Vapor-Phase Deposition of Surface Polymers and Cross-Linking on Cotton Fabrics 1

Abstract

Vapor-phase deposition of selected polymers on cotton fibers offers certain potentially attractive characteristics over conventional liquid-phase textile processing. These include uniformity and completeness of coverage at low add-on's in the absence of solvents, lower reaction temperatures and/or shorter exposure times, and use of reactants normally sensitive to water and solvents, all or some of which may result in a more favorable balance of the performance properties of such polymer-coated cottons.

High molecular-weight polyoxymethylene polymer deposits were obtained by the immersion of cotton fabrics in a suit able alkaline catayst solution at ambient temperatures and in air, followed by exposure of the catalyzed cloths to purified monomeric formaldehyde vapor. Polyamide polymer deposits were realized by modified interfacial polymerization tech niques, also under mild reaction conditions. The properties of these polymer-coated cotton fabrics were determined over a range of polymer add-on's, with emphasis on the effects of treatments with various cross-linking agents. Both methylo lamide-treated, polyoxymethylene-coated and diisocyanate-treated polyamide-coated cotton fabrics were found to exhibit significant improvements in wrinkle recovery and other performance properties with superior strength retention at re latively low polymer add-on's, compared to conventionally cross-linked fabrics.

Keywords

Cotton formaldehyde polyoxymethylene hexamethylenediamine sebacoyl chloride Nylon 610 (TN)polyamide polymers methylol amides methylol compounds acetic anhydride 2 4-(2,4,4-) trimethylhexamethylene diisocyanate isocyanates Rhonite R1 (TN)DMEU Aerotex Reactant LC (TN)glyoxal compounds Aerotex Reactant 1 (TN)uron compounds 1,2,3,4-cyclopentane tetracarboxylic acid maleic acid carboxylic acids epichlorhydrin Permafresh 183 (TN)DHDMEU cross-linking agents reactants. Chemically modified cotton coated fabrics. Textile materials Textile processing (general). Shape abrasion wrinkle recovery esterification tear strength flame resistance. Sodium hydroxide t-butylamine ethanol dimethylformamide halogenated compounds solvents diphenylamine antioxidant Mykon SF (TN)softener sodium acetate Triton X405 (TN)Triton X100 (TN)zinc nitrate Catalyst X4 (TN)dibutyl diacetate alkaline catalyst catalyst. Concentration time temperature. Deposition cross-linking interfacial polymerization end-capping strength retention abrasion resistance flame resistance deposition shape. Chemically modified cotton coated fabrics. Interfacial polymerization pad-dry-cure process abrasion testing fire resistance testing strength testing wrinkle recovery testing strength elongation testing tear testing add-on testing chemical analysis.

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