The results of irradiations of brightened and unbrightened wools in the wavelength range 300–600 nm show that the brightener accelerates both yellowing and free radical formation in the region where maximum excitation of fluorescence occurs (350–410 nm). Radical-decay studies have enabled comparisons of the radicals produced at 310 and 365 nm to be made.
. AyscoughP. B.IvinK. J.O'DonnellJ. H., Electron Spin Resonance Investigation of Trapped Hydrocarbon-Sulphonyl Radicals, Proc. Chem. Soc., 71–72 (1961).
2.
. DunlopJ. I., “The Effects of Ultraviolet Irradiation on Keratin and Related Proteins,” Ph.D. thesis, Univ. N.S.W., Australia, 1964.
3.
. DunlopJ. I.NichollsC. H., Electron Spin Resonance Studies of Ultra-Violet Irradiated Keratin and Related Proteins, Photochem. Photobiol.4, 881 (1965).
. FallawD. C.TuckerD. J., Optical Brightening Agents on Wool: A Report of a Study on Uses for Production of White and Pastel Shades, Textile J. Aust.40(8), 46–48 (1965).
6.
. GordyW.ArdW. B.ShieldsH., Microwave Spectroscopy of Biological Substances. I. Paramagnetic Resonance in X-Irradiated Amino Acids and Proteins, Proc. Natl. Acad. Sci. U. S.41, 983–996 (1955).
7.
. GrahamD. R.StathamK. W., The Photochemical Oxidation of Wool in the Presence of Fluorescent Compounds, J. Soc. Dyers Colourists72, 434–438 (1956).
8.
. GruenL. C.InglisA. S., Studies in Wool Yellowing. Part XXI: Further Studies on Wool Fabrics Treated with Fluorescent Brightening Agents and Thiourea Formaldehyde, Textile Res. J.38, 509–517 (1968).
9.
. HendricksenT., in “Free Radicals in Biological Systems,” Ed. BloisM. S., N. Y., Academic Press, 1961, p. 279.
10.
. InglisA. S.LennoxF. G., Studies in Wool Yellowing. Part IX: Irradiation with Different UV Wavebands, Textile Res. J.35, 104–109 (1965).
11.
. LaunerH. F., Effect of Light Upon Wool. Part IV: Bleaching and Yellowing by Sunlight, Textile Res. J.35, 395–400 (1965).
12.
. LaunerH. F., Effect of Light Upon Wool. Part V: Yellowing and Bleaching by Ultraviolet and Visible Arc Light, Textile Res. J.35, 813–819 (1965).
13.
. LaunerH. F., Effect of Light Upon Wool. Part VI: Spectral Conformity in Photobleaching of Wool, Textile Res. J.36, 606–611 (1966).
14.
. LeaverI. H., Studies in Wool Yellowing. Part XXII: ESR Investigations of the Action of UV Radiation, Textile Res. J.38, 729–734 (1968).
15.
. LennoxF. G., A Spectrophotometric Study of Yellowing in Wool Fabric, J. Textile Inst.51, T1193–T1213 (1960).
16.
. LennoxF. G.InglisA. S.HoltL. A., Studies in Wool Yellowing. Part XIII: Partial Bleaching with Visible Light, Textile Res. J.36, 837–843 (1966).
17.
. LennoxF. G.KingM. G., Studies in Wool Yellowing. Part XXIII: UV Yellowing and Blue-Light Bleaching of Different Wools, Textile Res. J.38, 754–761 (1968).
18.
. MaclarenJ. A., Studies in Wool Yellowing. Part VI: Changes in Amino Acid Composition due to Yellowing, with Particular Reference to Cystine, Textile Res. J.33, 773–778 (1963).
19.
. MilliganB.TuckerD. J., Studies in Wool Yellowing. Part III: Sunlight Yellowing, Textile Res. J.32, 634–640 (1962).
20.
. RobsonA., Joint Discussion on Papers by Bell, Clegg, and Whewell: Norton and Nicholls: Lennox, J. Textile Inst.51, T1210–T1213 (1960).
21.
. RoxburghC. M., Unpublished work.
22.
. SavigeW. E., Studies in Wool Yellowing. Part XVIII: Processes for Retardation of Sunlight Yellowing of Fluorescent-Brightened Wool, Textile Res. J.38, 101–102 (1968).
23.
. WindleJ. J., Naturally Occurring Electron Paramagnetic Resonance in Wool, Textile Res. J.32, 963–965 (1962).
24.
. WindleJ. J., “Technical Wool Conference, Agricultural Research Services, ARS-74–29,”U. S. Department Agriculture, 1964, p. 74.