Binary Adsorption of Vapours in Active Carbons Described by the Combined Theories of Myers—Prausnitz and Dubinin (II)

Abstract

The new MPD method, described recently, has been applied to the adsorption of benzene +1,2-dichloroethane vapours by a typical active carbon at 293 K. A total of 102 experiments have been carried out for adsorbed mole fractions between 0.06 and 0.94. Good agreement was found between the experimental and calculated values of the selectivity of the carbon for benzene, which decreased as the mole fraction of benzene increased. This variation reflects the heterogeneity of the carbon, which is taken into account by the DR equation. Although the liquid mixture is ideal, deviations from Raoult's law are observed in the adsorbed state, indicating a clear preference for benzene. The values of the activity coefficients obtained from the liquid/solid equilibrium improve the fit of the MPD method.