A technique of thin-layer chromatography is described wherein cellulose-reactive materials are cured on the cellulose adsorbent prior to development. The technique should prove useful as a rapid means of evaluating the reactivity or mechanism of action of cotton finishing agents.
Block, R.J., Durrum, E.L., and Zweig, G., "Paper Chromatography and Paper Electrophoresis," 2nd ed., New York, Academic Press , p. 345, 1958.
2.
"Cyanamide," American Cyanamide Company, Process Chemicals Department, Wayne, New Jersey.
3.
Gagliardi, D.D. , Jutras, W.J., Jr., and Stem , E., "Polyalkylated Monoureins ," U. S. 3,209,010, September 28, 1965.
4.
Gonzales, E.J. and Benerito, R., Effect of the Catalyst upon the Physical and Chemical Properties of Cotton Cellulose Finished with Derivatives of Ethyleneurea , Textile Res. J.35, 168-78 (1965).
5.
Meckel, L., Milster, H., and Krause U., Textile-Chemical Testing by Means of Film Chromatography, Textil-Praxis16, 1032-1037 (1961); translated by Nathan, H. A. G., Technical Translation 1040, National Research Council of Canada, Ottawa, 1961.
6.
Northern Piedmont Section AATCC Research Committee , "Thin-Layer Chromatography: An Overlooked Analytical Tool ," Textile Chem. Colorist1, 32-40 (1969).
7.
Petersen, H. , Reaction Mechanisms , Structure, and Properties ofMethylol Compounds in Cross-Linking Cotton, Textile Res. J.38, 156-176 (1968).
8.
Randerath, K., "Thin-Layer Chromatography," translated by Libman, D. D., New York, Academic Press, 1966.
9.
Sanderson, W.A. , Mueller, W.A., and Swidler, R., Phosphonate Finishes for Fire-Retardant, Durable-Press Cotton, Textile Res. J.40, 217-222 (1970).
10.
Stahl, E., Ed., "Thin-Layer Chromatography, A Laboratory Handbook," New York, Academic Press, 1965.
