Methods for quickly determining the cure state of peroxidecured compounds used in dielectric cables are investigated. The properties measured as indicators of cure state include percentage heat distortion, percentage extractables, and percentage residual peroxide (PRP). High pressure differential scanning calorimetry seems to offer a promising method for measuring PRP, and might be applicable to process control and to other polymer systems cured using thermal initiators.
Get full access to this article
View all access options for this article.
References
1.
“Crosslinked Thermosetting Polyethylene Insulation for Wire and Cable”, ASTM Methods D2655- and D2656-70.
2.
“Crosslinked-Thermosetting Polyethylene Insulated Wire and Cable for the Transmission and Distribution of Electrical Energy”, IPCEA Pub. No. S-66-524, National Electrical Manufacturers Association, New York, May 1971.
3.
“Specifications for PE and XLPE Insulated Shielded Power Cables Rated 5 Through 69-KV”, 4th Ed, AEIC No. 5–74, Assoc. of Edison Illuminating Companies, New York, June 1974.
4.
“Degree of Crosslinking in Crosslinked Ethylene Plastics as Determined by Solvent Extraction”, ASTM Method D2765–68.
5.
“Iodometric Assay Methods for Dicupr; Dicumyl Peroxide”, Bulletin ORC-205C, Organics Dept, Hercules Inc, Wilmington, Del. 19899.