The introduction of 1.5 vol.% carbon dioxide into the reaction mixture (CO/H2 = 1:2) is shown to accelerate the rate of formation of methanol and the selectivity towards oxygen-containing products over palladium catalysts supported on oxides of various chemical natures. The maximum degree of impact of CO2 was observed over palladium supported on magnesia and zirconia.
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References
1.
ErdohelyiA.PasztorM.SolymosiF. (1986) J. Catal.98, 166.
2.
HermanR.G.KlierK.SimonsG.M. (1979) J. Catal.56, 407.
3.
PoutsmaM.L.ElekL.F.IbarbiaP.A. (1978) J. Catal.52, 157.
4.
RamarosonE.KifferR.KiennemannA. (1982) J. chim. Phys.79, 753.