The use of Dimethylformamide-Trichloroethylene (DMF-TCE) as a solvent-nonsolvent mixture is suggested for the purification of acid and direct dyes of varying degrees of sulphonation. The dye purity was varied from 93% to 100% as indicated by the sodium analysis of the purified dyes. In addition to TCE the feasibility of various other solvents as precipitating agents was also qualitatively tested.
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References
1.
BoultonJ.DelphA. E.FothergillF.MortonT. H., Viscose Yarns: Affinity for Dyes, J. Textile Inst.24, 113–129 (1933).
2.
BrownJ. C., Paper Chromatography of Synthetic Dyes, J. Soc. Dyers Colorists, 76, 536–542 (1960).
3.
ChavanR. B., Studies in the Use of Solvent Mixtures for the Dyeing and Finishing of Cotton, Ph.D. thesis, University of Manchester, August 1974.
4.
GilesC. H.GreczekJ. J., A Review of Methods of Purifying and Analyzing Water-Soluble Dyes, Textile Res. J.32, 506–515 (1962).
5.
HallD. M.PerkinsW. S., Practical Methods for Purification of Anionic Dyes as their Sodium, Potassium, and Lithium Salts, Textile Res. J.41, 923–927 (1971).
6.
KissaE., Urea in Reactive Dyeing, Textiles Res. J.39, 734–741 (1969).
7.
LeminD. R., Quoted in Reference No. [10].
8.
RobinsonD.MillsH. A. T., The Colloid Chemistry of Dyes. Part I, Proc. Roy. Soc.A131, 576–595 (1931).