Polyvinyl chloride is the most common polymer for organosols Sec ond to PVC are the acrylics Polymer particles of colloidal size required for microgel formation can be formed by standard emulsion polymerization techniques. Effect of the solvent on film formation and the coating is important. Judicious choice of solvent must include : Thermodynamic stability of the sol, coalescence and evaporation during baking, and viscosity dictated by applications requirements.
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References
1.
M. L. Huggins, Physical Chemistry of High Polymers, John Wiley, New York, 1958, Chaps. 5 and 6.
2.
W. R. Moore, An Introduction to Polymer Chemistry, Aldine, Chicago, 1963, p 99.
3.
R. M. Fitch , U. S. Patent 3,104,231, to E. I. du Pont de Nemours & Co.
4.
G. Natta and P. Corradini, J. Polymer Sci. 20, 251 (1956)
5.
P. Geil, Polymer Single Crystals, Interscience, New York, 1963, pp. 102-139.
6.
Colloidal and Morphological Behavior of Block and Graft Copolymers, G. E. Molan, Editor, Plenum, New York, 1971.
7.
T. Vaughn, et al., J. Am. Chem. Soc., 81, 240 (1952).
8.
R. J. Ceresa, Block and Graft Copolymers, Butterworths, Washington, 1962; (a) p. 158; (b) pp. 108-110.
9.
K. J. Mysels, Introduction to Colloid Chemistry, Interscience, New York , 1959, p. 77.
10.
(a) D. H. Napper, J. Colloid Interfac. Sci . 32(1) 106-114 (1970),
11.
(b) D. H. Napper, Kolloid Z & Z fur Polymere234 (2) 1149-1158(1970).
12.
(c) E. J. Clayfield and E.C. Lumb, J. Colloid Interfac. Sci. 22 , 269-284 (1966).
13.
E. J. W. Verwey & J. Th. G. Overbeek, Theory of the Stability of Lyophobic Colloids, Elsevier, Amsterdam, 1948.
14.
D. W. J. Osmond, Brit. Pat. 1,052,241.
15.
D. W. J. Osmond, F.A. Waite, D.J. Walbridge & H.H. Thompson, to Imperial Chemical Ind., Brit. Pats. 893,429; 941,305; 1,123,611; 1,122,397; and 1,052,241.
16.
K.E.J. Barrett and H.R. Thomas, J. Polym. Sci ., Part A-1, 7, 2621-2650 (1969 ).
17.
R. M. Fitch and C. H. Tsai, Polymer Colloids, R. M. Fitch, Editor, Plenum, New York, 1971, pp. 73-116.
18.
R M. Fitch, M.B. Prenosil and K.J. Sprick, J. Polym. Sci., Part C, 27, 95-118 (1969)
19.
. V. K. LaMer and R.H. Dinegar, J. Amer. Chem. Soc . 72, 4847-4854 (1950).