Results are presented of structural studies of a silica-based surface-porous adsorbent. It is shown that a reliable estimate of the size of the surface micropores of this adsorbent can be obtained using the gas chromatographic version of the molecular probe method. This is based on a comparison of the thermodynamic properties for the adsorption of substances of known molecular size on the surface-porous adsorbent with those characteristic for the adsorption of the same substances on to a non-porous adsorbent of a similar chemical nature.
Get full access to this article
View all access options for this article.
References
1.
AksenenkoE.V. and TarasevichYu.I. (1989) J. Phys. Chem. (USSR) 63, 2150 (in Russian).
2.
AksenenkoE.V. and TarasevichYu.I. (1993) Adsorp. Sci. Technol. 9, 54.
3.
BondarenkoS.V. (1981) Proc. Ukr. Acad. Sci., Ser. B 30 (in Ukrainian).
4.
BondarenkoS.V., NazarenkoA.V. and TarasevichYu.I. (1989) J. Appl. Chem. (USSR) 62, 1252 (in Russian).
5.
BreckD.W. (1974) Zeolite Molecular Sieves Wiley, New York.
6.
DubininM.M. (1970) in Basic Problems in Physical Adsorption Theory Nauka, Moscow, p. 251 (in Russian).
7.
DubininM.M. (1972) Adsorption and Porosity VACZ, Moscow (in Russian).
8.
KiselyovA.V. (1986) Intermolecular Interactions in Adsorption and Chromatography Vyshaja Shkola, Moscow (in Russian).
9.
KiselyovA.V. and YashinYa.I. (1969) Gas Adsorption Chromatography Plenum Press, New York.
10.
LisichkinG.V. (1986) Modified Silica in Adsorption, Catalysis and Chromatography Khimija, Moscow (in Russian).
11.
PatiukL.K., TarasevichYu.I., ZabolotnykhV.L., PanasevichA.A., MakarovA.M. and SemionovYu.F. (1982) Chem. Technol. Water (USSR) 4, 546 (in Russian).
12.
TarasevichYu.I., AksenenkoE.V. and BondarenkoS.V. (1992) J. Phys. Chem. (Russia) 66, 712 (in Russian).
13.
TarasevichYu.I., BondarenkoS.V., ZhukovaA.I., NazarenkoA.V. and AksenenkoE.V. (1993) Pure Appl. Chem. 65, 2257.
14.
ZhukovaA.I., KozlovaV.S., BondarenkoS.V. and TarasevichYu.I. (1989) J. Appl. Chem. (USSR) 62, 1311 (in Russian).
