The unique properties of ZrB2-based ceramics are suitable for ultra-high temperature structural applications such as re-entry space vehicles, hypersonic vehicles, and propulsion systems. Monolithic ZrB2 is associated with challenges during processing and sintering, limiting its widespread application, in addition, its physical and mechanical properties degrade at above 1200 °C due to its critical oxidation resistance. These problems are partially addressed by adding carbides, like SiC and ZrC, into ZrB2 ceramic. The synthesis and sintering of ZrB2-based ceramics are much more accessible than monolithic ZrB2, resulting in overall better performance. The present review focuses on the processing route and sintering techniques of ZrB2-based binary, ternary ceramics and composite and their effect on physical and mechanical properties. Also, novel advanced processing and fabrication techniques of ZrB2-based materials are mentioned. This research article tackles the drawbacks and challenges present in the existing literature and how a sustainable approach can rectify these issues.
GollaBRMukhopadhyayABasuB, et al.Review on ultra-high temperature boride ceramics. Prog Mater Sci2020; 111: 100651.
2.
BinnerJPorterMBakerB, et al.Selection, processing, properties and applications of ultra-high temperature ceramic matrix composites, UHTCMCs – a review. Int Mater Rev2020; 65: 389–444.
3.
FahrenholtzWGHilmasGETalmyIG, et al.Refractory diborides of zirconium and hafnium. J Am Ceram Soc2007; 90: 1347–1364.
4.
FahrenholtzWGHilmasGE. Oxidation of ultra-high temperature transition metal diboride ceramics. Int Mater Rev2012; 57: 61–72.
5.
GuoSQ. Densification of ZrB2-based composites and their mechanical and physical properties: a review. J Eur Ceram Soc2009; 29: 995–1011.
6.
SonberJKSuriAK. Synthesis and consolidation of Zirconium diboride: review. Adv Appl Ceram2011; 110: 321–334.
7.
WuchinaEOpilaEOpekaM, et al.UHTCs: ultra-high temperature ceramic materials for extreme environment applications. Electrochem Soc Interface2007; 16: 30–36.
8.
KrishnaraoRVSankarasubramanianR. Thermite assisted synthesis of ZrB2 and ZrB2–SiC through B4C reduction of ZrO2 and ZrSiO4 in air. J Adv Ceram2017; 6: 139–148.
9.
MaBLiJ. ZrB2-SiC-ZrC coating on ZrC ceramics deposited by plasma spraying. Results Phys2019; 15: 102550.
10.
NorasetthekulSEubankPTBradleyWL, et al.Use of zirconium diboride-copper as an electrode in plasma applications. J Mater Sci1999; 34: 1261–1270.
11.
LevineSROpilaEJHalbigMC, et al.Evaluation of ultra-high temperature ceramics for aeropropulsion use. J Eur Ceram Soc200; 2:275–276.
12.
BlumYDMarschallJHuiD, et al.Thick protective UHTC coatings for sic-based structures: process establishment. J Am Ceram Soc2008; 91: 1453–1460.
13.
CorralELLoehmanRE. Ultra-high-temperature ceramic coatings for oxidation protection of carbon-carbon composites. J Am Ceram Soc2008; 91: 1495–1502.
14.
GuriaJFBansalAKumarV. Effect of additives on the thermal conductivity of zirconium diboride based composites – A review. J Eur Ceram Soc2021; 41: 1–23.
15.
LiHZhangLZengQ, et al.Crystal structure and elastic properties of ZrB compared with ZrB2: a first-principles study. Comput Mater Sci2010; 49: 814–819.
16.
ChakrabortySDasPKGhoshD. Spark plasma sintering and structural properties of ZrB2 based ceramics: a review. Rev Adv Mater Sci2016; 44: 182–193.
17.
ZhangGJNiDWZouJ, et al.Inherent anisotropy in transition metal diborides and microstructure/property tailoring in ultra-high temperature ceramics—A review. J Eur Ceram Soc2018; 38: 371–389.
18.
CacciamaniGRianiPValenzaF. Equilibrium between MB2 (M = ti,zr,hf) UHTC and Ni: a thermodynamic database for the BHfNiTiZr system. Calphad Comput Coupling Phase Diagrams Thermochem2011; 35: 601–619.
19.
KumariJTiwariMSinghA, et al.Effect of different carbon and silicon source for the preparation of ZrB2-SiC composite powder: a comparative study. Silicon2023; 15: 6833–6841.
20.
JyotiTiwariMKumarV. Influence of SiC content to control morphology of in-situ synthesized ZrB2 – SiC composite through single-step reduction process. Vacuum2022; 203: 1–10.
21.
JyotiTiwari M.SinghAKumarV. Effect of SiC on ablation mechanism and morphological evolution of in situ synthesized ZrB2 – SiC composites. Mater Chem Phys2023; 297: 1–11.
22.
PengFSpeyerRF. Oxidation resistance of fully dense ZrB2 with SiC, TaB 2, and TaSi2 additives. J Am Ceram Soc2008; 91: 1489–1494.
23.
InoueRAraiYKubotaY. Oxidation behaviors of ZrB2–SiC binary composites above 2000 °C. Ceram Int2017; 43: 8081–8088.
24.
KashyapSKMitraR. Densification behavior involving creep during spark plasma sintering of ZrB2-SiC based ultra-high temperature ceramic composites. Ceram Int2020; 46: 5028–5036.
25.
DasJSurajPKumarDSS, et al.Microstructure and mechanical properties of hot pressed ZrB2-20SiC composite. Int J Refract Met Hard Mater2017; 69: 49–59.
26.
Shahedi AslMGhassemi KakroudiM. Fractographical assessment of densification mechanisms in hot pressed ZrB2-SiC composites. Ceram Int2014; 40: 15273–15281.
27.
ZhangZShaJDaiJ, et al.Enhanced fracture properties of ZrB2 -based composites by in-situ grown SiC nanowires. Adv Appl Ceram2019; 118: 137–144.
28.
ScitiDGuicciardiSSilvestroniL. Sic chopped fibers reinforced ZrB2: effect of the sintering aid. Scr Mater2011; 64: 769–772.
29.
MonteverdeFBellosiA. Development and characterization of metal-diboride-based composites toughened with ultra-fine SiC particulates. Solid State Sci2005; 7: 622–630.
30.
SilvestroniLFaillaSNeshporI, et al.Method to improve the oxidation resistance of ZrB2-based ceramics for reusable space systems. J Eur Ceram Soc2018; 38: 2467–2476.
31.
ScitiDMonteverdeFGuicciardiS, et al.Microstructure and mechanical properties of ZrB2-MoSi2 ceramic composites produced by different sintering techniques. Mater Sci Eng A2006; 434: 303–309.
32.
ScitiDGuicciardiSBellosiA, et al.Properties of a pressureless-sintered ZrB2-MoSi2 ceramic composite. J Am Ceram Soc2006; 89: 2320–2322.
33.
ScitiDBrachMBellosiA. Oxidation behavior of a pressureless sintered ZrB2-MoSi2 ceramic composite. J Mater Res2005; 20: 922–930.
GuoSNishimuraTKagawaY. Low-temperature hot pressing of ZrB2-based ceramics with ZrSi2 additives. Int J Appl Ceram Technol2011; 8: 1425–1435.
36.
GuoSQKagawaYNishimuraT, et al.Pressureless sintering and physical properties of ZrB2-based composites with ZrSi2 additive. Scr Mater2008; 58: 579–582.
37.
GuoSQKagawaYNishimuraT. Mechanical behavior of two-step hot-pressed ZrB2-based composites with ZrSi2. J Eur Ceram Soc2009; 29: 787–794.
38.
GuoWMYangZGZhangGJ. High-temperature deformation of ZrB2 ceramics with WC additive in four-point bending. Int J Refract Met Hard Mater2011; 29: 705–709.
39.
MonteverdeFSilvestroniL. Combined effects of WC and SiC on densification and thermo-mechanical stability of ZrB2 ceramics. Mater Des2016; 109: 396–407.
40.
BinMHManZYLiuJX, et al.Microstructures, solid solution formation and high-temperature mechanical properties of ZrB2 ceramics doped with 5vol.% WC. Mater Des2015; 81: 133–140.
41.
ShimSHNiiharaKAuhKH, et al.Crystallographic orientation of ZrB2-ZrC composites manufactured by the spark plasma sintering method. J Microsc2002; 205: 238–244.
42.
LiQDongSWangZ, et al.Fabrication and properties of 3-D Cf/ZrB2-ZrC-SiC composites via polymer infiltration and pyrolysis. Ceram Int2013; 39: 5937–5941.
43.
ScitiDGuicciardiSNygrenM. Spark plasma sintering and mechanical behaviour of ZrC-based composites. Scr Mater2008; 59: 638–641.
44.
JyotiTiwariMSinghA, et al.The microstructural and mechanical behavior of in-situ synthesized ZrB2–ZrC and ZrB2–SiC–ZrC composites: A comparative study. Vacuum2024; 214: 1–11.
45.
GropyanovVMBel’tyukovaLM. Sintering and recrystallization of ZrC-ZrB2 compacts. Sov Powder Metall Met Ceram1968; 7: 527–533.
46.
MitraRUpenderSMallikM, et al.Mechanical, thermal, and oxidation behaviour of zirconium diboride based ultra-high temperature ceramic composites. Key Eng Mater2009; 395: 55–68.
47.
MashhadiIFMashhadiM. Pressureless Sintering & Mechanical & Thermal Properties of ZrB2-ZrC-SiC Nanocomposite. J Adv Mater Eng2021; 39: 115–129.
48.
RanSVan Der BiestOVleugelsJ. Zrb2 powders synthesis by borothermal reduction. J Am Ceram Soc2010; 93: 1586–1590.
49.
GuoWMZhangGJ. New borothermal reduction route to synthesize submicrometric ZrB2 powders with low oxygen content. J Am Ceram Soc2011; 94: 3702–3705.
50.
GuoWMTanDWZhangZL, et al.Synthesis of fine ZrB2 powders by new borothermal reduction of coarse ZrO2 powders. Ceram Int2016; 42: 15087–15090.
51.
WangYWuYWuK, et al.Effect of NaCl on synthesis of ZrB2 by a borothermal reduction reaction of ZrO2. Int J Miner Metall Mater2019; 26: 831–838.
