Abstract
An expression for the isosteric heat of the partially mobile monolayer adsorption of a single gas on a homogeneous adsorbent surface has been derived. Optimization of the model parameters has been performed for selected experimental systems.
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References
1.
Beebe
R.A.
Kiselev
A.V.
Tizon
R.F.S.
Holmes
J.M.
(1964 ) Zh. Fiz. Khim. 38 , 708 .
2.
Bezus
A.G.
Dreving
W.P.
Kiselev
A.V.
(1964 ) Zh. Fiz. Khim. 38 , 59 .
3.
Bowen
J.M.
Donohue
J.
(1958 ) Tables of Interatomic Distances and Configurations in Molecules and Ions ,
Mitchel
A.D.
Cross
L.C.
, Eds, The Chemical Society , London, UK .
4.
Fowler
R.H.
Guggenheim
E.A.
(1939 ) Statistical Thermodynamics , Cambridge University Press , Cambridge, UK .
5.
Garbacz
J.K.
Karpinski
K.
(1995 ) Pol. J. Chem. 69 , 400 .
6.
Garbacz
J.K.
Kopkowska
E.
Rymian
B.
(1991 ) Pol. J. Chem. 65 , 1825 .
7.
Garbacz
J.K.
Kopkowski
A.
Ziolkowska
D.
(1993 ) Pol. J. Chem. 67 , 119 .
8.
Garbacz
J.K.
Kopkowski
A.
Ziolkowska
D.
(1994 ) Adsorp. Sci. Technol. 11 , 31 .
9.
Hill
T.L.
(1946 ) J. Chem. Phys. 14 , 441 .
10.
Hill
T.L.
(1952 ) Adv. Catal. 4 , 211 .
11.
Linsen
B.G.
, Ed (1970 ) Physical and Chemical Aspects of Adsorbents and Catalysts , Academic Press , London/New York .
12.
Reiss
H.
Frisch
H.L.
Lebowitz
J.L.
(1959 ) J. Chem. Phys. 31 , 369 .
13.
Ross
S.
Olivier
J.P.
(1964 ) On Physical Adsorption , Interscience , New York .
14.
Shay
G.
(1953 ) Acta Chim. Acad. Sci. Hung. 3 , 511 .
15.
Shay
G.
(1956 ) J Chem. Phys. 53 , 691 .
