Elution of a variety of types of water-soluble solutes from gel-permeation columns of chopped native cotton and of Sephadex G-15 was studied. Evidence was obtained concerning (a) the fraction of internal water that is available as solvent water for selected types of solutes, (b) the sorption of strong donor and acceptor hydrogen-bonding solutes on cellulose and Sephadex surfaces, and (c) negative sorption (or repulsion) of carboxyl-containing solutes.
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References
1.
AggebrandtL. G.SamuelsonO., Penetration of Water-Soluble Polymers in Cellulose Fibers, J. Appl. Polym. Sci. 8, 2801–2812 (1964).
AllanG. G.ReifW. M., Fiber Surface Modification; the Stereotopochemistry of Ionic Bonding in Paper, Sven. Papperstidn. 74, 563–570 (1971).
4.
BlouinF. A.MartinL. F.RowlandS. P., Gel-Permeation Properties of Cellulose. Part III: Measurement of Pore Structure of Unmodified and of Mercerized Cottons in Fibrous Form, Textile Res. J. 40, 809–813 (1970).
5.
EliasH.-G., Multimerisation: Assoziation und Aggregation. III. Einflusz der Offenen Assoziation auf die Ungestorten Dimensionen von Polyathylenglykolen, Makromol. Chem. 103, 214–229 (1967).
6.
FlodinP.KupkeD. W., Zone Electrophoresis on Cellulose Columns, Biochim. Biophys. Acta21, 368–376 (1956).
7.
GillisR. G., Trideuteromethylation in Dimethyl Sulphoxide, Tetrahedron Lett. No. 12, 1413–1414 (1968).
8.
GranathK. A.KvistB. E., Molecular Weight Distribution Analysis by Gel Chromatography on Sephadex, J. Chromatogr. 28, 69–81 (1967).
9.
GrotteG., Passage of Dextran Molecules Across the Blood-Lymph Barrier, Acta Chir. Scand. Suppl. 211, 1–84 (1956).
10.
HermansP. H., “Physics and Chemistry of Cellulose Fibers with Particular Reference to Rayon,”Elsevier, New York, 1949, p. 20.
11.
LongsworthL. G., Diffusion Measurements, at 1°, of Aqueous Solutions of Amino Acids, Peptides and Sugars, J. Amer. Chem. Soc. 744155–4159 (1952).
12.
MartinL. F.BertoniereN. R.RowlandS. P., The Effects of Sorption and Molecular Size of Solutes Upon Elution From Polyhydroxylic Gels, J. Chromatogr. 64, 263–270 (1972).
13.
MartinL. F.BlouinF. A.RowlandS. P., Characterization of the Internal Pore Structures of Cotton and Chemically Modified Cottons by Gel Permeation, Sep. Sci. 6 (2) 287–296 (1971).
14.
NealJ. L.GoringD. A. I., Interaction of Cellulose with Liquid Water: Accessibility Determined from Thermal Expansion, J. Polym. Sci., Part C, 28, 103–113 (1969).
15.
NelsonR.OliverD. W., Study of Cellulose Structure and Its Relation to Reactivity, J. Polym. Sci., Part C, 36, 305–320 (1971).
16.
StoneJ. E.ScallanA. M., A Structural Model for the Cell Wall of Water-Swollen Wood Pulp Fibers Based on Their Accessibility to Macromolecules, Cellul. Chem. Technol. 2, 343–358 (1968).
17.
ThomasD. K.CharlesbyA., Viscosity Relationships in Solutions of Polyethylene Glycols, J. Polym. Sci. 42, 195–202 (1960).
18.
WadeC. P.RobertsE. J.RowlandS. P., Substantivity of Polyethylenimines on Cotton Fabric, Textile Res. J. 42, 158–160 (1972).