The soft segment of poly (polyamide-polytetramethylene glycol) esters crystallize at strains beginning at about 500%, raising the observed crys tal melting temperature from about 7 to 38°C. Accompanying the strain- induced crystallization, the polymer hardens, changing from elastic to plastic. Upon melting of the PTMO crystallites, Pebax reasserts its elastic character.
Get full access to this article
View all access options for this article.
References
1.
Estes, G.M., S.L. Cooper and A.V. Tobolsky.1970. J Macromol. Sci.—Revs. Macromol. Chem. , C4:313.
2.
Hesketh, T.R. , J.W.C. Van Bogart and S.L. Cooper, 1980. Poly. Eng. and Sci., 20:190.
3.
Wilkes, G.R. , S. Bagrodia, W. Humphries and R. Wildnauer.1975. J. Poly. Sci.: Pol. Let. Ed., 13:321.
4.
Folkes, M. J., ed. 1985. Processing, Structure, and Properties of Block Copolymers, London: Elsevier.
5.
5. Foy, P. and R. Kern. 1978. U.S. Patent 4,115,475.
6.
6. Foy, P., C. Jungblut and G. Deleens. 1980. U.S. Patent 4,230,838.
7.
Deleens, G.1984. Private communication.
8.
1984. Technical Information, Pebax, Atochem.
9.
Faruque, H.S. and C. Lacabanne.1987. J. Mat. Sci., 22:675.
10.
Tadokoro, H.1979. Structure of Crystalline Polymers, New York: Wiley-Interscience, p. 362.
11.
11. Pohl, F. K. and P. Meissner. 1953. Ger. Patent 944,181.
12.
Flory, P.J.1953. Principles of Polymer Chemistry, Ithaca, New York: Cornell Univ. Press, p. 437.