52.
LiuQYSunSKZengLY, et al.Improvement of sinterability and mechanical properties of ZrB2 ceramics by the modified borothermal reduction methods. J Eur Ceram Soc2020; 40: 3844–3850.
53.
JungEYKimJHJungSH, et al.Synthesis of ZrB2 powders by carbothermal and borothermal reduction. J Alloys Compd2012; 538: 164–168.
54.
ZhaoHHeYZongzheJ. Preparation of zirconium boride powder. J Am Ceram Soc1995; 78: 2534–2536.
55.
GhelichRAghdamRMTorknikFS, et al.Carbothermal reduction synthesis of ZrB2 nanofibers via pre-oxidized electrospun zirconium n-propoxide. Ceram Int2015; 41: 6905–6911.
56.
GuoWMZhangGJ. Reaction processes and characterization of ZrB2 powder prepared by boro/carbothermal reduction of ZrO2 in vacuum. J Am Ceram Soc2009; 92: 264–267.
57.
ZhangGJGuoWMNiDW, et al.Ultrahigh temperature ceramics (UHTCs) based on ZrB2 and HfB2 systems: Powder synthesis, densification and mechanical properties. J Phys Conf Ser2009; 176: 1–11.
58.
QiuHYGuoWMZouJ, et al.Zrb2 powders prepared by boro/carbothermal reduction of ZrO 2: the effects of carbon source and reaction atmosphere. Powder Technol2012; 217: 462–466.
59.
KrishnaraoRV. Preparation of ZrB2 and ZrB2-SiC powders in a single step reduction of zircon (ZrSiO4) with B4C. Ceram Int2017; 43: 1205–1209.
60.
AnGSHanJSHurJU, et al.Synthesis of sub-micro sized high purity zirconium diboride powder through carbothermal and borothermal reduction method. Ceram Int2017; 43: 5896–5900.
61.
ChenZZhaoXLiM, et al.Synthesis of rod-like ZrB2 crystals by boro/carbothermal reduction. Ceram Int2019; 45: 13726–13731.
62.
SonberJKMurthyTSRCSubramanianC, et al.Investigations on synthesis of ZrB2 and development of new composites with HfB2 and TiSi2. Int J Refract Met Hard Mater2011; 29: 21–30.
63.
VelashjerdiMSarpoolakyHMirhabibiA. Novel synthesis of ZrB2 powder by low temperature direct molten salt reaction. Ceram Int2015; 41: 12554–12559.
64.
MohammadVSarpoolakyHMirhabibiA. The effects of different molten salt composition on morphology and purity of ZrB2 powder obtained via direct molten salt reaction method. J Adv Mater Process2015; 3: 25–34.
65.
LiuJHuangZHuoC, et al.Low-Temperature rapid synthesis of rod-like ZrB2 powders by molten-salt and microwave co-assisted carbothermal reduction. J Am Ceram Soc2016; 99: 2895–2898.
66.
BaiLNiSJinH, et al.Zrb2 powders with low oxygen content: synthesis and characterization. Int J Appl Ceram Technol2018; 15: 508–513.
67.
VelashjerdiMSoleymaniMSarpoolakyH, et al.Formation pathway of plate-like ZrB2 particles via the molten salt synthesis method. Ceram Int2020; 46: 28639–28651.
68.
LiMKeCZhangJ. Synthesis of ZrB2 powders by molten-salt participating silicothermic reduction. J Alloys Compd2020; 834: 155062.
69.
MaJCaoSLiT, et al.Low-temperature preparation of h-ZrB2 crystallites in the air. Mater Sci Eng B Solid-State Mater Adv Technol2020; 261: –5.
70.
BaiLJinHLuC, et al.RF Thermal plasma-assisted metallothermic synthesis of ultrafine ZrB2 powders. Ceram Int2015; 41: 7312–7317.
71.
AkgünBÇamurluHETopkayaY, et al.Mechanochemical and volume combustion synthesis of ZrB2. Int J Refract Met Hard Mater2011; 29: 601–607.
72.
SetoudehNWelhamNJ. Formation of zirconium diboride (ZrB2) by room temperature mechanochemical reaction between ZrO2, B2O3 and Mg. J Alloys Compd2006; 420: 225–228.
73.
JalalyMBafghiMSTamizifarM, et al.An investigation on the formation mechanism of nano ZrB2 powder by a magnesiothermic reaction. J Alloys Compd2014; 588: 36–41.
74.
NishiyamaKNakamurTUtsumiS, et al.Preparation of ultrafine boride powders by metallothermic reduction method. J Phys Conf Ser2009; 176: 1–8.
75.
ZhangSKhangkhamanoMZhangH, et al.Novel synthesis of ZrB2 powder via molten-salt-mediated magnesiothermic reduction. J Am Ceram Soc2014; 97: 1686–1688.
76.
YanYHuangZDongS, et al.New route to synthesize ultra-fine zirconium diboride powders using inorganic-organic hybrid precursors. J Am Ceram Soc2006; 89: 3585–3588.
77.
XieYSandersTHSpeyerRF. Solution-based synthesis of submicrometer ZrB2 and ZrB 2-TaB2. J Am Ceram Soc2008; 91: 1469–1474.
78.
YangLJZhuSZXuQ, et al.Synthesis of ultrafine ZrB2 powders by sol-gel process. Front Mater Sci China2010; 4: 285–290.
79.
ZhangYLiRJiangY, et al.Morphology evolution of ZrB2 nanoparticles synthesized by solgel method. J Solid State Chem2011; 184: 2047–2052.
80.
LiRZhangYLouH, et al.Synthesis of ZrB2 nanoparticles by sol-gel method. J Sol-Gel Sci Technol2011; 58: 580–585.
81.
YangBLiJZhaoB, et al.Synthesis of hexagonal-prism-like ZrB2 by a sol-gel route. Powder Technol2014; 256: 522–528.
82.
JiHYangMLiM, et al.Low-temperature synthesis of ZrB2 nano-powders using a sorbitol modified sol-gel processing route. Adv Powder Technol2014; 25: 910–915.
83.
JingLLeiEWangE, et al.Preparation and characterization of ultra-fine ZrB2 by sol-gel method. Key Eng Mater2014; 602–603: 122–125.
84.
TaoXYZhouSXXiangZM, et al.Fabrication of continuous ZrB2nanofibers derived from boron-containing polymeric precursors. J Alloys Compd2017; 697: 318–325.
85.
RadevDDMarinovM. Properties of titanium and zirconium diborides obtained by self-propagated high-temperature synthesis. J Alloys Compd1996; 244: 48–51.
86.
MishraSKDasSPathakLC. Defect structures in zirconium diboride powder prepared by self-propagating high-tempeture synthesis. Mater Sci Eng A2004; 364: 249–255.
87.
TsuchidaTYamamotoS. Mechanical activation assisted self-propagating high-temperature synthesis of ZrC and ZrB2 in air from Zr/B/C powder mixtures. J Eur Ceram Soc2004; 24: 45–51.
88.
ÇamurluHEMagliaF. Preparation of nano-size ZrB2 powder by self-propagating high-temperature synthesis. J Eur Ceram Soc2009; 29: 1501–1506.
89.
WuWWZhangGJSakkaY. Nanocrystalline ZrB2 powders prepared by mechanical alloying. J Asian Ceram Soc2013; 1: 304–307.
90.
RandichEAllredDD. Chemically vapor deposited ZrB2 as a selective solar absorber. Thin Solid Films1981; 83: 393–398.
91.
MotojimaSFunahashiKKurosawaK. Zrb2 coated on copper plate by chemical vapour deposition and its corrosion and oxidation stabilities. Metall Prot LAYERS 731990; 189: 73–79.
92.
WangAMaléG. Experimental investigation of the ZrBClH CVD system. J Eur Ceram Soc1993; 11: 241–251.
93.
ReichSSuhrHHankóK, et al.Deposition of thin films of zirconium and hafnium boride by plasma enhanced chemical vapor deposition. Adv Mater1992; 4: 38–39.
94.
PiersonJFBelmonteTCzerwiecT, et al.Low temperature ZrB2 remote plasma enhanced chemical vapor deposition. Thin Solid Films2000; 359: 68–76.
95.
WaydaALSchneemeyerLFOpilaRL. Low-temperature deposition of zirconium and hafnium boride films by thermal decomposition of the metal borohydrides (M[BH4]4). Appl Phys Lett1988; 53: 361–363.
96.
ChenLGuYYangZ, et al.Preparation and some properties of nanocrystalline ZrB2 powders. Scr Mater2004; 50: 959–961.
97.
ScitiDSilvestroniLSacconeG, et al.Effect of different sintering aids on thermo-mechanical properties and oxidation of SiC fibers - reinforced ZrB2 composites. Mater Chem Phys2013; 137: 834–842.
98.
Krishnarao RVAlamMZKumar DasD, et al.Synthesis of ZrB2-SiC composite powder in air furnace. Ceram Int2014; 40: 15647–15653.
99.
HeJGaoYWangY, et al.Synthesis of ZrB2-SiC nanocomposite powder via polymeric precursor route. Ceram Int2017; 43: 1602–1607.
100.
XieBYuJZhangY, et al.In situ synthesis of ZrB2–SiC composite powders by carbothermal reduction. CMC. Advanced Functional Materials: Springer Singapore, 2017.
101.
XieBMaLLinX, et al.Synthesis of ZrB2-SiC powders in one-step reduction process. Ceram Int2018; 44: 19522–19525.
102.
LiuJDuSLiF, et al.Preparation of ZrB2-SiC powders via carbothermal reduction of zircon and prediction of product composition by back-propagation artificial neural network. J Wuhan Univ Technol Mater Sci Ed2018; 33: 1062–1069.
103.
Nithin ChandranBSDevapalDPrabhakaranPV. Synthesis of zirconium diboride based ultra high temperature ceramics via preceramic route. Ceram Int2019; 45: 25092–25096.
104.
LiFTanCLiuJ, et al.Low temperature synthesis of ZrB2 -SiC powders by molten salt magnesiothermic reduction and their oxidation resistance. Ceram Int2019; 45: 9611–9617.
105.
