Abstract
A heterogeneous catalyst for the oxidation of small molecules has been prepared by the immobilization of PtII and PtIV complex compounds on the surface of amorphous macroporous silica. The structure of the surface platinum complex compounds has been established by means of vibrational and electronic spectroscopy while the catalytic activity of the catalyst was investigated for the hydrogen (or carbon monoxide) oxidation reaction by molecular oxygen under mild conditions.
References
1.
Bellamy
L.J.
(1957 ) The Infra-red Spectra of Complex Molecules , Methuen , New York .
2.
Belyakova
L.A.
Simurov
A.V.
(1995 ) Ukr. Khim. Zh . 61 , 24 .
3.
Belyakova
L.A.
Ivanova
V.G.
Lyashenko
D.Yu.
Simurov
A.V.
Tertykh
V.A.
(1992 ) USSR Pat. No. $1 776 433 (23 November).
4.
Ermakov
Yu.I.
Zakharov
V.A.
Kuznetsov
B.N.
(1980 ) Grafted Complexes on Oxide Carriers in Catalysis , Nauka , Novosibirsk .
5.
Gibson
D.
Lewis
I.
Oldman
C.
(1967 ) J. Chem. Soc. A 72 .
6.
Gorokhovatsky
Y.B.
Kornienko
T.P.
Shalya
V.V.
(1972 ) Heterogeneous–Homogeneous Reactions , Technical Press , Kiev .
7.
Iler
R.K.
(1979 ) The Chemistry of Silica , Wiley-Interscience , New York .
8.
Jannes
G.
(1975 ) Catalysis. Heterogeneous and Homogeneous , Elsevier , Amsterdam .
9.
Kreshkov
A.I.
Bork
V.A.
Bondarevskaya
E.A.
Myshlyaeva
L.V.
Syavtsillo
S.V.
Shemyatenkova
V.T.
(1962 ) Practical Guidebook in Analysis of Monomeric and Polymer Compounds , Gos. Nauchnotekh. Izd-vo khim. lit. , Moscow .
10.
Lever
A.B.P.
(1984 ) Inorganic Electronic Spectroscopy , Elsevier , Amsterdam .
11.
Lewis
I.
Long
R.
Oldman
C.J.
(1965 ) J. Chem. Soc. A 6740 .
12.
Lyashenko
D.Yu.
Belyakova
L.A.
(1993 ) React. Kinet. Catal. Lett . 50 , 333 .
13.
Nakamoto
K.
(1989 ) Infrared and Raman Spectra of Inorganic and Coordination Compounds , John Wiley & Sons , New York .
14.
Nalbandian
A.B.
Mantashian
A.A.
(1975 ) Elementary Processes in Slow Gas Phase Reactions , Academic Press of Armenia , Erevan .
15.
Peshkova
V.M.
Mel'chakova
N.V.
(1986 ) β-Diketones , Nauka , Moscow .
16.
Pukhnarevich
V.B.
Trofimov
B.A.
Kopylova
L.I.
Voronkov
M.G.
(1973 ) Zh. Obshch. Khim . 43 , 2691 .
17.
Speier
I.L.
(1979 ) Adv. Inorganometal. Chem . 17 , 407 .
18.
Ukharsky
A.A.
Berhman
A.D.
(1992 ) Kinet. Katal . 33 , 5 .
19.
Zharkova
G.I.
Igumenov
I.K.
Tkashyov
S.V.
Zemskov
S.V.
(1982 ) Koord. Khim . 8 , 74 .
