New comb-shaped polymers containing side polyoxyethylene blocks were synthesised. For the case of model compounds, the possibility of using the polymers obtained as matrices of chemical optical sensors was assessed. The influence of the length and number of block substituents on the swelling of the polymers in water was investigated. Almost 100% binding of the model compounds by the polymer matrix was observed, and also the practically complete absence of hydrolysis of the model compounds for 1 h. The conducted investigations showed the promise of using the polymers obtained as matrices for chemical optical sensors.
CattrallR.W., Chemical Sensors.Oxford University Press, Oxford, UK (1997).
3.
EgginsB.R., Chemical Sensors and Biosensors.Wiley, New York, NY (2002).
4.
OehmeI., and WolfbeisO.S., Fundamental review – optical sensors for determination of heavy metal ions. Microchim. Acta, 126: 177–192 (1997).
5.
ChovelonJ.-M., and GrabchevI., A novel fluorescent sensor for metal cations and protons based on bis-1,8-naphthalimide. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 67(1): 87–91 (2007).
6.
CzamikA.W. (ed.), Fluorescent Chemosensors for Ion and Molecular Recogition. ACS Symposium Series 538, ACS, Washington, DC (1992).
7.
YanY., A novel azathia-crown ether dye chromogenic chemosensor for the selective detection of mercury(II) ion. Dyes and Pigments, 79(2): 210–215 (2008).
8.
BatistaR.M.F., Synthesis and evaluation of bipendant-armed (oligo)thiophene crown ether derivatives as new chemical sensors. Tetrahedron Lett., 49(46): 6575–6578 (2008).
9.
AdhikariB., and MajumdarS., Polymers in sensor applications. Prog. Polym. Sci., 29(7): 699–766 (2004).
10.
SavvinS.B., Optical chemical sensors (micro- and nanosystems) for analysis of liquids. Ros. Khim. Zh. (Zh. Ros. Khim. Ob-va im. D.I. Mendeleeva), LII(2): 7–16 (2008).
11.
ArmaregoW.L.F., and PerrinD.D., Purification of Laboratory Chemicals, 4th edition. Butterworth-Heinemann (1998).
12.
PanchenkoP.A., Synthesis and spectral-luminescent properties of 4-(acetyl)amino-N-arylnaphthalimides containing electron-donor groups in N-aryl substituent. Izv. Akad. Nauk Ser. Khim., 6: 1199–1206 (2009).
