A calculation scheme is proposed for assessing and predicting storage and loss moduli. The examination is based on atomic constants, which take into account the contribution of each atom and polar group and the van der Waals volume and shear modulus at high frequencies. The obtained relationship makes it possible to calculate the shear modulus and storage and loss moduli as a function of frequency, temperature, and molecular weight distribution.
AskadskiiA.A., Physical Properties of Polymers. Prediction and Control.Gordon and Breach, Amsterdam, 336 pp. (1996).
2.
AskadskiiA.A., and KondrashchenkoV.I., Computational Materials Science of Polymers. Vol. 1. The Atomic Molecular Level.Nauchnyi Mir, Moscow, 544 pp. (1999).
3.
AskadskiiA.A., Computational Materials Science of Polymers.Cambridge International Science Publishing, Cambridge, UK, 696 pp. (2003).
4.
AskadskiiA.A., and MatveevYu.I., The Chemical Structure and Physical Properties of Polymers.Khimiya, Moscow, 240 pp. (1983).
5.
RajuV.R., J. Polym. Sci., Polym. Phys. Edn, 17: 1183–1195 (1979).
6.
RochefortW.E., J. Polym. Sci., Polym. Phys. Edn, 17: 1197–1210 (1979).
