Confocal Raman microspectroscopy is capable of measuring the density and birefrin gence of the poly(ethylene terephthalate) (PET) core of a PET/polypropylene core/shell fiber. Sample preparation is simple and data collection times are short. This technique should prove valuable in furthering the development of bicomponent fibers.
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References
1.
Adar, F., and Noether, H., Raman Microprobe Spectra of Spin-oriented and Drawn Filaments of Poly(ethylene Terephthalate), Polymer26, 1935-1943 (1985 ).
2.
Bulkin, B.J. , DeBlase, F.J., McKelvy , M.L., and Lewin, M., Low-frequency Raman Spectra of Poly(ethylene Terephthalate), J. Polym. Sci. Poly. Lett. Ed.23, 109-115 (1985).
3.
Bulkin, B.J. , Lewin, M., and DeBlase, F.J., Conformational Change, Chain Orientation, and Crystallinity in Poly(ethylene Terephthalate) Yarns: Raman Spectroscopic Study , Macromolecules18, 2587-2594 (1985 ).
4.
DeVries, H., A. NewApproach to the Continuum Theory of Birefringence of Oriented Polymers, Colloid Polym. Sci.257, 226-238 (1979).
5.
Everall, N., Tayler, P., Chalmers, J.M., MacKerron, D., Ferwerda, R., and van derMaas, J. H., Study of Density and Orientation in Poly(ethylene Terephthalate) Using Fourier Transform Raman Spectroscopy and Multivariate Data Analysis , Polymer35, 3184-3192 (1994 ).
6.
Kikutani, T. , Radhakrishnan, J., Arikawa , S., Takaku, A., Okui, N., Jin, X., Niwa, F., and Kudo, Y., High-Speed Melt Spinning of Bicomponent Fibers: Mechanism of Fiber Structure Development in a Poly(ethylene Terephthalate)/ Polypropylene System, J. Appl. Polym. Sci.62, 1913-1924 (1996).
7.
Melveger, A.J. , Laser-Raman Study of Crystallinity Changes in Poly(ethylene Terephthalate), J. Polym. Sci.A-210, 317-322 (1972).
8.
Natarajan, S. , Characterization of Poly(ethylene Terephthalate) Fibers Using Raman Microscopy, Masters thesis, Georgia Institute of Technology, 1998.
9.
Natarajan, S. , and Michielsen, S., Correlations of the Density and Birefringence of Poly(ethylene Terephthalate) with the Raman Spectra, J. Appl. Polym. Sci.73, 943-952 ( 1999).
10.
Tabaksblat, R., Meier, R.J., and Kip, B.J., Confocal Raman Microspectroscopy: Theory and Application to Thin Polymer Samples, Appl. Spectros.46, 60-68 (1992).