Sorption uptake of propane and n-hexane on ZSM-5 type zeolite monocrystals has been investigated at 313 K and 323 K, respectively, by means of a constant-volume/variable-pressure method. In the case of propane no reliable information on the molecular mobility could be found. The intracrystalline diffusivity of n-hexane in the Na,H-ZSM-5 zeolite sample is 10−8 to 10−9 cm2s−1.
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References
1.
BülowM.MietkW.StruveP.LorenzP. (1983) J. Chem. Soc. Faraday Trans. I., 79, 2457.
2.
BülowM.StruveP.MietkW.KočiřikM. (1984) J. Chem. Soc. Faraday Trans. I., 80, 813.
3.
CaroJ.BülowM.SchirmerW.KärgerJ.HeinkW.PfeiferH.ŻdanovS. P. (1985) J. Chem. Soc. Faraday Trans. I., 81, 2541.
4.
ChiangA. S.DixonA. G.MaY. H. (1984) Chem. Eng. Sci., 39, 1461.
5.
ParavarA.HayhurstD. T. (1984) Proc. 6th Intern. Zeolite Conf. (eds. OlsenD.BisioA.) Butterworths, Guildford, p. 217.
6.
StruveP.KočiřikM.BülowM.ZikánováA.BezusA. G. (1983) Z. phys. Chem. Leipzig., 264, 49.