LinYLiuJSongS, et al.Microstructure evolution and growth behavior of rod-shaped ZrB2 in situ preparation of ZrB2-SiC composite powders. Ceram Int2019; 45: 4016–4021.
106.
QiYJiangKZhouC, et al.Preparation and properties of high-porosity ZrB2-SiC ceramics by water-based freeze casting. J Eur Ceram Soc2021; 41: 2239–2246.
107.
AĝaoĝullariDGökçeHDumanI, et al.Characterization investigations of ZrB 2/ZrC ceramic powders synthesized by mechanical alloying of elemental Zr, B and C blends. J Eur Ceram Soc2012; 32: 1447–1455.
108.
AngCSeeberAWangK, et al.Modification of ZrB2 powders by a sol-gel ZrC precursor-A new approach for ultra high temperature ceramic composites. J Asian Ceram Soc2013; 1: 77–85.
109.
LiuCLiKLiH, et al.In situ synthesis mechanism of ZrB2-ZrC-C composites. Ceram Int2014; 40: 10297–10302.
110.
XuZZhaoKLiF, et al.The oxidation behavior of ZrB2–ZrC composite nanofibers fabricated by electrospinning and carbothermal reduction. Ceram Int2020; 46: 10409–10415.
111.
BaiLYuanFFangZ, et al.Rf thermal plasma synthesis of ultrafine ZrB2-ZrC composite powders. Nanomaterials2020; 10: 1–12.
112.
LicheriROrrùRMusaC, et al.Combination of SHS and SPS techniques for fabrication of fully dense ZrB2-ZrC-SiC composites. Mater Lett2008; 62: 432–435.
113.
QuQHanJHanW, et al.In situ synthesis mechanism and characterization of ZrB2-ZrC-SiC ultra high-temperature ceramics. Mater Chem Phys2008; 110: 216–221.
114.
TorabiONaghibiSGolabgirMH, et al.The effect of the mg content on mechanosynthesis of ZrB2–SiC–ZrC composite in the Mg/ZrSiO4/B2O3/C system. J Adv Mater Process2015; 3: 85–98.
115.
EmamiSMSalahiEZakeriM, et al.Synthesis of ZrB2-SiC-ZrC nanocomposite by spark plasma in ZrSiO4/B2O3/C/Mg system. Ceram Int2016; 42: 6581–6586.
116.
LiFHuangX. Preparation of highly porous ZrB2/ZrC/SiC composite monoliths using liquid precursors via direct drying process. J Eur Ceram Soc2018; 38: 1103–1111.
117.
LiFBaoWWeiX, et al.In-situ synthesis of porous ZrB2/ZrC/SiC ceramics decorated with SiC whiskers. Ceram Int2019; 45: 9313–9315.
118.
LiuCChangXWuY, et al.In-situ synthesis of ultra-fine ZrB2–ZrC–SiC nanopowders by sol-gel method. Ceram Int2020; 46: 7099–7108.
119.
LiuCZhangLYuanX, et al.Preparation of ZrB2-ZrC-SiC-ZrO2 nanopowders with in-situ grown homogeneously dispersed SiC nanowires. Mater Des2020; 196 (109186): 1–11.
120.
LiuCChangXWuY, et al.Effect of SiC content on microstructure evolution of ZrB2-ZrC-SiC ceramic in sol-gel process. Vacuum2020; 177: 109430.
121.
XuZLiFWangY, et al.Microstructure and oxidation resistance of ZrB2–ZrC–SiC composite nanofibers fabricated via electrospinning combined with carbothermal reduction. Ceram Int2021; 47: 20740–20744.
122.
XieBMaLGaoD, et al.Influence of SiC on phase and microstructure of ZrB2 powders synthesized via carbothermal reduction at different temperatures. Ceram Int2018; 44: 8795–8799.
123.
QiangQXinghongZSongheM, et al.Reactive hot pressing and sintering characterization of ZrB2 – SiC – ZrC composites. Mater Sci Eng A2008; 491: 117–123.
124.
WattsJHilmasGFahrenholtzWG. Mechanical characterization of ZrB2-SiC composites with varying SiC particle sizes. J Am Ceram Soc2011; 94: 4410–4418.
125.
ZhuSFahrenholtzWGHilmasGE. Influence of silicon carbide particle size on the microstructure and mechanical properties of zirconium diboride-silicon carbide ceramics. J Eur Ceram Soc2007; 27: 2077–2083.
126.
FahrenholtzWWattsJ. Data RUSA Method for toughening via the production of spiral architectures through powder loaded polymeric extrusion and toughened materials formed thereby. 2.
127.
EakinsEJayaseelanDDLeeWE. Toward oxidation-resistant ZrB2-SiC ultra high temperature ceramics. Metall Mater Trans A Phys Metall Mater Sci2011; 42: 878–887.
128.
SilvestroniLLandiEBejtkaK, et al.Oxidation behavior and kinetics of ZrB2 containing SiC chopped fibers. J Eur Ceram Soc2015; 35: 4377–4387.
129.
BullJWSan JoseCWhiteMJ, et al.Ablation resistant zirconium and hafnium ceramics. 1998: 1–8.
130.
LiuHLLiuJXBaoWC, et al.Interface characteristics in ZrB2-based ceramics containing SiC and/or ZrC particles via hot-pressing sintering. Mater Charact2021; 176: 111144.
131.
RezapourABalakZ. Fracture toughness and hardness investigation in ZrB2–SiC–ZrC composite. Mater Chem Phys2020; 241: 122284.
132.
Sabahi NaminiADelbariSAShahedi AslM, et al.Characterization of reactive spark plasma sintered (Zr,Ti)B2–ZrC–SiC composites. J Taiwan Inst Chem Eng2021; 119: 187–195.
133.
TelleR. Boride and Carbide Ceramics . Materials Science and Technology: A Comprehensive Treatment, The Classic Edition. Willy, 2006.
134.
ZouJMaHBD’AngioA, et al.Tungsten carbide: a versatile additive to get trace alkaline-earth oxide impurities out of ZrB2 based ceramics. Scr Mater2018; 147: 40–44.
135.
OhHCLeeSHChoiSC. Two-step reduction process and spark plasma sintering for the synthesis of ultra fine SiC and ZrB2 powder mixtures. Int J Refract Met Hard Mater2014; 42: 132–135.
136.
DengXDuSZhangH, et al.Preparation and characterization of ZrB2-SiC composite powders from zircon via microwave-assisted boro/carbothermal reduction. Ceram Int2015; 41: 14419–14426.
137.
CaoYZhangHLiF, et al.Preparation and characterization of ultrafine ZrB2-SiC composite powders by a combined sol-gel and microwave boro/carbothermal reduction method. Ceram Int2015; 41: 7823–7829.
138.
JalalyMTamizifarMBafghiMS, et al.Mechanochemical synthesis of ZrB2-SiC-ZrC nanocomposite powder by metallothermic reduction of zircon. J Alloys Compd2013; 581: 782–787.
139.
WangTZhangYLiJ, et al.Synthesis of ZrB2 and ZrB2-SiC powders using a sucrose-containing system. J Nanosci Nanotechnol2015; 15: 7402–7406.
140.
BaiLYuanFFangZ, et al.RF Thermal Plasma Synthesis of Ultrafine ZrB2-ZrC Composite Powders. Nanomaterials2020; 10 (12): 1–13.
141.
JalalyMBafghiMSTamizifarM, et al.The role of boron oxide and carbon amounts in the mechanosynthesis of ZrB2-SiC-ZrC nanocomposite via a self-sustaining reaction in the zircon/magnesium/boron oxide/graphite system. J Alloys Compd2014; 598: 113–119.
142.
ChamberlainALFahrenholtzWGHilmasGE. Pressureless sintering of zirconium diboride. J Am Ceram Soc2006; 89: 450–456.
143.
BrochuMGaunttBZimmerlyT, et al.Fabrication of UHTCs by conversion of dynamically consolidated Zr + B and Hf + B powder mixtures. J Am Ceram Soc2008; 91: 2815–2822.
144.
BrochuMGaunttBDBoyerL, et al.Pressureless reactive sintering of ZrB2 ceramic. J Eur Ceram Soc2009; 29: 1493–1499.
145.
YanYHuangZDongS, et al.Pressureless sintering of high-density ZrB2-SiC ceramic composites. J Am Ceram Soc2006; 89: 3589–3592.
146.
ZhuMWangY. Pressureless sintering ZrB2-SiC ceramics at low temperatures. Mater Lett2009; 63: 2035–2037.
147.
ZhangHYanYHuangZ, et al.Properties of ZrB2-SiC ceramics by pressureless sintering. J Am Ceram Soc2009; 92: 1599–1602.
148.
MashhadiMKhaksariHSafiS. Pressureless sintering behavior and mechanical properties of ZrB2-SiC composites: effect of SiC content and particle size. J Mater Res Technol2015; 4: 416–422.
149.
KrishnaraoRVBhanuprasadVVMadhusudhan ReddyG. Zrb2–SiC based composites for thermal protection by reaction sintering of ZrO2 + B4C + Si. J Adv Ceram2017; 6: 320–329.
150.
KalishDCloghertyEVKrederK. Strength, fracture mode, and thermal stress resistance of HfB2 and ZrB2. J Am Ceram Soc1969; 52: 30–36.
151.
KimHWKohYHKimHE. Reaction sintering and mechanical properties of B4C with addition of ZrO2. J Mater Res2000; 15: 2431–2436.
152.
NeumanEWHilmasGEFahrenholtzWG. Strength of zirconium diboride to 2300 °C. J Am Ceram Soc2013; 96: 47–50.
153.
NeumanEWHilmasGEFahrenholtzWG. Processing, microstructure, and mechanical properties of large-grained zirconium diboride ceramics. Mater Sci Eng A2016; 670: 196–204.
154.
LiuLHouZZhaoY, et al.Fabrication of ZrB2 ceramics by reactive hot pressing of ZrB and B. J Am Ceram Soc2018; 101: 5294–5298.
155.
ZhangGJDengZYKondoN, et al.Reactive hot pressing of ZrB2-SiC composites. J Am Ceram Soc2000; 83: 2330–2332.
156.
ChamberlainALFahrenholtzWGHilmasGE, et al.High-strength zirconium diboride-based ceramics. J Am Ceram Soc2004; 87: 1170–1172.
