Increased molecular weight and branching agents are used in melt spinning partially oriented nylon 66. The fiber solidifies more rapidly during spinning and has larger crystallites and increased elongation-to-break versus conventional PON, consistent with a stress-induced crystallization mechanism. When textured, the fiber produces higher crimp. Gains in both spinning and texturing productivity are documented.
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References
1.
AdamsE. B., Polyhexamethylene Adipamide Yarn, U.S. patent 3994121, October 30, 1976.
2.
BlackW. B.WuW. L., Eds., Symposium issue: Stress Induced Crystallization, Part II, Polym. Eng. Sci.19, 385–468 (1979).
3.
ChamberlinJ. M.ChilversE. W.NunningW. J.SouthernJ. H., Partially Oriented Nylon Yarn and Process, U.S. patent 4583357, April 22, 1986, reissue 33059, September 19, 1989.
4.
CogswellF. N., “Polymer Melt Rheology,”John Wiley, New York, 1981, pp. 81–83.
5.
GargS. K., Critical Stress for Crystallization in the Threadline during High-Speed Spinning of Poly (ethylene Terephthalate), J. Appl. Polym. Sci.29, 2111–2116 (1984).
6.
HostetterB. J., Branched Polyolefin as a Quench Control Agent for Spin Melt Compositions, U.S. patent 4626467, December 2, 1986.
7.
KoschinekG., Process for High-Speed Spinning of Polyamides, U.S. patent 4181697, January 1, 1980.
8.
KoyamaK.SuryadavaraJ.SpruiellJ. E., The Effect of Molecular Weight on High Speed Melt Spinning of Nylon 6, J. Appl. Polym. Sci.31, 2203–2229 (1986).
9.
MacLeanD. L.EstesR. T., High Draw Ratio Polyester Feed Yarn and its Draw Texturing, U.S. patent 4092299, May 30, 1978.
10.
MacLeanD. L.EstesR. T., Polyester Filament-Forming Polymer and its Method of Production, U.S. patent 4113704, September 12, 1978.
11.
MeadW. T., Ed., Symposium issue: Crystallinity Control and Polymer Mechanics, Polym. Eng. Sci.18, 429–548 (1978).
12.
NunningW. J.PlischkeL. W.SelivanskyD.SouthernJ. H.WuC. C., Partially Oriented Nylon Yarn and Process, U.S. patent 4721650, January 26, 1988.
13.
ShimizuJ.OkuiN.KikutaniT.ToriumiK., High Speed Melt Spinning of Poly(ethylene) Terephthalate (PET): Effect of Molecular Weight, Sen-I Gakkaishi, 34, T93–98 (1978).
14.
ShimizuJ.OkuiN.TamakiS.ImaiY.TakakuA., The High Speed Melt Spinning of Nylon 66: Fine Structure and Mechanical Properties, Sen-I Gakkaishi41, T101–108 (1985).
15.
SimpsonP. G.SouthernJ. H.BallmanR. L., Nylon 6,6 Fiber Tensile Properties as a Function of Morphology, Textile Res. J.51, 97–100 (1981).
16.
SmithR. L.PietersR.MorrisonM. E., Fundamentals of False-twist Texturing of Thermoplastic Continuous Filament Yarns, Trans. Soc. Rheol.16, 557–576 (1972).
ThwaitesJ. J., The Mechanics of Friction Twisting, J. Textile Inst.61, 116–138 (1970).
19.
WalzakZ., “Formation of Synthetic Fibers,”Gordon and Breach, New York, 1977.
20.
WhiteJ. L.CakmakM., Orientation Development and Crystallization in Melt Spinning of Fibers, Adv. Polym. Technol.6, 295–338 (1986).
21.
ZiabickiA., “Fundamentals of Fiber Formation,”John Wiley, New York, 1976.
22.
ZiabickiA.KawaiH., Eds., “High Speed Fiber Spinning,”John Wiley, New York, 1985.
23.
ZieminskiK.SpruiellJ. E., On-line Studies and Computer Simulation of the Melt Spinning of Nylon 66 Filaments, J. Appl. Polym. Sci.35, 2223–2245 (1988).