Abstract
Based on a summation to infinity of the virial expansion for the 2D compressibility factor, simple equations have been developed for adsorption isotherms, and heats of adsorption, of 2D dense mobile films adsorbed on solid surfaces. They have subsequently been generalized for the presence of an external, randomly varying potential field, created by the random surface topography exhibited by heterogeneous solid surfaces.
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References
1.
Andrews
F.C.
(1976 ) J. Chem. Phys. 64 , 1941 .
2.
Antoniou
A.
(1986 ) J. Chem. Soc., Faraday Trans . 1 82 , 483 .
3.
Antoniou
A.
Scaife
P.H.
Peacock
J.M.
(1971 ) J. Chem. Phys. 54 , 5403 .
4.
Antoniou
A.
Scaife
P.H.
Peacock
J.M.
(1976 ) J. Chem. Phys. 64 , 4901 .
5.
Bergman
E.
(1974 ) J. Phys. Chem. 78 , 405 .
6.
Bojan
M.J.
Steele
W.A.
(1988 ) Surf. Sci. 199 , L395 .
7.
Campbell
C.E.
Dash
J.G.
Schick
M.
(1971 ) Phys. Rev. Lett. 26 , 966 .
8.
Cohran
T.W.
Kabel
R.L.
Danner
R.P.
(1985 ) AIChE J . 31 , 268 .
9.
Dash
J.G.
(1975 ) Films on Solid Surfaces , Academic Press , New York .
10.
Dash
J.G.
Puff
R.D.
(1981 ) Phys. Rev. B 24 , 295 .
11.
Devonshire
A.D.
(1937 ) Proc. R. Soc. London, Ser. A 163 132 .
12.
Everett
D.H.
(1964 ) Discuss. Faraday Soc . 40 , 177 .
13.
Fehder
P.L.
(1969 ) J. Chem. Phys. 50 , 2017 .
14.
Fehder
P.L.
(1970 ) J. Chem. Phys. 52 , 791 .
15.
Findenegg
G.H.
(1986 ) Proc. 2nd Int. Conf. Fundamentals of Adsorption ,
Liapis
A.I.
Everett
D.H.
Sing
K.S.W.
Eds, Engineering Foundation , New York .
16.
Heinbuch
U.
Fischer
J.
(1986 ) Proc. 2nd Int. Conf. Fundamentals of Adsorption ,
Liapis
A.I.
Everett
D.H.
Sing
K.S.W.
Eds, Engineering Foundation , New York .
17.
Helfand
E.
Frisch
H.L.
Lebowitz
J.L.
(1961 ) J. Chem. Phys. 34 , 1037 .
18.
Hill
T.L.
(1946 ) J. Chem. Phys. 14 , 268 .
19.
Holleran
E.M.
(1967 ) J. Chem. Phys. 47 , 5318 .
20.
Holleran
E.M.
(1968 ) J. Chem. Phys. 49 , 39 .
21.
Hyun
S.H.
Danner
R.P.
(1982 ) J. Chem. Eng. Data 27 , 196 .
22.
Klein
J.R.
Cole
M.W.
(1985 ) Faraday Discuss. Chem. Soc. 80 , 71 .
23.
Kuro-Oka
M.
Suzuki
T.
Nitta
T.
Katayama
T.
(1984 ) J. Chem. Eng. Jpn. 17 , 590 .
24.
Lado
F.
(1969 ) J. Chem. Phys. 9 , 3092 .
25.
McAlpin
J.J.
Pierotti
R.A.
(1964 ) J. Chem. Phys. 41 , 68 .
26.
Monson
P.A.
Steele
W.A.
Henderson
D.
(1981 ) J. Chem. Phys. 74 , 6431 .
27.
Morrison
J.A.
(1985 ) Faraday Discuss. Chem. Soc. 80 , 7 .
28.
Novaco
A.
(1972 ) J. Low Temp. Phys. 9 , 457 .
29.
Pierotti
R.A.
(1969 ) Vac. Microbalance Tech . 6 , 1 .
30.
Poshkus
K.
(1965 ) Discuss. Faraday Soc . 41 , 200 .
31.
Prasad
S.D.
Toxvaerd
S.
(1980 ) J. Chem. Phys. 72 , 1689 .
32.
Ree
F.H.
Hoover
H.G.
(1967 ) J. Chem. Phys. 46 , 418 .
33.
Rosenbluth
M.N.
Rosenbluth
A.W.
(1954 ) J. Chem. Phys. 22 , 881 .
34.
Ross
S.
Morrison
I.D.
(1975 ) Surf. Sci. 52 , 103 .
35.
Ross
S.
Olivier
J.P.
(1964 ) On Physical Adsorption , Interscience , New York .
36.
Rowley
L.A.
Nicholson
D.
Parsonage
N.G.
(1976 ) Mol. Phys. 31 , 389 .
37.
Rudzinski
W.
Jagiello
J.
(1982 ) J. Low Temp. Phys. 48 , 307 .
38.
Rudzinski
W.
Michalek
J.
Brun
J.
Partyka
S.
(1987 ). J. Chomatogr. 406 , 295 .
39.
Rudzinski
W.
Patrykiejew
A.
Narkiewicz
J.
(1978a ) Z. Phys. Chem. (Leipzig) 259 , 377 .
40.
Rudzinski
W.
Sokolowski
S.
(1977 ) Surf. Sci. 65 , 593 .
41.
Rudzinski
W.
Sokolowski
S.
(1978b ) Acta Phys. Pol. A 53 , 201 .
42.
Sokolowski
S.
(1978 ) J. Colloid Interface Sci . 66 , 399 .
43.
Sokolowski
S.
(1980 ) Mol. Phys. 41 , 859 .
44.
Sokolowski
S.
Steele
W.A.
(1985a ) J. Chem. Phys. 82 , 2499 .
45.
Sokolowski
S.
Steele
W.A.
(1985b ) J. Chem. Phys. 82 , 3413 .
46.
Speedy
R.J.
(1977 ) J. Chem. Soc. Faraday Trans . 2 75 , 714 .
47.
Steele
W.A.
(1966 ) The Gas-Solid Interface ,
Floody
E.A.
Ed, Vol. 1 , Chap. 10, Dekker , New York .
48.
Steele
W.A.
(1974 ) The Interaction of Gases with Solid Surfaces , Pergamon , Oxford .
49.
Steele
W.A.
Karl
R.
(1968 ) J. Colloid Interface Sci . 28 , 397 .
50.
Suwanayuen
S.
Danner
R.P.
(1980 ) AIChE J . 26 , 68 .
51.
Thorny
A.
Duval
X.
Reginer
J.
(1981 ) Surf. Sci. Rep. 1 , 1 .
52.
Tompkins
F.C.
(1950 ) Trans. Faraday Soc . 46 , 569 .
53.
Toxvaerd
S.
(1974 ) Mol. Phys. 29 , 373 .
54.
Tsien
F.
Valleau
J.P.
(1974 ) Mol. Phys. 27 , 174 .
55.
Weeks
J.D.
Chandler
D.
Anderson
H.C.
(1971 ) J. Phys. Chem. 54 , 5237 .
56.
Weeks
J.D.
Chandler
D.
Anderson
H.C.
(1976 ) Adv. Chem. Phys. 34 , 105 .