157.
MonteverdeF. Beneficial effects of an ultra-fine α-SiC incorporation on the sinterability and mechanical properties of ZrB2. Appl Phys A Mater Sci Process2006; 82: 329–337.
158.
HwangSSVasilievALPadtureNP. Improved processing and oxidation-resistance of ZrB2 ultra-high temperature ceramics containing SiC nanodispersoids. Mater Sci Eng A2007; 464: 216–224.
159.
RezaieAFahrenholtzWGHilmasGE. Effect of hot pressing time and temperature on the microstructure and mechanical properties of ZrB2-SiC. J Mater Sci2007; 42: 2735–2744.
160.
TianWBKanYMZhangGJ, et al.Effect of carbon nanotubes on the properties of ZrB2-SiC ceramics. Mater Sci Eng A2008; 487: 568–573.
161.
GuoSQYangJMTanakaH, et al.Effect of thermal exposure on strength of ZrB2-based composites with nano-sized SiC particles. Compos Sci Technol2008; 68: 3033–3040.
162.
GrigorievONGalanovBAKotenkoVA, et al.Mechanical properties of ZrB2-SiC(ZrSi2) ceramics. J Eur Ceram Soc2010; 30: 2173–2181.
163.
ZhouPHuPZhangX, et al.Laminated ZrB2-SiC ceramic with improved strength and toughness. Scr Mater2011; 64: 276–279.
164.
JinXZhangXHanJ, et al.Thermal shock behavior of porous ZrB2-SiC ceramics. Mater Sci Eng A2013; 588: 175–180.
165.
ZouJZhangGJVleugelsJ, et al.High temperature strength of hot pressed ZrB2-20vol% SiC ceramics based on ZrB2 starting powders prepared by different carbo/boro-thermal reduction routes. J Eur Ceram Soc2013; 33: 1609–1614.
166.
PatelMSinghVReddyJJ, et al.Densification mechanisms during hot pressing of ZrB2-20 vol.% SiC composite. Scr Mater2013; 69: 370–373.
167.
ZouJZhangGJZhangH, et al.Improving high temperature properties of hot pressed ZrB2-20 vol% SiC ceramic using high purity powders. Ceram Int2013; 39: 871–876.
168.
Jaberi ZamharirMShahedi AslMGhassemi KakroudiM, et al.Significance of hot pressing parameters and reinforcement size on sinterability and mechanical properties of ZrB2-25 vol% SiC UHTCs. Ceram Int2015; 41: 9628–9636.
169.
AslMSKakroudiMGNooriS. Hardness and toughness of hot pressed ZrB2-SiC composites consolidated under relatively low pressure. J Alloys Compd2015; 619: 481–487.
170.
Pourmohammadie VafaNNayebiBShahedi AslM, et al.Reactive hot pressing of ZrB2-based composites with changes in ZrO2/SiC ratio and sintering conditions. Part II: mechanical behavior. Ceram Int2016; 42: 2724–2733.
171.
NayebiBShahedi AslMGhassemi KakroudiM, et al.Temperature dependence of microstructure evolution during hot pressing of ZrB2–30 vol.% SiC composites. Int J Refract Met Hard Mater2016; 54: 7–13.
172.
ZhouPFanYWangP, et al.The indentation thermal shock behavior of laminated ZrB2–SiC ceramics with strong interfaces. Ceram Int2016; 42: 17489–17496.
173.
Shahedi AslMKakroudiMGFarahbakhshI, et al.Synergetic effects of SiC and csf in ZrB2-based ceramic composites. Part II: grain growth. Ceram Int2016; 42: 18612–18619.
174.
ZhangZShaJZuY, et al.Fabrication and mechanical properties of self-toughening ZrB2–SiC composites from in-situ reaction. J Adv Ceram2019; 8: 527–536.
175.
WangWWeiCLiuZ, et al.Sic whiskers: a strategy to modify the high-temperature performance of laminated ZrB2–SiC ceramics. Ceram Int2020; 46: 9347–9352.
176.
NguyenVHDelbariSAShahedi AslM, et al.Role of hot-pressing temperature on densification and microstructure of ZrB2–SiC ultrahigh temperature ceramics. Int J Refract Met Hard Mater2020; 93: 1–10.
177.
VenkateswaranTBasuBRajuGB, et al.Densification and properties of transition metal borides-based cermets via spark plasma sintering. J Eur Ceram Soc2006; 26: 2431–2440.
178.
GuoSQNishimuraTKagawaY, et al.Spark plasma sintering of zirconium diborides. J Am Ceram Soc2008; 91: 2848–2855.
179.
GuoSNishimuraTKagawaY. Preparation of zirconium diboride ceramics by reactive spark plasma sintering of zirconium hydride-boron powders. Scr Mater2011; 65: 1018–1021.
180.
ZamoraVOrtizALGuiberteauF, et al.Crystal-size dependence of the spark-plasma-sintering kinetics of ZrB2 ultra-high-temperature ceramics. J Eur Ceram Soc2012; 32: 271–276.
181.
ZamoraVOrtizALGuiberteauF, et al.Spark-plasma sintering of ZrB2 ultra-high-temperature ceramics at lower temperature via nanoscale crystal refinement. J Eur Ceram Soc2012; 32: 2529–2536.
182.
PatraNNasiriNAJayaseelanDD, et al.Synthesis, characterization and use of synthesized fine zirconium diboride as an additive for densification of commercial zirconium diboride powder. Ceram Int2016; 42: 9565–9570.
183.
PhamDDycusJHLeBeauJM, et al.Processing low-oxide ZrB2 ceramics with high strength using boron carbide and spark plasma sintering. J Am Ceram Soc2016; 99: 2585–2592.
184.
WangHWangCAYaoX, et al.Processing and mechanical properties of zirconium diboride-based ceramics prepared by spark plasma sintering. J Am Ceram Soc2007; 90: 1992–1997.
185.
ZhaoYWangLJZhangGJ, et al.Preparation and microstructure of a ZrB2-SiC composite fabricated by the spark plasma sintering-reactive synthesis (SPS-RS) method. J Am Ceram Soc2007; 90: 4040–4042.
186.
AkinIHottaMSahinFC, et al.Microstructure and densification of ZrB2-SiC composites prepared by spark plasma sintering. J Eur Ceram Soc2009; 29: 2379–2385.
187.
GuoWMVleugelsJZhangGJ, et al.Effect of heating rate on densification, microstructure and strength of spark plasma sintered ZrB2-based ceramics. Scr Mater2010; 62: 802–805.
188.
ZhangXLiuRXiongX, et al.Mechanical properties and ablation behavior of ZrB2-SiC ceramics fabricated by spark plasma sintering. Int J Refract Met Hard Mater2015; 48: 120–125.
189.
ChakrabortySDebnathDMallickAR, et al.Microscopic, mechanical and thermal properties of spark plasma sintered ZrB2 based composite containing polycarbosilane derived SiC. Int J Refract Met Hard Mater2015; 52: 176–182.
190.
StadelmannRLugovyMOrlovskayaN, et al.Mechanical properties and residual stresses in ZrB2-SiC spark plasma sintered ceramic composites. J Eur Ceram Soc2016; 36: 1527–1537.
191.
PazhouhanfarYSabahi NaminiAShaddelS, et al.Combined role of SiC particles and SiC whiskers on the characteristics of spark plasma sintered ZrB2 ceramics. Ceram Int2020; 46: 5773–5778.
192.
ZhaoXChenZWangH, et al.The influence of additive and temperature on thermal shock resistance of ZrB2 based composites fabricated by Spark Plasma Sintering. Mater Chem Phys2020; 240: 122061.
193.
YuanJHLiuQYYouY, et al.Effect of ZrB2 powders on densification, microstructure, mechanical properties and thermal conductivity of ZrB2-SiC ceramics. Ceram Int2021; 47: 15843–15848.
194.
BellosiAMonteverdeFScitiD. Fast densification of ultra-high-temperature ceramics by spark plasma sintering. Int J Appl Ceram Technol2006; 3: 32–40.
195.
GuoSQKagawaYNishimuraT, et al.Mechanical and physical behavior of spark plasma sintered ZrC-ZrB2-SiC composites. J Eur Ceram Soc2008; 28: 1279–1285.
196.
CaseEDSmythJRHunterO. Grain-size dependence of microcrack initiation in brittle materials. J Mater Sci1980; 15: 149–153.
197.
ChamberlainALFahrenholtzWGHilmasGE. Reactive hot pressing of zirconium diboride. J Eur Ceram Soc2009; 29: 3401–3408.
198.
ZimmermannJWHilmasGEFahrenholtzWG, et al.Fabrication and properties of reactively hot pressed ZrB2-SiC ceramics. J Eur Ceram Soc2007; 27: 2729–2736.
199.
LiuHLZhangGJLiuJX, et al.Synergetic roles of ZrC and SiC in ternary ZrB2-SiC-ZrC ceramics. J Eur Ceram Soc2015; 35: 4389–4397.
200.
WuWWZhangGJKanYM, et al.Reactive hot pressing of ZrB2-SiC-ZrC ultra high-temperature ceramics at 1800 °C. J Am Ceram Soc2006; 89: 2967–2969.
201.
MaHBLiuHLZhaoJ, et al.Pressureless sintering, mechanical properties and oxidation behavior of ZrB2 ceramics doped with B4C. J Eur Ceram Soc2015; 35: 2699–2705.
202.
MashhadiMShambuliMSafiS. Effect of MoSi2 addition and particle size of SiC on pressureless sintering behavior and mechanical properties of ZrB2-SiC-MoSi2 composites. J Mater Res Technol2016; 5: 200–205.
203.
CsanádiTKovalčíkováADuszaJ, et al.Slip activation controlled nanohardness anisotropy of ZrB2 ceramic grains. Acta Mater2017; 140: 452–464.
ZhangSCHilmasGEFahrenholtzWG. Pressureless densification of zirconium diboride with boron carbide additions. J Am Ceram Soc2006; 89: 1544–1550.
206.
ZhuSFahrenholtzWGHilmasGE, et al.Pressureless sintering of zirconium diboride using boron carbide and carbon additions. J Am Ceram Soc2007; 90: 3660–3663.
207.
