Restricted accessResearch articleFirst published online 1996-8
Peculiarities Associated with the Adsorption of Alkyne Peroxides from Dimethyl Formamide/Water Solutions on to the Mercury Electrode in the Presence of Tetraethylammonium Cations
The adsorption of alkyne peroxides on to the surface of a mercury electrode from dimethyl formamide (DMFA)/water solutions in the presence of tetraethylammonium perchlorate [(C2H5)4NClO4] has been investigated by polarography and electrocapillarity techniques. It has been shown that the interfacial activity of these peroxides is determined by products arising from associative interactions both between these peroxides and DMFA and tetraethylammonium cations. Comparable estimations of the interfacial activity of various alkyne peroxides in the solutions studied have been made.
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