Studies of the Separation of Palladium(II) Microquantities from Macroquantities of Salts of other Elements on Selective Ion Exchangers

Abstract

The applicability of selective ion exchangers for the removal of palladium(II) from solutions of copper(II), nickel(II), aluminium(III) salts, hydrochloric acid, a mixture of hydrochloric and nitric acids as well as a mixture of hydrochloric acid and ammonium chloride has been studied by frontal analysis. The best results were obtained in the purification of copper(II) and nickel(II) salts on Chelite S with functional thiol groups, Duolite ES-346 with functional amidoxime groups and Lewatit TP-214 with functional thiourea groups. A decrease of palladium(II) content below 5 × 10⁻⁵% was obtained in the process of purification of macroquantities of these salts. In addition, these ion exchangers possess a considerable ion-exchange capacity (e.g. 3.18 mequiv. Pd/g for Lewatit TP-214) and a high resistance to mineral acids.