FahrenholtzWGHilmasGEZhangSC, et al.Pressureless sintering of zirconium diboride: particle size and additive effects. J Am Ceram Soc2008; 91: 1398–1404.
208.
ZhuSFahrenholtzWGHilmasGE, et al.Pressureless sintering of carbon-coated zirconium diboride powders. Mater Sci Eng A2007; 459: 167–171.
209.
SilvestroniLScitiD. Effects of MoSi2 additions on the properties of Hf- and Zr-B2 composites produced by pressureless sintering. Scr Mater2007; 57: 165–168.
210.
SilvestroniLScitiD. Microstructure and properties of pressureless sintered ZrC-based materials. J Mater Res2008; 23: 1882–1889.
211.
WattsJLStress measurement and development of zirconium diboride silicon carbide ceramics. 2011.
212.
McClaneDLFahrenholtzWGHilmasGE. Thermal properties of (Zr,TM)B2 solid solutions with TM = Hf, Nb, W, Ti, and y. J Am Ceram Soc2014; 97: 1552–1558.
213.
FengLFahrenholtzWGHilmasGE. Effect of ZrB2 content on the densification, microstructure, and mechanical properties of ZrC-SiC ceramics. J Eur Ceram Soc2020; 40: 220–225.
214.
YuZGuoWYangS, et al.Study on the bonding properties of ZrB2 (0001)/ZrC (111) interface via first-principles calculations. Mater Chem Phys2021; 269: 124755.
215.
JarmanJDFahrenholtzWGHilmasGE, et al.Fusion welding of refractory metals and ZrB2-SiC-ZrC ceramics. J Eur Ceram Soc2022; 42: 5195–5207.
216.
GardiniDBackmanLKaczmarekP, et al.Viable route to the manufacture of short carbon fiber-rich UHTC complex shapes with enhanced toughness. Compos Part B Eng2024; 277: 111373.
217.
ZhangXQuQHanJ, et al.Microstructural features and mechanical properties of ZrB2-SiC-ZrC composites fabricated by hot pressing and reactive hot pressing. Scr Mater2008; 59: 753–756.
218.
WuWWZhangGJKanYM, et al.Reactive hot pressing of ZrB2-SiC-ZrC composites at 1600 °C. J Am Ceram Soc2008; 91: 2501–2508.
219.
LiuHLLiuJXLiuHT, et al.Contour maps of mechanical properties in ternary ZrB2SiCZrC ceramic system. Scr Mater2015; 107: 140–144.
220.
TokitaM. Trends in advanced SPS spark plasma sintering systems and technology. J. Soc. Powder Technol. Japan1993; 30: 790–804.
221.
NygrenMShenZ. On the preparation of bio-, nano- and structural ceramics and composites by spark plasma sintering. Solid State Sci2003; 5: 125–131.
222.
AguirreTGCramerCLCakmakE, et al.Processing and microstructure of ZrB2–SiC composite prepared by reactive spark plasma sintering. Results Mater2021; 11: 100217.
223.
ToddRIZapata-SolvasEBonillaRS, et al.Electrical characteristics of flash sintering: thermal runaway of Joule heating. J Eur Ceram Soc2015; 35: 1865–1877.
224.
NiuBZhangFZhangJ, et al.Ultra-fast densification of boron carbide by flash spark plasma sintering. Scr Mater2016; 116: 127–130.
225.
Gonzalez-JulianJJähnertKSpeerK, et al.Effect of internal current flow during the sintering of zirconium diboride by field assisted sintering technology. J Am Ceram Soc2016; 99: 35–42.
226.
GrassoSKimEYSaundersT, et al.Ultra-Rapid crystal growth of textured SiC using flash spark plasma sintering route. Cryst Growth Des2016; 16: 2317–2321.
227.
Gil-GonzálezEPérez-MaquedaLASánchez-JiménezPE, et al.Flash sintering research perspective: A bibliometric analysis. Materials (Basel)2022; 15 (2): 1–20.
228.
GrassoSSaundersTPorwalH, et al.Flash spark plasma sintering (FSPS) of pure ZrB2. J Am Ceram Soc2014; 97: 2405–2408.
229.
DemirskyiDSuzukiTSGrassoS, et al.Microstructure and flexural strength of hafnium diboride via flash and conventional spark plasma sintering. J Eur Ceram Soc2019; 39: 898–906.
230.
De BonaEManièreCSglavoVM, et al.Ultrafast high-temperature sintering (UHS) of ZrB2-based materials. J Eur Ceram Soc2024; 44: 567–573.
231.
SharmaAKarunakarDB. Development and investigation of densification behavior of ZrB2–SiC composites through microwave sintering. Mater Res Express2019; 6: 15354–15373.
232.
ZhuSFahrenholtzWGHilmasGE, et al.Microwave sintering of a ZrB2-B4C particulate ceramic composite. Compos Part A Appl Sci Manuf2008; 39: 449–453.
233.
KruthJPMercelisPVan VaerenberghJ, et al.Binding mechanisms in selective laser sintering and selective laser melting. Rapid Prototyp J2005; 11: 26–36.
234.
SunCNGuptaMC. Laser sintering of ZrB2. J Am Ceram Soc2008; 91: 1729–1731.
235.
LiuYChengYMaD, et al.Continuous carbon fiber reinforced ZrB2-SiC composites fabricated by direct ink writing combined with low-temperature hot-pressing. J Eur Ceram Soc2022; 42: 3699–3707.
236.
SilvestroniLPavanDMelandriC, et al.Functionally graded ultra-high temperature ceramics: From thermo-elastic numerical analysis to damage tolerant composites. Mater Des2022; 224: 1–13.
237.
De BianchiFPonnusamiSASilvestroniL, et al.Thermo-elastic properties in short fibre reinforced ultra-high temperature ceramic matrix composites: characterisation and numerical assessment. Mater Today Commun2021; 29: 102754.
238.
RueschhoffLMCarneyCMApostolovZD, et al.Processing of fiber-reinforced ultra-high temperature ceramic composites: a review. Int J Ceram Eng Sci2020; 2: 22–37.
239.
ScitiDSilvestroniLMonteverdeF, et al.Introduction to H2020 project C3HARME–next generation ceramic composites for combustion harsh environment and space. Adv Appl Ceram2018; 117: s70–s75.
240.
SilvestroniLVinciAFaillaS, et al.Ablation behaviour of ultra-high temperature ceramic matrix composites: role of MeSi2 addition. J Eur Ceram Soc2019; 39: 2771–2781.
241.
MungiguerraSSilvestroniLSavinoR, et al.Qualification and reusability of long and short fibre-reinforced ultra-refractory composites for aerospace thermal protection systems. Corros Sci2022; 195: 109955.
242.
SessoMLSlaterSThorntonJ, et al.Direct ink writing of hierarchical porous ultra-high temperature ceramics (ZrB2). J Am Ceram Soc2021; 104: 4977–4990.
243.
KempJWDiazAAMalekEC, et al.Direct ink writing of ZrB2-SiC chopped fiber ceramic composites. Addit Manuf2021; 44: 102049.
244.
ZhangZSongXSuH, et al.Microstructure evolution and solidification behaviour of ZrB2-SiC composite ceramics fabricated by laser surface zone-melting. J Mater Sci Technol2024; 190: 145–154.
245.
ServadeiFZoliLGaliziaP, et al.Development of UHTCMCs via water based ZrB2 powder slurry infiltration and polymer infiltration and pyrolysis. J Eur Ceram Soc2020; 40: 5076–5084.
246.
HuPZhangDDongS, et al.A novel vibration-assisted slurry impregnation to fabricate cf/ZrB2-SiC composite with enhanced mechanical properties. J Eur Ceram Soc2019; 39: 798–805.
247.
HuangDZhangMHuangQ, et al.Ablation mechanism of C/C-ZrB2-ZrC-SiC composite fabricated by polymer infiltration and pyrolysis with preform of Cf/ZrB2. Corros Sci2015; 98: 551–559.
248.
ZhangSWangSLiW, et al.Preparation of ZrB2 based composites by reactive melt infiltration at relative low temperature. Mater Lett2011; 65: 2910–2912.
249.
LuJNiDChenB, et al.Ablation behaviour of csf/ZrB2-SiC composites fabricated by direct ink writing and reactive melt infiltration. J Eur Ceram Soc2023; 43: 3034–3042.
250.
WangRZhangJFeiJ, et al.Effect of ZrB2 on the ablation behavior of Cf/ZrB2-ZrC-SiC sharp leading edge composites by PIP and RMI. Mater Charact2024; 211: 113898.
251.
SuHJiangHZhangZ, et al.Crucible-free fabrication of ZrB2–SiC composite ceramics with ultra-fine eutectic microstructure by laser surface zone-melting: the selection of lasers. Ceram Int2023; 49: 9346–9354.
252.
LiuJLiYHeP, et al.Microstructure and properties of ZrB2-SiC continuous gradient coating prepared by high speed laser cladding. Tribol Int2022; 173: 107645.
253.
LonnéQGlandutNLefortP. Surface densification of porous ZrB2-39mol.% SiC ceramic composites by a laser process. J Eur Ceram Soc2012; 32: 955–963.
254.
TuHHirayamaHGotoT. Preparation of ZrB2-SiC composites by arc melting and their properties. J Ceram Soc Japan2008; 116: 431–435.
255.
RenZWangXBLiYL, et al.In situ fabrication of ZrB2-SiC composite with arrayed ZrB2 micro-rods by arc-melting. Scr Mater2012; 67: 696–699.
256.
SuHJZhangJRenQ, et al.Laser zone remelting of Al2O3/Er3Al 5O12 bulk oxide in situ composite thermal emission ceramics: influence of rapid solidification. Mater Res Bull2013; 48: 544–550.
257.
ShenZSuHLiuH, et al.Directly fabricated Al2O3/GdAlO3 eutectic ceramic with large smooth surface by selective laser melting: rapid solidification behavior and thermal field simulation. J Eur Ceram Soc2022; 42: 1088–1101.
258.
XiongZZhangKLiuT, et al.Role of scanning speed on the microstructure and mechanical properties of additively manufactured Al2O3‒ZrO2. J Am Ceram Soc2023; 106: 7760–7775.
259.
