The effect of thermal energy on matrix mobility of oriented polyamide fibers can be determined by ATR infrared spec troscopy, broad-line nmr and DSC. A composite of these techniques are required for predicting the response of the polyamide fiber during dyeing and heat setting.
Alexander, L.E., "X-Ray Diffraction Methods in Polymer Science," New York City, John Wiley and Sons, 262-268 (1969).
2.
Anton, A., Detection of Polymer Transition Temperature by Infrared Absorption Spectrometry , ACS Polymer Preprints, 8, 873-880 (1967).
3.
Anton, A., Detection of Polymer Transition Temperature by Infrared Absorption Spectrometry , J. Appl. Poly. Sci., 12, 2117-2128 (1968 ).
4.
Anton, A., Transition Temperatures of N-Grafted Polyurethanes, Poly. Letters7, 215-218 (1969).
5.
Billmeyer, F.W., Jr., "Textbook of Polymer Science," New York City , John Wiley and Sons, 198-204 (1965).
6.
Carroll, B., "Physical Methods in Macromolecular Chemistry," Vol. 1, New York City, Marcel Dekker, 109164 (1969).
7.
Dismore, P.S. , Statton, W.O., Chain Folding in Oriented Nylon-6,6 Fibers , J. Poly. Sco. (C) 13, 133 -148 (1966).
8.
Fox, T.G., Flory, P.J., Second-Order Transition Temperatures and Related Properties of Polystyrene, I. Influence of Molecular Weight, J. Appl. Poly. Sci.21, 581 (1950).
9.
Fukuhara, S. , Suzuki, Y., Osmote, S., Studies of Tensile Strength, Heat-Shrinkage Force, and Crystallinity of Nylon-6 Tire Cords and Nylon-6 Films at Elevated Temperatures, J. Poly. Sci. (C), 873-879 (1968).
10.
Gibbs, J.H. , DiMarzio, E.A., Nature of the Glass Transition and the Glassy State, J. Chem. Phys.28, 373-383 (1958).
11.
Kovacs, A.J. , La Contraction Isotherme du Volume des Polymères Amorphes, J. Poly. Sci., 30, 131-147 (1958).
12.
Lynch, L.J. , Feughelman, N., "The Role of Water in the Segmental Mobility of Hydrophilic Fibers," J. Appl. Poly. Sci.14, 1394-1396 (1970).
13.
Statton, W.O. , Studies of Matrix Rigidity to Determine Intimate Morphology, J. Poly. Sci., (C) 3, 3-8 (1963).
14.
Weyland, H.G. , Hoftyzer, P.J., Van Krevelen , D.W., Prediction of the Glass Transition Temperature of Polymers, Polymer11, 79-87 (1970).