This paper looks at patterns in the mechanical behaviour of plasticised poly(ether urethane ureas) over a wide range of relative air humidity values. In the presence of a plasticiser that lowers the solubility of rigid blocks in the flexible phase of the polymer, the stability of the mechanical characteristics of poly(ether urethane urea) with exposure to a humid atmosphere is shown to increase.
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References
1.
RameyJ.S., PorterR.A.Softening aid, flushing agent. Viscosity reducer, a study of plasticizers for polyurethanes. Polyurethane, 1995, 26, 9, 216–223.
2.
LiamkinD.I., MisiukK.G., PasternakV.Sh., Al'terYu.M., Vorob'evaT.V.On the relationship between thermomechanical and fatigue properties of polyurethane elastomers. Vysokomolekul. soed. B, 1997, 39, 3, 545–548.
TereshatovV.V., SenichevV.Yu., TereshatovaE.N., MakarovaM.A.The mechanism of the specific action of plasticizers and its effect on polyurethane properties. Handbook of plasticizers. Toronto – New York: ChemTec Publishing, William Andrew Publishing, 2004, 346–354.
6.
TereshatovA.V., FedchenkoV.V., TereshatovaE.N., MakarovaM.A., TereshatovV.V.Impact of the chemical structure of flexible blocks on the mechanical properties of poly(ether urethane ureas) in a humid environment. Zhurnal prikladnoi khimii, 2005, 78, 9, 1547–1550.
7.
TereshatovV.V., MakarovaM.A., VolkovaE.R., SenichevV.Yu.Impact of moisture sorption on the mechanical properties of segmented polyurethanes with urethane urea and urethane rigid blocks. Plasticheskie massy, 2008, 7, 7–9.
8.
GreenspanL.Humidity fixed points of binary saturated aqueous solutions. J. of Research of the National Bureau of Standards, Physics and Chemistry, 1977, 81A, 1, 89–96.
9.
By O'BrienF.E.M. M.A. Control of Humidity by saturated salt solutions.British electrical and allied industries research association: London, 1947, 73–76.
10.
Standard Practice for Maintaining Constant Relative Humidity by means of Aqueous Solutions. ASTM Standard E 104-85. Reapproved. 1991.
11.
Engineering design for plastics. Edited by BaerEricRheinhold Pub. Corp.: New York, 1964, 1202 pp.
12.
RazumovskiiL.P., IordanskiiA.L., ZolotovaE.V., TrezvovaA.V., FortunatovO.G., ZaikovG.E.Features of sorption-diffusion processes in segmented polyether urethanes. Vysokomolekul. soed. A, 1991, 33, 5, 989–996.