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Abstract

High-molecular-weight poly(arylene ether kekone) (PAEK) containing 3-(trifluoromethyl) phenyl pendants and biphenyl units with a mole ratio of 3:7 (FP30-PEDEKK) has been synthesized by nucleophilic substitution copolymerization from 3-(trifluromethyl) phenylhydroquinone, 4,4′-biphenol, and 1,4-bis(p-flurobenzoyl) benzene. FP30-PEDEKK shows good mechanical strength and high thermal stability. The friction and wear behaviors of the copolymer were investigated on pin-on-disk tribological test method using UMT-2. Compared to poly(ether ether ketone) (PEEK), FP30-PEDEKK has better friction reduction property and more stable friction behavior, although it shows lower wear resistance. These results could be supported by the scanning electron microscope investigations which showed that FP30-PEDEKK did have smoother worn surface than PEEK under given conditions. From microscopic images and the evolution of the friction coefficient and specific wear rate, the wear mechanisms of FP30-PEDEKK were suggested. This work significantly highlights the potential of molecular design as a route toward the tribological development of PAEK.

Keywords

Poly(arylene ether ketone) (PAEK)biphenyl units friction reduction wear resistance

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References

Bhushan

. Introduction to tribology. New York, NY: Wiley Publishing, Inc, 2002.

Friedrich

Hager

. Recent advances in polymer composites tribology. Wear 1998; 190: 139–144.

Cotter

. Engineering plastics. Handbook of polyarylethers. Basel, Switzerland: Gordon & Breach, 1995.

Harsha

Tewari

. Tribo performance of polyaryletherketone composites. Polym Test 2002; 21: 697–709.

Stolarski

. Tribology of poly ether ether ketone. Wear 1992; 158: 71–78.

Stuart

. Tribological studies of poly(ether ether ketone) blends. Tribol Int 1998; 31: 647–651.

Akagaki

. Tribological properties and applications of PEEK material. Tribologist 2006; 52: 126–131.

Geringer

Tatkiewicz

Rouchouseb

. Wear behavior of PAEK, poly(aryl-ether-ketone), under physiological conditions, outlooks for performing these materials in the field of hip prosthesis. Wear 2011; 271: 2793–2803.

Laux

Schwartz

. Effects of contact pressure, molecular weight, and supplier on the wear behavior and transfer film of polyetheretherketone (PEEK). Wear 2013; 297: 919–925.

10.

Zhang

Liao

Cherigui

. Effect of crystalline structure on the hardness and interfacial adherence of flame sprayed poly (ether–ether–ketone) coatings. Eur Polym J 2007; 43: 1077–1082.

11.

Friedeich

. On sliding friction and wear of PEEK and its composites. Wear 1995; 181-183: 624–631.

12.

Chiu

Vail

Barry

. Design of low wear polymer composites. Tribol Lett 2012; 45: 79–87.

13.

Jia

Chen

Zhou

. Comparative study on tribological behaviors of polyetheretherketone composite reinforced with carbon fiber and polytetrafluoroethylene under water-lubricated and dry-sliding against stainless steel. Tribol Lett 2004; 17: 231–238.

14.

Wang

Xue

Liu

. Tribological characteristics of nanometer Si₃N₄ filled poly (ether ether ketone) under distilled water lubrication. J Appl Poly Sci 2001; 79: 1394–1400.

15.

Long

Wang

. Wear and mechanical properties of Ekonol/G/MoS2/PEEK composites. J Mater Sci 2004; 39: 1499–1501.

16.

Sharma

Bijwe

Mitschang

. Abrasive wear studies on composites of PEEK and PES with modified surface of carbon fabric. Tribol Int 2011; 44: 81–91.

17.

Xie

Sui

Yang

. Effects of potassium titanate whiskers and carbon fibers on the wear behavior of poly ether ether ketone composite under water lubricated condition. Compos Sci Technol 2011; 71: 828–835.

18.

Zhang

Schlarb

. Correlation of the tribological behaviors with the mechanical properties of poly-ether-ether-ketones (PEEKs) with different molecular weights and their fiber filled composites. Wear 2009; 266: 337–344.

19.

Francisco-José

Ginés

Patricia

. Liquid crystals in tribology. Int J Mol Sci 2009;10: 4102–4115.

20.

Hanchi

Eiss

. Preliminary study of the elevated temperature tribological behaviour of poly(ether ether ketone)-based in situ composites under unlubricated sliding conditions. Tribol Trans 1995; 38: 305–310.

21.

Hanchi

Eiss

. Tribological behaviour of poly(ether ether ketone), a thermotropic liquid crystalline polymer and in situ composites based on their blends under dry sliding conditions at elevated temperatures. Wear 1996; 200: 105–121.

22.

Liu

Wang

. Poly (aryl ether ketone)s with (3-Methyl)phenyl and (3-Trifluoromethyl) phenyl Side groups. J Polym Sci: Pol Chem 2002; 40: 3392–3398.

23.

Wang

Jiang

Zhang

. Synthesis and characterization of thermotropic liquid crystalline poly(aryl ether ketone) copolymers with pendant 3-(trifluoromethyl) phenyl groups. Polym Int 2006; 55: 657–661.

24.

Wang

. Fluoro-poly(aryl ether ketone). China: Jilin University, 2000.

25.

Hutching

. Tribology: friction and wear of engineering materials. London, UK: CRC Press, 1992.

Investigations on the tribological properties of poly(arylene ether ketone) copolymer with 3-(trifluoromethyl) phenyl pendants and biphenyl units

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