 148: 148–154.
47.
SinghKQuaziTUpadhyayS, et al.Development of low permittivity material using fly ash. Indian J Eng Mater Sci2005; 12: 345–350.
