Synthesis and characterization of new aromatic copoly(ether amide)s bearing 4-trifluoromethylphenyl-2,6-diphenylpyridyl moieties in the main chain

Abstract

A series of new aromatic fluorinated copoly(ether amide)s containing 4-(4-trifluoromethylphenyl)-2,6-diphenylpyridyl moiety with high molecular weight were prepared by a low-temperature solution polycondensation of terephthaloyl chloride with 4-(4-trifluoromethylphenyl)-2,6-bis(4-aminophenyl)pyridine and 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene with various mole ratios of the two monomers ranged from 20/80 to 80/20. All polymers were amorphous and soluble in common organic solvents such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide and tetrahydrofuran at room temperature or upon heating at 70^oC, and could be solution cast into transparent, tough, and flexible films with tensile strengths of 66.9–80.2 MPa, tensile moduli of 1.84–2.03 GPa, and elongations at break of 11.8–20.7%. These new polyamides displayed good thermal stability with gradually increasing of glass temperatures of 259–285^oC as an increase of the 4-(4-trifluoromethylphenyl)-2,6-diphenylpyridyl component, the temperature at 10% weight loss of 476–505^oC, and the residue of 55–61% at 750^oC in nitrogen. They also exhibited low dielectric constants of 3.11–3.38 (1 MHz), low moisture absorption in the range of 1.43–1.75%, and high transparency with an UV–vis absorption cut-off wavelength in the 350–368 nm range.