Degradation of refractory organic matter in the effluent from a semi-aerobic aged refuse biofilter-treated landfill leachate by a nano-Fe 3 O 4 enhanced ozonation process

Abstract

In this study, the transformation and degradation mechanisms of refractory organic matter in biologically treated leachate from a semi-aerobic aged refuse biofilter (SAARB) in a nano-Fe₃O₄ enhanced ozonation process (nFe₃O₄-O₃) were investigated in batch experiments. A continuous experiment then confirmed the effectiveness of the process for SAARB effluent treatment. In a batch experiment, the effects of influencing factors, including nFe₃O₄ dosage, O₃ dosage and initial pH on the treatment performance of nFe₃O₄-O₃ process, were comprehensively investigated. The results showed that when the nFe₃O₄ dosage = 6 g L⁻¹, O₃ dosage = 0.15 L minute⁻¹ and initial pH = 7, the total organic carbon, absorbance at 254 nm and colour number removal efficiencies were 40.58%, 62.55% and 89.80%, respectively. In addition, most of the humic- and fulvic-like substances in the SAARB effluent were removed, and the condensation degree, aromaticity and humification degree of the organics were substantially reduced. The morphology and elemental valence state analysis showed that the nFe₃O₄ in the process was relatively stable and could form an nFe₃O₄-organic complex. Therefore, the probability of organics reacting with hydroxyl radical increased and the oxidation efficiency was enhanced. In the continuous experiment, both the O₃ dosage and hydraulic retention time (HRT) were the key influencing factors. The treatment efficiency of the nFe₃O₄-O₃ process was enhanced at a higher O₃ dosage and longer HRT. The electrical energy consumption of the continuous nFe₃O₃-O₃ process was calculated to be 17.72 kW h m⁻³ in SAARB effluent treatment. This study proved the feasibility of biologically treated landfill leachate treatment by the nFe₃O₃-O₃ process.