Restricted accessResearch articleFirst published online 2017-4
An Approach to Analysing the Influence of the Chemical Structure of the Solvents and their Concentration on the Glass Transition Temperature of the Polymer for Systems Containing a Polymer and Two Solvents
A scheme has been developed for calculating the glass transition temperature of a system containing a polymer and two different solvents. Account is taken of the chemical structure of the polymer and solvents (one of them may be a plasticiser), the intermolecular interaction between the polymer and solvents, and also between the solvents themselves, the van der Waals volume of the repeating unit of the polymer and molecules of both solvents, and their concentration.
Get full access to this article
View all access options for this article.
References
1.
MatseevichT.A., Plast. Massy, in press.
2.
AskadskiiA.A., Computational Materials Science of Polymers.Cambridge International Science Publishing, Cambridge, UK (2003).
3.
AskadskiiA.A., and KondrashchenkoV.I., Computational Materials Science of Polymers. Vol. 1. Atomic-Molecular Level.Nauchnyi Mir, Moscow (1999).
4.
AskadskiiA.A., Lectures on the Physico-Chemistry of Polymers.Physics Faculty, Moscow State University, Moscow (2001).
5.
AskadskiiA.A., Lectures on the Physico-Chemistry of Polymers.Nova Science Publishers, New York, NY (2003).
6.
AskadskiiA.A., and KhokhlovA.R., An Introduction to the Physical Chemistry of Polymers.Nauchnyi Mir, Moscow (2009).
7.
AskadskiiA.A., The Physical Chemistry of Polymeric Materials and Methods for Investigating Them.Izd-vo ASV, Moscow (2015).
