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Abstract

Ultrahigh molecular weight polyethylene UHMW-PE fibers intended to be used as reinforcing fillers in elastomers were subjected to ionizing radiation vulcanization to avoid the deleterious effect of conventional sulfur vulcanization conditions, i.e., vulcanization temperature on the properties of polyethylene fibers. Thus, UHMW-PE fibers (Spectra™ 1000) were subjected to both gamma as well as electron beam radiation in absence of air and up to 250 kGy. Changes in melting (T_m) and crystallization temperature (T_c) enthalpy of melting and crystallization depending on the type and dose of radiation were followed up using differential scanning calorimetry (DSC). In addition to the observed decrease in tensile strength, decrease in fiber diameter and increase in modulus depending on radiation dose were correlated with the changes in fiber morphology.

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References

1. Briggs, D. , D. M. Brewis and H. B. Konieczko . 1976. J. Mater. Sci., 11:1270.

2. Briggs, D. , D. M. Brewis , J. Comyn , R. J. Dahm , M. A. Green and M. B. Konieczko . 1980. Surface Interface Anal., 2:107.

3. Brewis, D. M. and D. Briggs . 1981. Polymer, 22:7.

4. Yamakawa, S. and F. Yamamoto . 1980. J. Appl. Polym. Sci., 25:41.

5. Morris, C. E. M. 1970. J. Appl. Polym. Sci., 14:2171.

6. Ladizesky, N. H. and I. M. Ward . 1983. J. Mater. Sci., 18:33.

7. Shaker, M. , E. M. Abdel-Bary and I. Kamel . 1995. J. of Elastomers and Plastic Engineering, 27(April):117.

8. Rostami, H. 1988. "Surface Modification, Interfacial Testing and Matrix Processing of Fiber Reinforced Composites," Ph.D. thesis, Drexel University, Philadelphia, PA.

9. Chapiro, A. 1955. J. Chim. Phy., 52:246.

10.

10. de Boer, J. and A. J. Penning . 1983. Colloid and Polymer Sci., 261:750.

11.

11. de Boer, J. , P. F. Van Hutten and A. J. Penning . 1984. J. Mater. Sci., 19:428.

12.

12. Ungar, G. and A. Keller . 1980. Polym., 21:1273.

13.

13. de Boer, J. and A. J. Penning . 1981. Polymer Bull., 5:317.

14.

14. Kamel, I. and L. Finegold . 1985. Radiation Phys. Chem., 26:685.

15.

15. Charlesby, A. 1960. Atomic Radiation and Polymers, Chap. 13. New York: Pergamon Press.

16.

16. Charlesby, A. and N. H. Hancock . 1953. Proc. Royal. Soc. London, A., 218:245.

17.

17. Manelelkern, L. 1972. In The Radiation Chemistry of Macromolecules, Vol. 1., Edited by Dole , New York: Academic Press, pp. 290-293.

18.

18. Slichterand, W. P. and E. R. Mandell . 1958. J. Phys. Chem., 62:334.

Effect of Ionizing Radiation on the Properties of Ultrahigh Molecular Weight Polyethylene Fibers

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