Crockfastness of three polyacrylate and two nitrile rubber pigment-printing binders was demonstrated to be dependent upon mechanical resistance of the pigmented binders to rubbing and adhesion of the binders to fabric. Of the tensile properties of binder films measured, higher 200% modulus correlated best with crockfastness of printed fabrics. With binders of nearly equal modulus, crockfastness was better if adhesion was better.
Get full access to this article
View all access options for this article.
References
1.
HarkinsW. D., “The Physical Chemistry of Surface Films,”Reinhold, New York, 1952, p. 42.
2.
OwensD. K.WendtR. C., Estimation of Surface Free Energy of Polymers, J. Appl. Polymer Sci.13, 1741–1747 (1969).
3.
VoyutskiiS. S., “Autohesion and Adhesion of High Polymers,”Interscience, New York, 1963, p. 38ff., p. 165ff.
4.
WarburtonC. E.Jr., Crockfastness of Polyacrylate Textile Pigment-Printing Binders: Effect of Binder Mechanical Properties and Adhesion to Fabric, J. Adhesion7, 109–119 (1975).
5.
WuS., Surface and Interfacial Tensions of Polymer Melts. H. Poly(methyl methacrylate), Poly (n-butyl methacrylate), and Polystyrene, J. Phys. Chem.74, 632–638 (1970).
6.
WuS., Polar and Nonpolar Interactions in Adhesion, J. Adhesion5, 39–55 (1973).