SuHJiangHZhangZ, et al.Microstructure and mechanical properties of ZrB2-SiC eutectic composite ceramic fabricated by laser surface zone-melting: the effect of laser power and scanning speed. J Eur Ceram Soc2023; 43: 5822–5829.
260.
SilvestroniLScitiDMelandriC, et al.Toughened ZrB2-based ceramics through SiC whisker or SiC chopped fiber additions. J Eur Ceram Soc2010; 30: 2155–2164.
261.
ScitiDPientiLFabbricheDD, et al.Combined effect of SiC chopped fibers and SiC whiskers on the toughening of ZrB2. Ceram Int2014; 40: 4819–4826.
262.
CaoMWangSHanW. Influence of nanosized SiC particle on the fracture toughness of ZrB2-based nanocomposite ceramic. Mater Sci Eng A2010; 527: 2925–2928.
263.
LiSWeiCWangW, et al.Fracture toughness and R-curve behavior of laminated ZrB2–SiC/SiCw ceramic. J Alloys Compd2019; 784: 96–101.
264.
SilvestroniLDalle FabbricheDMelandriC, et al.Relationships between carbon fiber type and interfacial domain in ZrB2-based ceramics. J Eur Ceram Soc2016; 36: 17–24.
265.
ScitiDGuicciardiSSilvestroniL. Are short Hi-Nicalon SiC fibers a secondary or a toughening phase for ultra-high temperature ceramics?Mater Des2014; 55: 821–829.
266.
SilvestroniLGuicciardiSNygrenM, et al.Effect of the sintering additive on microstructure and mechanical properties of Hi-nicalonTM SiC fibers in a HfB2 matrix. J Am Ceram Soc2013; 96: 643–650.
267.
SilvestroniLKupschAMüllerBR, et al.Determination of short carbon fiber orientation in zirconium diboride ceramic matrix composites. J Eur Ceram Soc. 2024 ; 44: 4853–4862.
268.
CroomBPAbbottAKempJW, et al.Mechanics of nozzle clogging during direct ink writing of fiber-reinforced composites. Addit Manuf2021; 37: 101701.
269.
FengTShiXHouW, et al.The ablation and mechanical behaviors of C/(SiC-ZrC)n multi-layer structure matrix composites by chemical vapor infiltration. J Eur Ceram Soc2022; 42: 4133–4143.
270.
ZhangJPQuJLFuQG. Ablation behavior of nose-shaped HfB 2 -SiC modified carbon/carbon composites exposed to oxyacetylene torch. Corros Sci2019; 151: 87–96.
271.
JiaYChenSLiY, et al.High-temperature mechanical properties and microstructure of C/C‒ZrC‒SiC‒ZrB2 composites prepared by a joint process of precursor infiltration and pyrolysis and slurry infiltration. J Alloys Compd2019; 811: 1–11.
272.
HeQLiHWangC, et al.Microstructure and ablation property of C/C-ZrC-SiC composites fabricated by chemical liquid-vapor deposition combined with precursor infiltration and pyrolysis. Ceram Int2019; 45: 3767–3781.
273.
LiYChenSMaX, et al.Effects of high-temperature annealing on the microstructure and properties of C/SiC-ZrC composites. Ceram Int2016; 42: 5171–5176.
274.
FeiRAOKePENGHuanYIN, et al.Preparation and properties of C/C−ZrB2−SiC composites by high-solid-loading slurry impregnation and polymer infiltration and pyrolysis (PIP). Trans Nonferrous Met Soc China (English Ed)2019; 29: 2141–2150.
275.
ChengYZhangYZhangF, et al.Using flexible hydrothermal carbon-coated continuous carbon fiber to fabricate Cf/ZrB2-SiC composites by fused deposition modeling and precursor infiltration pyrolysis. J Eur Ceram Soc2024; 44: 721–728.
276.
SilvestroniLVinciAGilliN, et al.Melt/solid interaction and melt super-saturation effect on the microstructure asset of ultra-refractory composites prepared by reactive melting infiltration. J Alloys Compd2023; 947: 169521.
277.
OrtonaAFinoPD’AngeloC, et al.Si-SiC-ZrB2 ceramics by silicon reactive infiltration. Ceram Int2012; 38: 3243–3250.
278.
InoueRAraiYKubotaY, et al.Development of short- and continuous carbon fiber-reinforced ZrB2-SiC-ZrC matrix composites for thermal protection systems. Ceram Int2018; 44: 15859–15867.
279.
XiangHDaiFZhouY. Secrets of high thermal emission of transition metal disilicides TMSi2 (TM = Ta, Mo). J Mater Sci Technol2021; 89: 114–121.
280.
ZhangSWangSZhuY, et al.Fabrication of ZrB2-ZrC-based composites by reactive melt infiltration at relative low temperature. Scr Mater2011; 65: 139–142.
281.
ChenXDongSKanY, et al.3D Cf/SiC-ZrC-ZrB2 composites fabricated via sol-gel process combined with reactive melt infiltration. J Eur Ceram Soc2016; 36: 3607–3613.
282.
ChenXNiDKanY, et al.Reaction mechanism and microstructure development of ZrSi2 melt-infiltrated cf/SiC-ZrC-ZrB2 composites: the influence of preform pore structures. J Mater2018; 4: 266–275.
283.
SilvestroniLVinciAGilliN, et al.Melt/solid interaction and melt super-saturation effect on the microstructure asset of ultra-refractory composites prepared by reactive melting infiltration. J Alloys Compd2023; 947: 169521.
284.
KongJHLeeSYSonY, et al.Synergistic reinforcement effects of ZrB2 on the ultra-high temperature stability of Cf/SiC composite fabricated by liquid silicon infiltration. J Eur Ceram Soc2023; 43: 3062–3069.
285.
XueCZhouHHuJ, et al.Fabrication and microstructure of ZrB2–ZrC–SiC coatings on C/C composites by reactive melt infiltration using ZrSi2 alloy. J Adv Ceram2018; 7: 64–71.
286.
UpadhyaKYangJ-MHoffmanWP. Advanced materials for ultrahigh temperature structural applications above 2000 °C. Am Ceram Soc Bull1997; 76: 51–56.
287.
BorrelliRRiccioATescioneD, et al.Thermo-structural behaviour of an UHTC made nose cap of a reentry vehicle. Acta Astronaut2009; 65: 442–456.
288.
MonteverdeFSavinoRFumoMDS, et al.Plasma wind tunnel testing of ultra-high temperature ZrB2-SiC composites under hypersonic re-entry conditions. J Eur Ceram Soc2010; 30: 2313–2321.
289.
MallikMKailathAJRayKK, et al.Effect of SiC content on electrical, thermal and ablative properties of pressureless sintered ZrB2-based ultrahigh temperature ceramic composites. J Eur Ceram Soc2017; 37: 559–572.
290.
WuchinaEOpekaMCauseyS, et al.Designing for ultrahigh-temperature applications: the mechanical and thermal properties of HfB2, HfCx, HfNx and αHf(N). J Mater Sci2004; 39: 5939–5949.
291.
NisarAHassanRAgarwalA, et al.Ultra-high temperature ceramics: Aspiration to overcome challenges in thermal protection systems. Ceram Int. 2022; 48(7): 8852–8881.
292.
BranscombTMHunterO. Improved thermal diffusivity method applied to TiB2, ZrB2, and HfB2 from 200 °C-1300 °C. J Appl Phys1971; 42: 2309–2315.
293.
SamsonovGVKovenskayaBASerebryakovaTI, et al.Thermal conductivity of diborides of group IV–VI transition metals. High Temp (Engl Transl)1972; 10: 1324–1326.
294.
WilliamsWS. Transition metal carbides, nitrides, and borides for electronic applications. Jom1997; 49: 38–42.
295.
NilssonOMehlingHHornR, et al.Determination of the thermal diffusivity and conductivity of monocrystalline silicon carbide (300-2300K). High Temp - High Press1997; 29: 73–79.
296.
ThomasDJ. Design and analysis of UHTC leading edge attachment.
297.
LoehmanRCorralEDummHP, et al.Ultra high temperature ceramics for hypersonic vehicle applications. Ind.Heat2004; 71(1): 36–38.
298.
ZimmermannJWHilmasGEFahrenholtzWG, et al.Thermophysical properties of ZrB2 and ZrB2-SiC ceramics. J Am Ceram Soc2008; 91: 1405–1411.
299.
WangZHongCZhangX, et al.Microstructure and thermal shock behavior of ZrB2-SiC-graphite composite. Mater Chem Phys2009; 113: 338–341.
300.
MallikMKailathAJRayKK, et al.Electrical and thermophysical properties of ZrB2 and HfB2 based composites. J Eur Ceram Soc2012; 32: 2545–2555.
301.
MonteverdeFSavinoR. ZrB2-SiC sharp leading edges in high enthalpy supersonic flows. J Am Ceram Soc2012; 95: 2282–2289.
302.
YuanHLiJShenQ, et al.Preparation and thermal conductivity characterization of ZrB2 porous ceramics fabricated by spark plasma sintering. Int J Refract Met Hard Mater2013; 36: 225–231.
303.
TuRXiaoBZhangS, et al.Mechanical, electrical and thermal properties of ZrC-ZrB2-SiC ternary eutectic composites prepared by arc melting. J Eur Ceram Soc2018; 38: 3759–3766.
304.
ThompsonMJFahrenholtzWGHilmasGE. Elevated temperature thermal properties of ZrB 2 with carbon additions. J Am Ceram Soc2012; 95: 1077–1085.
305.
ZouJZhangGJHuCF, et al.High-temperature bending strength, internal friction and stiffness of ZrB2-20vol% SiC ceramics. J Eur Ceram Soc2012; 32: 2519–2527.
306.
LiJPorterLYipS. Atomistic modeling of finite-temperature properties of crystalline β-SiC: iI. Thermal conductivity and effects of point defects. J Nucl Mater1998; 255: 139–152.
KinoshitaHOtaniSKamiyamaS, et al.Zirconium diboride (0001) as an electrically conductive lattice-matched substrate for gallium nitride. Japanese J Appl Physics, Part 2 Lett2001; 40: 10–13.
309.
ZhangLPejakovićDAMarschallJ, et al.Thermal and electrical transport properties of spark plasma-sintered HfB2 and ZrB2 ceramics. J Am Ceram Soc2011; 94: 2562–2570.
