A neural network is used to predict the concentrations of three dyes from their spectrophotometric absorbances. With this technique, the network achieves a peak of 5% and an average of 2.6% error over a range of dye concentrations of 0 to 0.15 g/l. The neural network is evaluated against two other models based on Beer's law, and performs significantly better over the entire range of concentrations measured.
Get full access to this article
View all access options for this article.
References
1.
Beck, K., Madderra, T., and Smith, B., Real-time Data Acquisition in Batch Dying. Textile Chem. Color.23 (6), 23 (1991).
2.
Christian, G.D., "Analytical Chemistry," 4th ed. Wiley, New York, 1986.
3.
Freeman, James A., and Skapura, David M. , "Neural Networks: Algorithms, Applications, and Programming Techniques," Computation and Neural Systems Series. Addison-Wesley Publishing Company, Inc., Reading, MA , 1991.
4.
Haaland, David , and Thomas. Edward, Partial Least-squares Methods for Spectral Analyses, Anal. Chem.60 (11), 1193-1202 (1988).
5.
Hamada, K., Nonogake, H., Fukushima, Y., Munkhbat, B., and Misuishi, M., Effects of Hydrating Water Molecules on the Aggregation Behavior of Azo Dyes in Aqueous Solutions, Dyes Pigments16 ( 2 ), 113 ( 1991 ).
6.
Johnson, Alan, Ed., "The Theory of Coloration of Textiles," 2nd ed., ch. 2, Society of Dyers and Colourists, West Yorkshire, England, 1989, pp. 147-149.
7.
Kobayashi, Michio , Maeda, Yoshio, Hoshi, Toshihiko, Okubo, Jun, and Tanizaki, Yoshie, Analysis of the Electronic Absorption Spectrum of Adsorbed Layers of Methylene Blue, J. Soc. Dyers Colour.105 (10), 362-368 (1989).
8.
Leighton, Russell R., "The Aspirin/Migraines Neural Network Software User's Manual," 66.0 ed., MITRE Corporation, October 1992.
9.
McClelland, James L., and Rumelhart, David E., "Parallel Distributed Processing," vol. 1 and 2, The MIT Press, Cambridge, MA, 1986 .
10.
McClelland, James L., and Rumelhart, David E., "Explorations In Parallel Distributed Processing—A Handbook of Models, Programs, and Exercises." includes Software for IBM PC, The MIT Press, Cambridge, MA, 1988.
11.
Neale and Stringfellow, The Absorption by Cellulose of Mixtures of Direct Cotton Dyes. J. Soc. Dyers Colour.59 (11), 241 (1943 ).
12.
Neter, John, Wasserman, William, and Kutner, Michael, "Applied Linear Statistical Models," 3rd ed., ch. 7, Irwin. Boston, MA, 1990, pp. 225-237.
13.
Parker, D.B., Learning Logic, Tech. Rep. TR-47, Center for Computational Research in Economics and Management Science, MIT, Cambridge, MA, April 1985.
14.
Shenai, V.A. , and Shah, M.G., Colourimetric Estimation of Dyes in Binary Mixtures, Textile Dyer Printer12 (6), 351 (1979).
15.
Wagner, Rigina Sue, and McNeill, Joey, Utilizing New Technology to Improve Textile Laboratory Performance, in "AATCC International Conference and Exhibition." Philadelphia, PA, 1989, 288-294.
16.
Werbos, P., Beyond Regression: New Tools for Prediction and Analysis in the Behavioral Sciences, Doctoral thesis. Harvard, Cambridge, MA, August 1974.