The chemical structure of the finish obtained from melamine-hased reagents depends primarily on the constitution of the reactant and the reaction conditions. Attempts are made to follow the reaction of these various reagents from the pad bath formulation to the finished fabric under reaction conditions of interest to the textile industry. Specific reactions discussed include hydrolysis, alkylation, demethylolation, and polymerization. The formation of oxydimethylene links from methylolated amides under acidic and basic conditions are considered and the conclusions applied to textile treat ments. Reaction conditions include those for conventional pad-dry-cure treatments and wet or steaming treatments.
Anderson, D.G. , Netzel, D.A., and Tassari, D.J.the Synthesis and Characterization of Monomeric Etherified Methylolated Melamines Using Gel Permeation Chroma tography and Proton Magnetic Resonance Spectroscopy. J. Appl. Polymer Sci.14, 30213032 (1970).
2.
Anderson, I.H. , Cawley, M., and Steedman, W., Melaminc Formaldehyde Resins I. An Examination of Some Model Compound Systems, British Polymer J.1, 2428 (1969).
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Anderson, I.H. , Cawley, M. and Steedman, W., Melamine Formaldehyde Resins. II. Thermal Degradation of Model Compounds and Resins, British Polymer J.3, 86-92 (1971)
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Berge, A., Gudmundsen. S., and Ugelstad, J., Melamine-Formaldehyde Compounds. I. The Alkaline Decomposition of Methylol Melamines and Methoxymethyl Melamines. European Polymer J.5, 171-183 (1969).
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Berge, A., Kvaeren, B., and Ugelstad, J., Melamine Formaldehyde Compounds. II. The Acid Decomposition of Methylol Melamines and Methoxymethyl Melamines. European Polymer J.6, 981-1003 (1970).
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Brace, N.O. and Mantell, G.J., Hydrophobic Compounds and Polymers from Long Chain Alkanamide-Formaldehy de Condensation Reactions, J. Org. Chem.26, 51765180 (1961).
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Dixon, J.K., Woodberry, N.T., and Costa, G.W., The Dissociation Constants of Melamine and Certain of its Compounds, J. Amer. Chem. Soc.69, 599-603 (1947).
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O'Brien, S.J. , Hagan, P.M., Nakajima, W.N., Roth, P.B., and White, D., Wet-Fixation Durable-Press Process Reactions with Cellulose, Textile Res. J.37, 288-297 (1967).
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Rawls, H.R., Klein, E., and Vail, S.L., The Relationship Between Polymer Elastic Properties and the Ability to Impart Improved Wrinkle Recovery to Cotton Fabric, J. Appl. Polymer Sci.15, 341-349 (1971).
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Rollins, M.L. , DeGruy, I.V., Hensarling, T.P., and Carra, J.H., Abrasion Phenomena in Durable-Press Cotton Fabrics. A Microscopial View, Textile Res. J.40. 903-916 (1970).
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Vail, S.L., Chemical and Physical Properties of Cotton Modified by N-Methylol Agents. I: Chemical Structure of the Modified Cotton, Textile Res. J.42, 360-367 (1972).
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Vail, S.L., Frick, J.G., and Reid, J.D., Further Study of Hypochlorite-Resistant Melamine-Type Finishes, Amer. Dyestuff-Reptr.51, 622-625 (1962).
21.
Vail, S.L. and Verburg, G.B., Chemical and Physical Properties of Cotton Modified by N-Methylol Agents. II: Influence of Degree of Cure on These Properties, Textile Res. J.42, 367-373 (1972).
