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Abstract

Controlled synthesis of a new thermoplastic elastomer (TPE), poly(isobutylene-g-styrene) (PIB-g-PSt) was achieved by quasiliving atom transfer radical polymerization (ATRP). A new commercially available butyl rubber containing bromobenzyl moieties was used as macroinitiator for ATRP of styrene catalyzed by CuBr/2,20-bipyridine complex. Both bulk and solution polymerization resulted in well-defined graft copolymers as indicated by analyses with ¹H NMR and GPC. Phase separated morphology in these graft copolymers was found by DSC. Stress-strain analyses indicate high elongation and tensile strength for PIB-g-PSt grafts with certain composition. This new grafting process and the resulting TPE are candidates for several useful applications.

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References

1. Hsieh, H.L. and Quirk, R.P. (1996). Anionic Polymerization: Principles and Practical Applications. New York: Marcel Dekker.

2. Ivan, B. (1993). Makromol. Chem., Makromol. Symp., 67: 311.

3. Ivan, B. (1994). Macromol. Symp., 88: 201.

4. Georges, M.K. , Veregin, R.P.N. , Kazmaier, P.M. and Hamer, G.K. (1993). Macromolecules, 26: 2987.

5. Fukuda, T. , Terauchi, T. , Goto, A. , Ohno, K. , Tsujii, Y. , Miyamoto, T. , Kobatake, S. and Yamada, B. (1996). Macromolecules, 29: 6393.

6. Colombani, D. , Steenbock, M. , Klapper, M. and Mullen, K. (1997). Macromol. Rapid Commun., 18: 243.

7. Wayland, B.B. , Poszmik, G. , Mukerjee, S.L. and Fryd, M. (1994). J. Am. Chem. Soc., 116: 7943.

8. Wang, J.-S. and Matyjaszewski, K. (1995). J. Am. Chem. Soc., 117: 5614.

9. Kato, M. , Kamigaito, M. , Sawamoto, M. and Higashimura, T. (1995). Macromolecules, 28: 1721.

10.

10. Percec, V. , Barboiu, B. , Neumann, A. , Ronda, J.C. and Zhao, M. (1996). Macromolecules, 29: 3665.

11.

11. Haddleton, D.M. , Waterson, C. , Derrick, P.J. , Jasieczek, C.B. and Shooter, A.J. (1997). Macromolecules, 30: 2190.

12.

12. Gao, B. , Chen, X. , Ivan, B. , Kops, J. and Batsberg, W. (1997). Polym. Bull., 39: 559.

13.

13. Chen, X. , Ivan, B. , Kops, J. and Batsberg, W. (1997). Polym. Prepr., 38(1): 715.

14.

14. Coca, S. and Matyjaszewski, K. (1997). Macromolecules, 30: 2808.

15.

15. Gaynor, S.G. and Matyjaszewski, K. (1997). Macromolecules, 30: 4241.

16.

16. Hawker, C.J. and Mecerreyes, D. , Elce, E. , Dao, J. , Hedrick, J.L. , Barakat, I. , Dubois, P. , Jérô me, R. and Volksen, I. (1997). Macromol. Chem. Phys., 198: 155.

17.

17. Grubbs, R.B. , Hawker, C.J. , Dao, J. and Frechet, J.M. (1997). J. Angew. Chem., Int. Ed. Engl., 36: 270.

18.

18. Kennedy, J.P. and Charles, J.J. (1977). J. Appl. Polym. Sci., 30: 119.

19.

19. Nuyken, O. , Sanchez, J.R. and Voit, B. (1997). Macromol. Rapid Commun., 18: 125.

20.

20. Wang, H.C. and Powers, K.W. (February, 1992). Elastomerics, 22.

New Thermoplastic Elastomers by Quasiliving Atom Transfer Free Radical Grafting

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