310.
IkegamiMMatsumuraKGuoSQ, et al.Effect of SiC particle dispersion on thermal properties of SiC particle-dispersed ZrB2 matrix composites. J Mater Sci2010; 45: 5420–5423.
311.
HarringtonGJKHilmasGEFahrenholtzWG. Effect of carbon on the thermal and electrical transport properties of zirconium diboride. J Eur Ceram Soc2015; 35: 887–896.
312.
KimSChaeJMLeeSM, et al.Change in microstructures and physical properties of ZrB2-SiC ceramics hot-pressed with a variety of SiC sources. Ceram Int2014; 40: 3477–3483.
313.
LonerganJMFahrenholtzWGHilmasGE. Zirconium diboride with high thermal conductivity. J Am Ceram Soc2014; 97: 1689–1691.
TakahashiKJimbouR. Effect of uniformity on the electrical resistivity of SiC-ZrB2 ceramic composites. J Am Ceram Soc1987; 70: C-369-C-373.
316.
RahmanMWangCCChenW, et al.Electrical resistivity of Titanium diboride and zirconium diboride. J. Am. Ceram. Soc1995; 78: 1380–1382.
317.
ShinY-DJuJ-YKwonJ-S. Electrical resistivity and fracture toughness of SiC-ZrB2. Korean J Ceram1999; 5: 400–403.
318.
LeeJ-HJuJ-YKimC-H, et al.The development of an electroconductive SiC-ZrB2 ceramic heater through spark plasma sintering. J Electr Eng Technol2009; 2009: 538–545.
319.
HeRFangDWangP, et al.Electrical properties of ZrB2-SiC ceramics with potential for heating element applications. Ceram Int2014; 40: 9549–9553.
320.
FengXWangXLiuY, et al.Investigation of electrical properties of pressureless sintered ZrB 2 -based ceramics. Ceram Int2019; 45: 7717–7722.
321.
GuicciardiSSilvestroniLNygrenM, et al.Microstructure and toughening mechanisms in spark plasma-sintered ZrB2 ceramics reinforced by SiC whiskers or SiC-chopped fibers. J Am Ceram Soc2010; 93: 2384–2391.
322.
GuoSKagawaYNishimuraT, et al.Elastic properties of spark plasma sintered (SPSed) ZrB2-ZrC-SiC composites. Ceram Int2008; 34: 1811–1817.
323.
SilvestroniLScitiD. Oxidation of ZrB2 ceramics containing SiC as particles, whiskers, or short fibers. J Am Ceram Soc2011; 94: 2796–2799.
324.
ZoliLMedriVMelandriC, et al.Continuous SiC fibers-ZrB2 composites. J Eur Ceram Soc2015; 35: 4371–4376.
325.
LankfordJ. Comparative study of the temperature dependence of hardness and compressive strength in ceramics. J Mater Sci1983; 18: 1666–16lp.
326.
HuCSakkaYTanakaH, et al.Microstructure and properties of ZrB2-SiC composites prepared by spark plasma sintering using TaSi2 as sintering additive. J Eur Ceram Soc2010; 30: 2625–2631.
327.
SmithE. The role of microcracking during crack growth in brittle materials. J Mater Sci Lett1983; 2: 204–206.
328.
YanXJinXLiP, et al.Microstructures and mechanical properties of ZrB2–SiC–Ni ceramic composites prepared by spark plasma sintering. Ceram Int2019; 45: 16707–16712.
329.
SubramanianCRoyTKMurthyTSRC, et al.Effect of zirconia addition on pressureless sintering of boron carbide. Ceram Int2008; 34: 1543–1549.
330.
WangHLHonMH. Temperature dependence of ceramics hardness. Ceram Int1999; 25: 267–271.
331.
DaiFZZhouY. A modified theoretical model of intrinsic hardness of crystalline solids. Sci Rep2016; 6: 1–8.
332.
GaoFHeJWuE, et al.Hardness of covalent crystals. Phys Rev Lett2003; 91(1): 15502.
333.
BsenkoLLundströmT. The high-temperature hardness of ZrB2 and HfB2. J Less Common Met1974; 34: 273–278.
334.
WangJFeilden-IrvingELucJ, et al.The Hardness of ZrB2 between 1373 K and 2273 K. Ceramic Engineering and Science Proceedings. John Wiley & Sons, 2012.
335.
KrishnaraoRVBhanuprasadVVReddyGM. Zrb2 – SiC based composites for thermal protection by reaction sintering of ZrO2 + B4C + si. 2017; 6: 320–329.
DeanEALopezJA. Empirical dependence of elastic moduli on porosity for ceramic materials. J Am Ceram Soc1983; 66: 366–370.
338.
RamakrishnanNArunachalamVS. Effective elastic moduli of porous ceramic materials. J Am Ceram Soc1993; 76: 2745–2752.
339.
JeongHHsuDK. Quantitative estimation of material properties of porous ceramics by means of composite micromechanics and ultrasonic velocity. NDT E Int1996; 29: 95–101.
340.
HarrisonRWLeeWE. Processing and properties of ZrC, ZrN and ZrCN ceramics: a review. Adv Appl Ceram2016; 115: 294–307.
341.
LiuLLiHShiX, et al.Influence of SiC additive on the ablation behavior of C/C composites modified by ZrB2-ZrC particles under oxyacetylene torch. Ceram Int2014; 40: 541–549.
342.
MonteverdeFScatteiaL. Resistance to thermal shock and to oxidation of metal diborides-SiC ceramics for aerospace application. J Am Ceram Soc2007; 90: 1130–1138.
343.
ZimmermannJWHilmasGEFahrenholtzWG. Thermal shock resistance of ZrB2 and ZrB2-30% SiC. Mater Chem Phys2008; 112: 140–145.
344.
LiWZhangYZhangX, et al.Thermal shock behavior of ZrB2-SiC ultra-high temperature ceramics with addition of zirconia. J Alloys Compd2009; 478: 386–391.
345.
ZimmermannJWHilmasGEFahrenholtzWG. Thermal shock resistance and fracture behavior of ZrB2-based fibrous monolith ceramics. J Am Ceram Soc2009; 92: 161–166.
346.
ZhouPWangZFanY, et al.Thermal shock resistance of laminated ZrB2-SiC ceramic evaluated by indentation technique. J Am Ceram Soc2015; 98: 2866–2872.
347.
WangAHuPZhangX, et al.Thermal shock behavior of ZrB2-based sharp leading edges evaluated by a novel water spraying method. Ceram Int2018; 44: 2376–2382.
348.
WangAHuPDuB, et al.Cracking behavior of ZrB2-SiC-graphite sharp leading edges during thermal shock. Ceram Int2018; 44: 7694–7699.
349.
ZhangLWeiCLiS, et al.Mechanical and thermal shock properties of laminated ZrB2-SiC/SiCw ceramics. Ceram Int2019; 45: 6503–6508.
350.
ZhiWQiangQZhanjunW, et al.The thermal shock resistance of the ZrB2-SiC-ZrC ceramic. Mater Des2011; 32: 3499–3503.
351.
WuZWangZShiG, et al.Effect of surface oxidation on thermal shock resistance of the ZrB2-SiC-ZrC ceramic. Compos Sci Technol2011; 71: 1501–1506.
352.
WangZZhouPWuZ. Effect of surface oxidation on thermal shock resistance of ZrB2-SiC-ZrC ceramic at temperature difference from 800 to 1900 °C. Corros Sci2015; 98: 233–239.
353.
PettinàMBiglariFHeatonA, et al.Modelling damage and creep crack growth in structural ceramics at ultra-high temperatures. J Eur Ceram Soc2014; 34: 2799–2805.
354.
Meléndez-MartínezJJDomínguez-RodríguezAMonteverdeF, et al.Characterisation and high temperature mechanical properties of zirconium boride-based materials. J Eur Ceram Soc2002; 22: 2543–2549.
355.
BirdMWAuneRPYuF, et al.Creep behavior of a zirconium diboride-silicon carbide composite. J Eur Ceram Soc2013; 33: 2407–2420.
356.
BirdMWRamptonTFullwoodD, et al.Local dislocation creep accommodation of a zirconium diboride silicon carbide composite. Acta Mater2015; 84: 359–367.
357.
BirdMWBecherPFWhiteKW. Grain rotation and translation contribute substantially to creep of a zirconium diboride silicon carbide composite. Acta Mater2015; 89: 73–87.
358.
TalmyIGZaykoskiJAMartinCA. Flexural creep deformation of ZrB2/SiC ceramics in oxidizing atmosphere. J Am Ceram Soc2008; 91: 1441–1447.
359.
GuoWMZhangGJLinHT. High-temperature flexural creep of ZrB2-SiC ceramics in argon atmosphere. Ceram Int2012; 38: 831–835.
360.
GangireddySHalloranJWWingZN. Flexural creep of zirconium diboride-silicon carbide up to 2200 °C in minutes with non-contact electromagnetic testing. J Eur Ceram Soc2013; 33: 2901–2908.
BelovskyL. Heat release from B4C oxidation in steam and air. 1995: 49–61.
370.
KarlsdottirSNHalloranJWHendersonCE. Convection patterns in liquid oxide films on ZrB2-SiC composites oxidized at a high temperature. J Am Ceram Soc2007; 90: 2863–2867.
371.
KarlsdottirSNHalloranJWGrundyAN. Zirconia transport by liquid convection during oxidation of zirconium diboride-silicon carbide. J Am Ceram Soc2008; 91: 272–277.
372.
RezaieAFahrenholtzWGHilmasGE. Evolution of structure during the oxidation of zirconium diboride-silicon carbide in air up to 1500 °C. J Eur Ceram Soc2007; 27: 2495–2501.
373.
HanJHuPZhangX, et al.Oxidation behavior of zirconium diboride-silicon carbide at 1800 °C. Scr Mater2007; 57: 825–828.
374.
KarlsdottirSNHalloranJW. Rapid oxidation characterization of ultra-high temperature ceramics. J Am Ceram Soc2007; 90: 3233–3238.
375.
HanWBHuPZhangXH, et al.High-temperature oxidation at 1900 °C of ZrB2-xSiC ultrahigh-temperature ceramic composites. J Am Ceram Soc2008; 91: 3328–3334.
