An investigation was made of the kinetics of single-electron transfer from a pyrrole molecule to a peroxy disulphate ion in the initial period of oxidative polymerisation. It was shown that the reaction is second order, and the rate constants and activation energy of single-electron transfer were determined.
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References
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KumarD., and SharmaR.C., Eur. Polym. J., 34: 1053 (1998).