In this article, polyimide (PI) composite films reinforced by graphitic carbon nitride (g-C3N4) have been synthesized using the in situ polymerization process via thermal imidization. Poly (amic acid) (PAA) solutions were prepared from pyromellitic dianhydride (PMDA) and 4,4′-(4,4′-isopropylidenediphenyl-1,1′-diyldioxy) dianiline (BAPP) in N,N-dimethylacetamide (DMAc) solvent. The different amounts of g-C3N4 obtained from the direct pyrolysis of dicyandiamide (DCDA) at 600°C were incorporated into PAA matrix, which formed g-C3N4/PI composite films by thermal imidization. The morphological structures of the synthesized g-C3N4 and g-C3N4/PI composite films were characterized using fourier transform infrared spectroscopy, x-ray diffraction, scanning electron microscopy and transmission electron microscopy. With 2 wt% g-C3N4 incorporated, the tensile strength and elongation at break of g-C3N4/PI composites were increased by about 23% and 21%, respectively, due to the strong interaction between the g-C3N4 particles and PI. Thermogravimetric analysis indicated that the incorporation of g-C3N4 improved the thermal stability of the PI at low g-C3N4 content. Besides, the dielectric and optical properties of these composites were also studied in this article.
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