A novel kind of resin poly(diethynylbenzene-siloxane) was synthesized. The resin was easily processable at room temperature and thermally polymerized above 180 °C to form a heat-resistant thermoset. The progress and the nature of polymerization reaction were studied by Fourier transform Infrared spectrometry and differential scanning calorimetry. The conversion of the resin to a highly cross-linked thermoset was discussed. The cross-linked resin exhibited high thermal stability. The sintered product of the crosslinked resin above 1450 °C was analyzed by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectrometry.
BacqueEPillotJP.New poly(carbosilane) models. 4. Derivatization of linear poly[(methylchlorosilylene)methylene]: application to the synthesis of functional poly(carbosilanes) possessing a poly[(methylsilylene)methylene] backbone. Chem Mater1991; 3: 348–355.
2.
ThomasJBSinaIMPangY.Thermal and catalytic polymerization of diethynyldiphenylsilane. Macromolecules1991; 24: 1257–1260.
3.
BrunoBRobertJP.Poly(carbosilane) precursors of silicon carbide: the effect of cross-linking on ceramic residue. Chem Mater1991; 3: 487–489.
4.
CorriuRGerbierPhJ. . Pyrolysis of poly[(silylene)diacetylenes]: Direct evidence between their morphology and thermal behavior. J. Organometallic Chemistry1993; 449: 111–118.
5.
KurokiSOkitaK.Thermosetting Mechanism Study of Poly[(phenylsilylene)ethynylene-1,3-phenyleneethynylene] by Solid-State NMR Spectroscopy and Computational Chemistry. Macromolecules1998; 31: 2804–2808.
6.
CorriuRJPGerbierP.Organosilicon polymers: pyrolysis chemistry of poly[(dimethylsilylene)diacetylene]. Organometallics1992; 11: 2507–2513.
7.
UnnikrishnanaKPThachilbET.Hybrid polymer networks of epoxy resin and substituted phenolic novolacs. Int J Polym Mater2006; 55: 563–576.
8.
ZikryaAAF. Dielectric behavior of silica/polyacrylamide nanocomposites. Int J Polym Mater2008; 57: 383–395.
9.
SunaJZhangaQGuaJPreparation and characterization of polyimide-silica hybrid thin films. Polym Plast Technol Eng2010; 49: 250–253.
BouillonEPaillerR. New poly(carbosilane) models. 5. Pyrolysis of a series of functional poly(carbosilanes). Chem Mater1991; 3: 356--367.
12.
RobertJPWilliamED. Preparation of diphenylsilylene polymers containing main-chain acetylene and (hetero)aromatic groups: X(2) Non-linear optical and other properties. J Organometal Chem1993; 445: 69–76.
13.
LiuHQHarrodJF. Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes. Can J Chem1990; 68: 1100–1105.
14.
BrefortJLCorriuR. New poly[(silylene)diacetylenes] and poly[(germylene)diacetylenes]: synthesis and conductive properties. J Organometal1992; 11: 2500–2506.
ItohMInoueK. A Novel Synthesis and Extremely High Thermal Stability of Poly[(phenylsilylene)ethynylene-1,3-phenyleneethynylene]. Macromolecules1994; 27: 7917–7919.
17.
BenfieldREBudnikUNiklasT.Synthesis and characterization of poly[(silylene)arylene] statistical copolymers. Polymer1996; 37: 5761–5764.
18.
YamashitaHLeonMSChannasanonS.Palladium-catalyzed hydrosilylation polymerization of dihydrosilanes with diynes affording silylene-divinylene polymers. Polymer2003; 44: 7089–7093.
19.
RuiWWeiLLeiF.Synthesis, characterization, and properties of novel phenylene-silazane-acetylene polymers. Polymer2010; 51: 5970–5976.
20.
YeLHanWJZhangRLSynthesis, characterization, and properties of silylene–acetylene preceramic polymers. J Appl Polym Sci2008; 110: 4064–4070.
21.
WangMC, Yang M and Zhao T. Propargyl silicon-cyclopentadiene oligomeric resin with high temperature resistance. Polym Adv Technol2008; 19: 1822–1827.
22.
SonDYKellerTM. Synthesis and Characterization of Linear Siloxane-Diacetylene Polymers. Macromolecules1995; 28: 399–400.
23.
BurilloG. Studies on diacetylenic vinyl compounds. Polym Bull1986; 16: 257–262.
24.
SundarRAKellerTM. Linear diacetylene polymers containing bis(dimethylsilyl) phenyl and/or bis-(tetramethyldisiloxane) carborane residues: Their synthesis, characterization and thermal and oxidative properties. J Polym Sci Part A: Polym Chem1997; 35: 2387–2394.
25.
HomrighausenCLKellerTM.Synthesis and characterization of a silarylene–siloxane–diacetylene polymer and its conversion to a thermosetting plastic, Polymer2002; 43: 2619–2623.
26.
HendersonLJKellerTM. Synthesis and Characterization of Poly(carborane-siloxane-acetylene). Macromolecules1994; 27: 1660–1661.
27.
BuccaDKellerTM. Thermally and oxidatively stable thermosets derived from preceramic monomers. J Polym Sci Part A: Polym Chem1997; 35: 1033–1038.
28.
BuccaDKellerTM. Oxidation-resistant thermosets derived from thermal copolymerization of acetylenic monomers containing boron and silicon. J Polym Sci Part A: Polym Chem1999; 37: 4356–4359.
ParnellDR and Macaione DP. Oxidative coupling as a potential route to polymers of group IV acetylenes. J Polym Sci Polym Chem Ed1973; 11: 1107–1110.
31.
WangFZhangJHuangJXSynthesis and Characterization of Poly(dimethylsilylene ethynylenephenyleneethynylene) Terminated with Phenylacetylene. Polym Bull2006; 56: 19–26.
