If a certain solubilization of lipoproteic material takes place during treatments of knitted wool fabrics with sodium sulphite in an isopropanol/water medium, and if these treatments prevent wool shrinkage at some particular conditions of solvent con centration and temperature, then a relationship exists between the dissolved lipoproteic material and the shrinkproofing effect. The lipids of the fiber play an important role in obtaining this effect.
Get full access to this article
View all access options for this article.
References
1.
Anderson, C.A. , and Leeder, J.D., Residual Lipid Contaminants in Processed Wool: The Composition of the Free Fatty Acids in Wool Fabric , Textile Res. J.35,416-421 (1965).
2.
Bartlett, G.R. , Phosphorus Assay in Column Chromatography , J. Biol. Chem.234, 466 (1959).
3.
Bradbury, J.H. , Leeder, J.D., and Watt, I.C., TheCell Membrane Complex of Wool, Appl. Polym. Symp.18, 227-236 (1971).
4.
Burton, R.M. , "Fundamentals of Lipid Chemistry," R. M. Burton and F. C. Guerra, Eds., 1974, p. 13.
5.
Crabtree, H.E. , Nicholls, P., and Truter, E.V., Identification of Internal Lipids of the Wool Fibre by Thin-layer Chromatography, Proc. Analyt. Div. Chem. Soc.16, 235-236 (1979).
6.
Coderch, M.L. , Erra, P., Juliá , M.R., Infante, M.R., and Garcia Dominguez , J.J., Analysis of Some Morphological Components Extracted from Wool Submitted to Shrink-resist Treatments , in "Proc. 7th. Int. Wool Text. Res. Conf. Tokyo ," vol. IV, 1985, pp. 252-261.
7.
de Fries, W. , Altenhofen, U., Föhles , J., and Zahn, H., A Protein Chemical Investigation of the Chlorine-Hercosett Process," J. Soc. Dyers. Colour.98, 13-16 (1983).
8.
Erra, P., Garcia Dominguez, J., Juliá, R., and Infante, R., Influence of an Organic Solvent and a Cationic Surfactant on Sulphite Treatments for Preventing Shrinkage of Wool Fabrics, Textile Res. J.53 (11), 665-669 (1983).
9.
Farnworth, A.J. , Shrinkproofing of Wool with Reducing Agents , J. Soc. Dyers Colour. 77, 483-488 (1961).
10.
Fraser, R.D.B. , MacRae, T.P., Rogers , G.E., and Filshie, B.K., lipids in Keratiniscd Tissues, J. Mol. Biol.7,90-91 (1963).
11.
Jacin, H., and Mischkin, A.R., Separation of Carbohydrates on Borate-Impregnated Silica Gel G Plates , J. Chromatog.18, 170 (1965).
12.
Kearns, J.E., and Madaren, J.A., Alkaline Modifications of Wool in Mixed Solvents, in " Proc 6th Int. Wool Textile Res. Conf. Pretoria," II, 1980, pp. 379-389.
13.
Koenig, N.H. , and Friedman, M., Cupric Acetate Treatment for Shrinkage-Resistance of Wool, Textile Res. J.50, 7, 422-427 (1980).
14.
Leeder, J.D. , Bishop, D.J., and Jones, L.N., Internal lipids of Wool Fibers, Textile Res. J.53 (7), 402-407 (1983).
15.
Leeder, J.D. , and Rippon, J.A., Changes Induced in the Properties of Wool by Specific Epicuticle Modification, J. Soc. Dyers Colour . 105, 11-16 (1985).
16.
Makinson, K.R. , "Wool Shrinkproofing," Marcel Dekker, New York, 1979.
17.
Rivett, D.E. , Evans, D.J., Leeder , J.D., and Rippon, J.A., Separation and Analysis of the Surface Lipids of the Wool Fibre, in " Proc. 7th. Int. Wool Text. Res. Conf. Tokyo," vol. IV, 1985, pp. 332-341.
18.
Röper, K., Föbles, J., Peters, D., and Zahn, H., Morphological Composition of the Cutide from Chemically Treated Wool, Part II: The Role of the Cuticle in Industrial Shrinkproofing Processes," Textile Res. J.54, 262-270 (1984).
19.
Sabasrabudhe, M.R., Lipid Composition of Oats, J. Am. Oil Chem. Soc.56, 80-84 (1979).
20.
Schwan, A., and Zahn, H., Isolation and Properties of Cell Membrane Complexes in Wool and Hair (in German) , in "Proc. 6th. Int. Wool Text. Res. Conf. Pretoria ," 1980, II, pp. 29-41.
21.
Spei, M., TheMicrofibrillar Swelling of α-Keratins, Coll. Polym. Sci.262 (6) (1984).
22.
Vaskovsky, V.E., and Kostetsky , E.Y., Modified Spray for Detection of Phospholipids on Thin-layer Chromatograms, J. Lipid Res.9, 396 (1968).
23.
Zahn, H., Wool Is Not Keratin Only, in "Proc. 6th Int. Wool Text. Res. Conf. Pretoria," Plenary Lecture , 1980.