An Approach to Analysing the Influence of the Chemical Structure of the Solvents and their Concentration on the Glass Transition Temperature of the Polymer for Systems Containing a Polymer and Two Solvents
Restricted accessResearch articleFirst published online April, 2017
An Approach to Analysing the Influence of the Chemical Structure of the Solvents and their Concentration on the Glass Transition Temperature of the Polymer for Systems Containing a Polymer and Two Solvents
A scheme has been developed for calculating the glass transition temperature of a system containing a polymer and two different solvents. Account is taken of the chemical structure of the polymer and solvents (one of them may be a plasticiser), the intermolecular interaction between the polymer and solvents, and also between the solvents themselves, the van der Waals volume of the repeating unit of the polymer and molecules of both solvents, and their concentration.
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