Indole-3 carboxaldehyde was isolated from aqueous extracts of cotton plant parts by HPLC. It was identified by its mass spectrum which was identical to that of an authentic sample of indole-3 carboxaldehyde. A mechanism to account for the mass spectral fragmentation pattern is proposed.
Get full access to this article
View all access options for this article.
References
1.
Gilbert, R.D. , Fornes, R.E., Wang, A., and Lee. K.S., The Isolation and Identification of Cotton Plant Components by High-Performance Liquid Chromatography, Textile Res. J.50, 29-33 (1980).
2.
Hedin, P.A., Thompson, A.C., and Gueldner, R.C., A Survey of the Volatile Constituents of Cotton Lint and Waste with Regard to Byssinosis, J. Agric. Food Chem.23, 698-703 (1975).
3.
Jeffs, P.W., and Lynn, D.G., Isolation andStructure of 1-Hydroxy-7-Methoxy-4-Isopropyl-1, 6-Dimethyl 1-2 (1H)-Naphthalenone from Cotton, J. Org. Chem.40, 2958-2960 (1975).
4.
Powers, J.C. , Mass Spectrometry of Simple Indoles, J. Org. Chem.33, 2044-2050 ( 1968).
5.
Silverstein, R.M., and Bassler, G.C., "Spectroscopic Identification of Organic Compounds," 2nd ed., Wiley-Interscience , New York, 1967, p. 31.
6.
Stipanovic, R.D., Wakelyn, P.J., and Bell, A.A., Lacinilene C, a Revised Structure and Lacinilene C-7 Methyl Ether from Gossypium Bracts, Phytochemistry14, 1041-1043 (1975).
7.
Wakelyn, P.J. , Stipanovic, R.D., and Bell, Jr. , A.A., Identification of Scopoletin in Dried Bract of the Cotton Plant, J. Agric. Food Chem.22, 567 (1974).