Dynamic dielectric properties of nickel (Ni)/epoxy composites are investigated by broadband dielectric spectroscopy over a wide frequency range (approximately 1–107 Hz) and temperature range (approximately −20 to 200°C). Multiple dielectric relaxation processes in the Ni/epoxy composites are identified, corresponding to conductivity, interfacial polarization (IP), and α-relaxation. With increasing temperature, both dielectric permittivity and loss of composites increase, arising from enhanced dipolar mobility; approaching the glass transition temperature (Tg), a clear α-relaxation appears, which can be attributed to the onset of cooperative chain movement. Further increasing temperature activates the long-range movement of space charges, as manifested by an IP superimposed on the ionic conductivity. A transition from insulator (below Tg) to semiconductor (above Tg) is also observed for the studied composite system.
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