An examination is made of a method for producing symmetric 1,4-butanediol esters in the presence of catalyst titanium nanodioxide of grade R-25 with a surface area of 140.9 m2/g and a particle size of 25 nm by the esterification of 1,4-butanediol with aliphatic fatty acids. The esters obtained have been tested as a plasticiser for polyvinyl chloride (PVC).
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References
1.
KaradeN.N., An exceedingly efficient and chemoselective esterification with activated alcohols using AlCl3/NaI/CH3CN system. Synthetic Communications, (34): 3391–3396 (2004).
2.
HilalM., Naphthenate esters as PVC plasticisers – synthesis and evaluation of some esters. Erdol Kohle Erdgas Petrochemie, 48(1): 24 (1995).
3.
MurshudliC.D., Efficiency of extraction of petroleum acids in an extractor with sieve plates. Method of calculation. Chem. Technol. Fuels Oils, 38(5): 296 (2002).
4.
SadievaN.F., Asymmetric diethylene glycol esters of fatty acids as plasticisers for polyvinyl chloride. Plast. Massy, (11): 29–31 (2007).
5.
MinskerK.S., The chemistry of chloride-containing polymers: degradation stabilisation, syntheses, in New Horizons. Nova Science Publishers, Inc., Commack, NY, 200 pp. (2000).