376.
ZhangXHHuPHanJC. Structure evolution of ZrB2-SiC during the oxidation in air. J Mater Res2008; 23: 1961–1972.
377.
MarschallJPejakovićDAFahrenholtzWG, et al.Oxidation of ZrB2-SiC ultrahigh-temperature ceramic composites in dissociated air. J Thermophys Heat Transf2009; 23: 267–278.
378.
CarneyCMMogilveskyPParthasarathyTA. Oxidation behavior of zirconium diboride silicon carbide produced by the spark plasma sintering method. J Am Ceram Soc2009; 92: 2046–2052.
379.
GuoWMZhangGJ. Oxidation resistance and strength retention of ZrB2-SiC ceramics. J Eur Ceram Soc2010; 30: 2387–2395.
380.
GaoDZhangYFuJ, et al.Oxidation of zirconium diboride-silicon carbide ceramics under an oxygen partial pressure of 200Pa: formation of zircon. Corros Sci2010; 52: 3297–3303.
381.
GaoDZhangYXuC, et al.Effect of ozone adsorption on the oxidation behaviour of ZrB2-SiC ceramic composites. Corros Sci2011; 53: 840–844.
382.
PatelMReddyJJBhanu PrasadVV, et al.Strength of hot pressed ZrB2-SiC composite after exposure to high temperatures (1000-1700 °C). J Eur Ceram Soc2012; 32: 4455–4467.
383.
WilliamsPASakidjaRPerepezkoJH, et al.Oxidation of ZrB2-SiC ultra-high temperature composites over a wide range of SiC content. J Eur Ceram Soc2012; 32: 3875–3883.
384.
HuPGuiKYangY, et al.Effect of SiC content on the ablation and oxidation behavior of ZrB2-based ultra high temperature ceramic composites. Materials (Basel)2013; 6: 1730–1744.
385.
SilvestroniLMungiguerraSScitiD, et al.Effect of hypersonic flow chemical composition on the oxidation behavior of a super-strong UHTC. Corros Sci2019; 159: 108125.
386.
WangZWuZShiG. The oxidation behaviors of a ZrB2-SiC-ZrC ceramic. Solid State Sci2011; 13: 534–538.
387.
GaoDZhangYXuC, et al.Atomic oxygen adsorption and its effect on the oxidation behaviour of ZrB2-ZrC-SiC in air. Mater Chem Phys2011; 126: 156–161.
388.
ShiGWangZSunX, et al.Effect of the surface oxidation on the flexural strength of the ZrB2-SiC-ZrC ceramic. Mater Sci Eng A2012; 546: 162–168.
389.
LiuHLLiuJXLiuHT, et al.Changed oxidation behavior of ZrB2-SiC ceramics with the addition of ZrC. Ceram Int2015; 41: 8247–8251.
390.
KubotaaYTanakabHAraicY, et al.Oxidation behavior of ZrB2-SiC-ZrC at 1700 ◦C. J Eur Ceram Soc2017; 37: 1187–1194.
391.
KubotaYYanoMInoueR, et al.Oxidation behavior of ZrB2-SiC-ZrC in oxygen-hydrogen torch environment. J Eur Ceram Soc2018; 38: 1095–1102.
392.
InoueRAraiYKubotaY, et al.Initial oxidation behaviors of ZrB2-SiC-ZrC ternary composites above 2000 °C.J Alloys Compd2018; 731: 310–317.
393.
ZhangXHuPHanJ, et al.Ablation behavior of ZrB2-SiC ultra high temperature ceramics under simulated atmospheric re-entry conditions. Compos Sci Technol2008; 68: 1718–1726.
394.
LiGHanWZhangX, et al.Ablation resistance of ZrB2-SiC-AlN ceramic composites. J Alloys Compd2009; 479: 299–302.
395.
ZhangYHuHZhangP, et al.SiC/ZrB2-SiC-ZrC multilayer coating for carbon/carbon composites against ablation. Surf Coatings Technol2016; 300: 1–9.
396.
NisarAAriharanSVenkateswaranT, et al.Effect of carbon nanotube on processing, microstructural, mechanical and ablation behavior of ZrB2-20SiC based ultra-high temperature ceramic composites. Carbon NY2017; 111: 269–282.
397.
ZouJRubioVBinnerJ. Thermoablative resistance of ZrB2-SiC-WC ceramics at 2400 °C. Acta Mater2017; 133: 293–302.
398.
ChengYHuYHanW, et al.Microstructure, mechanical behavior and oxidation resistance of disorderly assembled ZrB 2 -based short fibrous monolithic ceramics. J Eur Ceram Soc2019; 39: 2794–2804.
399.
XuXPanXNiuY, et al.Difference evaluation on ablation behaviors of ZrC-based and ZrB2-based UHTCs coatings. Corros Sci2021; 180: 109181.
400.
FahrenholtzWG. Thermodynamic analysis of ZrB2-SiC oxidation: formation of a SiC-depleted region. J Am Ceram Soc2007; 90: 143–148.
401.
ShugartKJenningsWOpilaE. Initial stages of ZrB2-30 vol% SiC oxidation at 1500 °C. J Am Ceram Soc2014; 97: 1645–1651.
402.
ShugartKN,2007,Oxidation Behavior of Zirconium Diboride-Silicon Carbide Composites at High Temperatures.
403.
VoitovichRFPugachÉAMen’shikovaLA. High-temperature oxidation of zirconium diboride. Sov Powder Metall Met Ceram1967; 6: 462–465.
404.
Berkowitz-mattuckJB. High-Temperature oxidation III. Zirconium and hafnium diborides. J Electrochem Soc1966; 113: 908–914.
405.
TrippWCGrahamHC. Thermogravimetric study of the oxidation of ZrB2 in the temperature range of 800 ∼ to 1500∼. J Electrochem Soc1971; 7: 1196–1199.
406.
ZhangXChenZXiongX, et al.Morphology and microstructure of ZrB2-SiC ceramics after ablation at 3000 oC by oxy-acetylene torch. Ceram Int2016; 42: 2798–2805.
407.
KolodziejPBowlesJVRobertsC, et al.. Optimizing hypersonic sharp body concepts from a thermal protection system perspective. Norfolk, VA: American Institute of Aeronautics and Astronautics, 1998, pp. 556–571.
408.
KontinosDAGeeKPrabhuDK. Temperature constraints at the sharp leading edge of a crew transfer vehicle. In: 35th AIAA Thermophys Conf, https://doi.org/10.2514/6.2001-2886.
409.
SavinoRDe Stefano FumoMPaternaD, et al.Aerothermodynamic study of UHTC-based thermal protection systems. Aerosp Sci Technol2005; 9: 151–160.
410.
MonteverdeFSavinoR. Stability of ultra-high-temperature ZrB2-SiC ceramics under simulated atmospheric re-entry conditions. J Eur Ceram Soc2007; 27: 4797–4805.
411.
ScitiDSavinoRSilvestroniL. Aerothermal behaviour of a SiC fibre-reinforced ZrB2 sharp component in supersonic regime. J Eur Ceram Soc2012; 32: 1837–1845.
412.
DynamicCFTunnelWStructuresSH, et al.. Thermo-structural design of ultra high temperature. Boston, MA: American Institute of Aeronautics and Astronautics, 2013, pp. 1–13.
413.
MercatelliLSaniEJafrancescoD, et al.Ultra-refractory diboride ceramics for solar plant receivers. Energy Procedia2014; 49: 468–477.
414.
WeiKHeRChengX, et al.A lightweight, high compression strength ultra high temperature ceramic corrugated panel with potential for thermal protection system applications. Mater Des2015; 66: 552–556.
415.
PengWHeYWangX, et al.Thermal protection mechanism of heat pipe in leading edge under hypersonic conditions. Chinese J Aeronaut2015; 28: 121–132.
416.
JayaseelanDDXinYVandeperreL, et al.Development of multi-layered thermal protection system (TPS) for aerospace applications. Compos Part B Eng2015; 79: 392–405.
417.
WangRLiDXingA, et al.. Temperature dependent fracture strength model for the laminated ZrB2 based composites. Composite Structures2017; 162: 39–46.
418.
SavinoRCriscuoloLDi MartinoGD, et al.Aero-thermo-chemical characterization of ultra-high-temperature ceramics for aerospace applications. J Eur Ceram Soc2018; 38: 2937–2953.
419.
FahrenholtzWGHilmasGE. Ultra-high temperature ceramics: materials for extreme environments. Scr Mater2017; 129: 94–99.
420.
MallikMMitraPSrivastavaN, et al.Abrasive wear performance of zirconium diboride based ceramic composite. Int J Refract Met Hard Mater2019; 79: 224–232.
421.
GopinathNKJagadeeshGBasuB. Shock wave-material interaction in ZrB2–SiC based ultra high temperature ceramics for hypersonic applications. J Am Ceram Soc2019; 102: 6925–6938.
422.
MurthyTSRCSonberJKSairamK, et al.Boron-Based Ceramics and Composites for Nuclear and Space Applications: Synthesis and Consolidation. Handbook of Advanced Ceramics and Composites. Springer, Cham, 2020. https://doi.org/10.1007/978-3-030-16347-1_22.
423.
ZhangXHeJHanL, et al.Foam gel-casting preparation of SiC bonded ZrB2 porous ceramics for high-performance thermal insulation. J Eur Ceram Soc2023; 43: 37–46.
424.
SaniEMercatelliLMeucciM, et al.Optical properties of dense zirconium and tantalum diborides for solar thermal absorbers. Renew Energy2016; 91: 340–346.
425.
SaniEMercatelliLMeucciM, et al.Compositional dependence of optical properties of zirconium, hafnium and tantalum carbides for solar absorber applications. Sol Energy2016; 131: 199–207.
426.
KennedyCE. Review of mid- to high- temperature solar selective absorber materials. 2002.
427.
BurlafingerKVetterABrabecCJ. Maximizing concentrated solar power (CSP) plant overall efficiencies by using spectral selective absorbers at optimal operation temperatures. Sol Energy2015; 120: 428–438.
428.
RaabeDMianroodiJRNeugebauerJ. Accelerating the design of compositionally complex materials via physics-informed artificial intelligence. Nat Comput Sci2023; 3: 198–209.
