New polyazomethine esters were obtained by low-temperature polycondensation on the basis of aromatic dialdehydes and 4,4′-diaminotriphenylmethane in an aprotic solvent. The polymers synthesised are low-melting substances with good solubility in organic solvents and concentrated sulphuric acid. The optimum conditions for the production of high-molecular-weight polyazomethine esters were determined, and their mesomorphic properties were investigated.
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References
1.
MarvelC.S., and HillW.S.J. Am. Chem. Soc., 72: 4891 (1950).
2.
BanerjeeS., and GutchP.J. Polym. Sci., 33: 1719 (1995).
3.
LiC.H.J. Polym. Sci., 29: 1447 (1991).
4.
LeeK.S., and SamocM.Polym. Commun., 32: 361 (1991).
5.
SoninA.S., and ChurochkinaN.A.Vys. Soed., 50: 342 (2008).
6.
LiC.-H., and ChangT.-C.J. Polym. Sci., 28: 3625 (1990).
7.
ZalovaT.V., and BorukaevT.A.Plast. Massy, (10):22 (2008).
8.
UmanskiiYa.S.Crystallography, X-Ray Diffraction Analysis, and Electron Microscopy.Metallurgiya, Moscow, 632 pp. (1982).
